活化能

There was no residue or few from asphaltene reprecipitation after acidolysis asphaltene, and using fatty acids were extracted by hexane.

结果表明，相同阳离子的不同羧酸盐活化能和频率因子分布特征相似，拥有相同的均值，不同之处在于短链的比长链的羧酸盐振荡幅度宽；不同阳离子的同种羧酸盐，活化能和频率因子分布却相差很大。

For the water-content explosives, the heat is released after the water is vapored during the heating.

对于含水炸药，受热过程中首先发生的是破乳、脱水，脱水之后才开始迅速分解放出热量，二级煤矿许用乳化炸药活化能随着分解率的增加而增大；平均活化能为E=124.05kJ/mol，从开始放热到热爆炸临界点的延滞期为

On the basis of DSC curves of B/KNO_3 igniter powder,the apparent activation energy E of thermal decomposition is calculated with Kissinger′s methods and the probable mechanism function is available from master plot method.

利用差示扫描量热法得到B/KNO3的热分解曲线，用K iss inger方程估算了B/KNO3的表观活化能，用标准作图法得到最可几热分解机理函数，再用积分法求得不同升温速率下热分解的动力学参数活化能E和指前因子A。

It has confirmed that the reactive terminated polyethylene glycols did participate into the curing reaction and construct the soft segments in the crosslinking network.

此外，聚乙二醇的加入还使不饱和聚酯固化反应的活化能明显提高；而改性聚乙二醇的加入，却不影响体系固化反应的活化能。

With increasing iodine value,the activation energy of vegetable oil hydrolysis in near-critical water decreased.

油脂水解活化能与其碘价密切相关，随着油脂碘价的增加，水解活化能逐渐降低。

The calculated results with B3LYP/6-31G-DFT show:(1)the molecular total energy of benzofuroxan is lower than that of o-dinitrosobenzene;(2)the activation energy(Ea+=51.0kJ/mol)of forward reaction that benzofuroxan isomerises into o-dinitrosobenzene,is in agreement with the experimental(58.6kJ/mol)provided by reference,and the activation energy(Ea-=4.6kJ/mol)of back-ward reaction is very small.It is concluded thereby that benzofuroxan is more stable than o-dinitrosobenzene.In addition,the corresponding ab initio calculations at the level of HF/3-21G,HF/6-31Gand MP2/6-31G//6-31G were completed,and it was found that the calculated results by B3LYP-DFT method are superior to those from ab initio calculation.

结果表明，苯并氧化呋咱的分子总能量比邻二亚硝基苯的低；由苯并氧化呋咱异构为邻二亚硝基苯的正向反应活化能（Ea+=51.0kJ/mol），与文献实测值（58.6kJ/mol）较接近，而其逆向反应活化能（Ea-=4.6kJ/mol）很小，从而揭示了苯并氧化呋咱比邻二亚硝基苯更稳定·此外，进行了HF/3-21G、HF/6-31G和MP2/6-31G//6-31G水平下相应的计算，发现B3LYP-DFT的结果较abinitio为优。

For (NH4)2S2O8 initiated ISP system consisted of AA, SPAN emulsifier and kerosine, it was found Rp 1.10.8, Eap=78.8kJ/mol for acrylic acid system and Rp 1.50.6, Eap=57.8-83.7kJ/mol for ammonium acrylate system The value of was negative when , the emulsifier concentration ,was low and became positive when was high for both systems.

用过硫酸铵引发AA类单体、SPAN系列乳化剂及煤油体系的ISP时，对AA体系Rp∝~(1.1)~(0.8)~Y，聚合总活化能为78.8KJ／mol；对丙烯酸铵体系，Rp∝~(1.4)~(0.6)~Y，聚合总活化能为57.6～83.7 kJ／mol，两体系中的γ值在乳化剂浓度较小时为负值，增加到一定程度时为正值。

Based on three hypotheses, the single reaction model was used for the calculation of active energies during pyrolyzing of HBs (except OH-π) in coal for the first time, and the values agreed well with those obtained with other methods.

在三条假设的基础上，采用单一反应模型的理论，研究了煤中除OH-π以外的其它氢键热分解的活化能，通过该方法计算的氢键的热解活化能与通过其它途径得到的值接近

Fitting curves are in good agreement with the experimental results,the calculated kinetic parameters are in good agreement with those reported in term of modeling of the pyrolysis of the three components assuming hemicellulose,cellulose and lignin pyrolyzing independently and para...

采用非线性最小平方算法，按三组分独立平行一级反应热解动力学模型，模拟计算的曲线与实验结果吻合较好，求解的动力学参数与文献报道值吻合较好，且随着升温速率的加快，纤维素和木质素热解的活化能有增加的趋势，而半纤维素活化能有下降的趋势。

To estimate the activation energy of the decomposition, the Friedman isoconversional method was applied. The activation energy was calculated as a function of conversion. The results confirm that more than one reaction occurs in the decomposition of basic zinc carbonate.

采用Friedman法对实验数据进行分析，结果表明，反应的活化能数值随着分解率的不同而变化，由此推断该反应是由多步反应组合而成的，其平均表观活化能E。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。