活化能

The transesterification reaction among poly,poly(ethylene 2,6- naphthalate),and PET／PEN copolymer were studied with1H-NMR.

通过用1H-NMR对聚对苯二甲酸乙二酯与聚2，6-萘甲酸乙二酯、PET/PEN共聚物的共混物酯交换反应的研究，测得了反应速率常数、反应活化能和诱导期。

From the valuves of activation energy and enthalpy,it was proved that the Ochrept'sbioavailability of nonexchangeable potassium was higher than the Ustochrepts'.

活化能和焓变的数据证明了褐土中的非交换性钾比潮土中的非交换性钾更容易释放，因而对植物也就更有效。

Firstly, the reaction thermodynamics was analyzed. Then, the reaction mechanism was studied, and the results are as following:① Ca moves to the surface of Dy〓O〓 by vapor phase;② Dy〓O〓 reduced to Dy by Ca is fast;③ Dy moves to the Fe surface mainly by vapor and various Dy-Fe alloys are produced gradually;④ The forming process of DyFe〓 may be described by Contracting Core Model;⑤ The rate-controlling step of the reaction is the Dy diffusing toward contracted and nonreaction nuclear center Fe.

首先考察反应的热力学可能性；其次探讨反应机理；通过实验确定：①Ca主要以气态形式迁移到Dy〓O〓表面参与反应；②Dy〓O〓被Ca还原为Dy的速度很快；③Dy主要以气态形式迁移到Fe表面逐级生成Dy-Fe合金；④DyFe〓的形成过程可以应用收缩核模型来描述；⑤Dy通过DyFe〓产物层向缩小的未反应核中心Fe的扩散是反应的控速步骤，通过动力学计算确定：还原扩散反应的表观活化能E〓=45kJ/mol。

Kinetics characteristics of α- pinene isomerization catalyzed by activated carbon supported phosphotungstic acid was studied .

研究了活性炭固载磷钨酸催化α－蒎烯的异构化反应的动力学特征，研究表明，以环己烷作溶剂，α－蒎烯在活性炭固载磷钨酸上的异构化服从准一级动力学模型，其反应的表观活化能为100。

Ti~(3+) appearance in the preparation process is good for improving photoactivity as well.

在上述研究的基础上，在本论文还试图从分子水平上解释Ni系复合催化剂光催化制氢反应的活化能变化及其表面氢气产生的微观反应过程。

In the temperature rang from 120 to 150℃, the relations between the apparent reaction rate constant and temperature of the photochlorination in the side chain of m-chloromethyl benzene were: min-1 min-1 min-1 The apparent reaction activation energies are: Ea1=33.54、Ea2=32.45、Ea3=24.26kJ/mol.

在120～150℃温度范围内，间氯甲苯侧链光氯化表观反应速度常数与温度的关系为： min-1 min-1 min-1 表观反应活化能分别为：Ea1=33.54、Ea2=32.45、Ea3=24.26kJ/mol。

The obtained potential energy curves disclosed that a four-state cycle existed in the ground and excited states. It was also found that the activation energy for the methyl transfer was higher compared to the phenyl transfer, which was consistent to the experimental results that the photoisomerization of the phenyl substituted derivative was more rapid than the methyl substituted derivatives.

对反应势能面的研究发现，在光异构化反应中化合物M21和M21、M31的基态和激发态虽然都可以构成四能级反应过程，但由于M21异构化过程的活化能较高，使其所构成的四能级反应难以进行，这就从理论上解释了迁移基团为甲基的M21变色性能低于迁移基团为苯基的M31的实验结果。

The new method can differentiate the pozzolanic reactivity of active SiO2 and Al2O3, and obtain the useful parameters, such as reaction rate constant and activation energy.

该法不但可以反映出活性SiO2、Al2O3火山灰反应能力差异，还可得到火山灰反应速率常数和表观活化能等有用的动力学参数。

For three different reaction paths leading to ortho, meta, para-chloropyridine, two transition states have been located by PM3 on each reaction path, while only one transition state by ab initio, however both methods give the same results: the energy of transition state and activation barrier on producing 2-chloropyridine are the lowest among three reaction paths, so 2-chloropyridine is obtained priorly, which agrees with the experimental results.

生成邻、间、对氯代吡啶三条不同反应途径PM3方法优化得到两个过渡态，而从头算方法中只优化得到一个过渡态。但两种方法的研究结果均表明：三条反应途径中生成2-氯吡啶的过渡态能量和活化能最低，因此反应优先生成2-氯吡啶，与实验结果一致。

Dissolution process of a-TCP cement hardened body accords with the kinetic model equation: y =-ln =kt05 , its activation energy is 9.87 kJ/mol, which means dissolution is diffusion control. The dissolution mechanism of a-TCP cement may be considered as dissolution and reprecipitation of defective calcium hydroxy- apatite hydrated from a-TCP.

含有TTCH的a一TCP骨水泥固化体在生理盐水中的溶解动力学方程为：y二一In(1一x)=kto.4；溶解过程为扩散控制；其中含l%TTCH的骨水泥溶解反应活化能约为7.17kJ/mol，随着药物含量的增加，骨水泥固化体的溶解速率常数下降。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。