活化能

The enzyme may exist in two interconvertible, active forms which possess different activation energies

酶可以以两种相互可变的、具有不同活化能的活性形式存在。

The results showed that the kinetical rule of the ion-exchange reaction was not changed, the ion-exchange process was still controlled by the grain diffusion, and the concentration of Cl~- has little effect on the apparent activation energy of reaction if the total concentration of ion in the solution kept invariableness.

结果表明，在维持溶液中离子总的当量浓度不变的条件下，离子交换反应的动力学规律不会发生改变，反应仍然是受粒扩散控制，氯离子浓度对交换反应表观活化能的影响不大。

In combination of oxygen nonstoichiometry data determined using the iodometric titration, the oxygen chemical diffusion coefficient D〓 for YBa〓Cu〓O〓 is calculated. D〓 takes a value of 7. 8×10〓 at 650℃ and 2. 0×l0〓cm〓s〓 at 800℃, and the associated apparent activation energy is 51±0.9 kJ·mol〓.

根据Fick第一定律，结合氧渗透率数据及氧非化学计量数据，可计算出YBa〓Cu〓O〓的氧化学扩散系数D〓在650～800℃，D〓为7.8×10〓～2.0×10〓cm〓，D〓的表观活化能为51±〓0.9 kJ·mol〓。

The synthesis of isoamyl acetate with the solid super acidic catalyst of S2O827TiO2-Al203 is investigated. The kinetic parameters of reaction are measured at 94℃, 100℃ and 106℃ respectively and the kinetic equation is thus built, which are compared with those of the reaction without catalyst.

文章研究了以固体超强酸S2O82-/TiO2-Al2O3为催化剂合成乙酸异戊酯的反应，在反应温度分别为94℃、100℃及106℃下，测出合成乙酸异戊酯的动力学方程参数，建立了动力学方程式，并与无催化剂时酯化反应的活化能及动力学方程式进行了比较。

The synthesis of isoamyl acetate with the solid super acidic catalyst of S2O82-/TiO2-Al2O3 is investigated.The kinetic parameters of reaction are measured at 94℃,100℃ and 106℃ respectively and the kinetic equation is thus built,which are compared with those of the reaction without catalyst.

文章研究了以固体超强酸S2O82-/TiO2-Al2O3为催化剂合成乙酸异戊酯的反应，在反应温度分别为94℃﹑100℃及106℃下，测出合成乙酸异戊酯的动力学方程参数，建立了动力学方程式，并与无催化剂时酯化反应的活化能及动力学方程式进行了比较。

6Fe_2O_3. 1.81 (CaO.2Fe_2O_3) The apparent activation energy of barite decomposition in air is 119.9 kJ/mol and the order of reaction is 1.3—1.4 obtained by kinetical calculation.

动力学计算表明，在空气中重晶石分解的表观活化能E~*=119.9kJ/mol，反应级数n=1.3—1.4。

Whereas, at the second stage H-transfer from indole to malonate occurs with the formation of the new C—H bond, the energy barriers calculated for this step are 99.2 and 115.1 kJ/mol for the R - and S -configuration product, respectively.

其中第一阶段由复合物经过渡态TS1生成中间体IM，是C—C键的形成阶段，该阶段的活化能垒较后一阶段要大，是该反应的决速步骤；第二阶段由IM经过渡态TS2生成产物，完成H迁移和C—H键的形成。

There are three platinum catalyst micro channels which have different width ,such as 1000 m , 400m and 40m. The platinum catalyst micro channel reactor is fabricated by MEMS technology. The reactor uses the exothermic reaction of hydrogen and oxygen on the platinum catalyst plate as the heat source and the platinum thin film resistance deposited on a glass chip by face micro machining process as catalyst and temperature sensor. The channel is bonded with a cover plate etched by bulk micromachining technology to become a mico- channel reactor.

实验主要以微机电加工技术制作白金触媒微管道反应系统，利用微机电面型加工技术将白金薄膜电阻制作於基材为玻璃的晶片上，以此为反应所需的触媒及温度量测元件，并用体型加工技术蚀刻出微流道的上盖板相结合成微管道反应系统，本研究以1000μm、400μm及40μm的白金触媒微管进行测试，并利用微管道管壁上触媒表面降低反应活化能的特性来维持反应，此微反应系统利用氢气与氧气在白金触媒平板上的放热反应作为能量的来源。

At a constant shearing rate,the influences of montmorilonite loading on the shearing stress and apparent viscosity were similar.The reduction of the viscous activation energy with the increm...

PA611/蒙脱土纳米复合材料的粘流活化能随剪切应力的增大而降低，说明在恒定剪切应力下其可在较宽的温度范围内加工、成型。

The results showed that the acidities of 13X molecular sieve and mordenite by CVD were unchanged, and the relationship between SiO〓 deposition and contraction of pore diameter was determined.

在HMC-60催化剂上，140-156℃范围反应均为一级，表观活化能为1.75KJ/mol，频率因子A=5.314×10〓，反应速率与温度的关系为k=5.314×10

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。