活化能

The optimal measuring conditions were investigated. The results indicated that the catalytic reaction to Pt and bromocresol purple was the first-order reaction. The apparent activation energy was 217.4kJ/mol and the maximum absorption wavelength of fading reaction was at 434 nm. The linear range of Pt was 0.16-4.0μg/L and the detection limit was 2.5×10^(-11)g/mL. Most of common ions had no interference with the determination, while ten multiples of Ru, Rh and Os had interference with the determination of Pt. Therefore.

选择了最佳测定条件，实验结果表明，催化反应对铂和溴甲酚紫为一级反应，反应的表观活化能为217.4kJ/mol，褪色反应的最大吸收波长为434nm，方法测定R哪的线性范围为0.16~4.0μg／L，检出限为2.5×10^(-11)g/mL，大多数常见离子不干扰测定，10倍以上的Ru，Rh和Os对测定有干扰，可在测定前分离除去。

In this thesis, by the means of calefactive oxidation test of coal samples, the characteristics of different samples spontaneous combustion are analyzed; the infrared spectrum is assimilated to review the rule that coal function corps change in the process of coal low-temperature oxidation ; by the means of thermal analysis by differential scanning calorimeter, thermogravimeter, the kinetic function of coal low-temperature oxidation in spontaneous combustion process are analyzed , depend on the device, the mathematical model of coal spontaneous combustion is developed, the model are dealt with, Finally, the temperature field and the velocity field with velocity of the entry flow is got.

论文通过煤的低温氧化和自燃过程，实验研究了煤的低温氧化气体产物特征和变化规律，研究得出了煤的低温氧化过程中气体生成量与氧气消耗量与煤温之间的指数关系式；在煤的低温自热氧化过程中，对煤的官能团等化学结构的变化研究，揭示了煤炭低温自热氧化化学基团变化规律；采用非等温TG和DSC法研究了烟煤低温氧化动力学，得出了煤低温氧化分布活化能及煤低温氧化机理函数的变化规律；建立了煤低温氧化自热数学模型，并对该模型进行数值解算，可得煤样的温度场与速度场随入口风量变化情况。

Differential scanning calorimetry of the thermo-analytical technique was used to determine the cure kinetics of this system.

分别采用Kissinger和Ozawa-Flynn-Wall方程推导了该固化体系的固化动力学方程，并计算了固化反应活化能。

The results demonstrated that the fractional conversion and reaction rate were rapidly increased in the initial curing reaction. The higher the curing temperature, the higher the fractional conversion and reaction rate was. With increasing of the curing temperature and time, the fractional conversion and reaction rate decreased and became constantly. The initial curing reaction was a first order reaction. The apparent activation energy and frequency factor of curing reaction used G- capryl ester was bigger than that of used G-oligomer.

结果表明：固化体系在研究的固化温度下，转化率和反应速率在固化反应初期增加快速，温度越高增加越快，随着固化时间的延长，这种变化逐渐变慢，并最终趋于恒定；初期固化反应为一级反应，反应初期的表观活化能和指前因子大小顺序为G-预聚体＞G-辛酯。

GC-MS is used to determine content of free TDI, reaction kinetics is analysed by chlorhydric acid/n-dibutyl amine titration -NCO method and DSC, so the system activation energy is calculated.

采用气相色谱-质谱法测定其游离TDI含量，用盐酸-正二丁胺滴定-NCO法和DSC法相结合，分析反应动力学规律，计算体系表观活化能。

The overall activation energies of crotonic acid, undecylenic acid and oleic acid systems are 118, 122 and 134 kJ/mol, respectively.

反式丁烯酸、10-十一烯酸、油酸接枝ABS树脂的反应活化能分别为：118、122、134kJ／mol。

Compared to the hydrogen storage material 70Mg30C and MgH2, the crystallitic carbon and the catalysts of Ni and Al cut down the dehydrogenation time, increased the dehydrogenation capacity of hydrogen storage material, and reduced its apparent activation energy. And the dehydrogenation kinetics performance was improved.

与储氢材料70Mg30C及纯MgH2相比，微晶碳和催化剂Ni、Al缩短了储氢材料的放氢时间，加快了放氢速度，提高了放氢量，降低了表观活化能，放氢动力学性能得到了改善。

Keywords rare earth composite solid superacid;cyclohexyl acetate;catalytic synthesis;kinetic equation;activation energy

稀土复合固体超强酸；乙酸环己酯；催化合成；动力学方程；活化能

Synthesis of cyclohexyl acetate with rare earth composite solid superacid catalyst of SO2-4/TiO2/Ce4+was investigated.

研究了以稀土复合固体超强酸SO42-/TiO2/Ce4+为催化剂合成乙酸环己酯的反应，在反应温度分别为100℃、110℃、120℃下，测出酯化反应的动力学参数，建立了动力学方程，并与无催化剂作用下合成乙酸环己酯反应的活化能及动力学方程进行了比较。

The activation energies were highly pH-depended and decreased very sharply as the pH went up from 6. 0 to 11. 0 or down from 6. 0 to 2. 0.The stability of Gln residues in peptides or corn protein was the most at pH6. 0.At pH 6. 0, the rate constants of deamidation were the lowest, and their half-life and Arrhenius activation energies were the highest.

过酸或过碱都将增加脱酰胺反应的速率，动力学结果表明，pH6.0时最为稳定，表现为pH6.0时的脱酰胺反应速率常数最小、半衰期最长、活化能最大。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。