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Thiourea can keep polymer solution steady well as antioxygen. And micromolecule-alcohol can associate with polymer, which maintains the network structure of polymer.

其中硫脲能起到抗氧剂的作用,在短期内能使溶液保持较好的稳定性;小分子醇类能与聚合物交联,使疏水缔合聚合物溶液的网状结构得以维持。

The object of this study is to evaluate the immunoregulation and anti-tumor activities of Arnebia root polysaccharide in vitro. The ARPS was obtained by hot-water extraction, alcohol precipitation, de-protein, de-color, and dialysis etc. from Arnebia root and was administered on mouse spleen lymphocyte and tumor cell with 24 μgmL^(-1), 121 μgmL^(-1), 364 μgmL^(-1), respectively.

为研究紫草多糖在体外对小鼠脾淋巴细胞的免疫调节活性及对肿瘤细胞的细胞毒作用,本实验采用水提醇沉法,经脱蛋白、脱色、透析等方法提取紫草多糖,MTT法检测紫草多糖对淋巴细胞增殖及对HepG2、SPC-A-1肿瘤细胞的杀伤作用。

Using benzyl chloride and chlorine as starting materials, benzal chloride is prepared through photo-chlorination in loop reactor.

采用环流反应器、以氯化苄和氯气为原料进行光氯化反应,制备苄叉二氯;将制得的苄叉二氯粗品进行真空精馏得到高纯度的精品;然后用一种新型醇胺类相转移催化剂,分别以盐酸和水作为介质,在 90~ 110℃水解后得到了高纯度的苯甲醛。

We studied the effect of water on the palladium acetate-catalyzed coupling reaction of aryl boronic acid with aryl bromide or acyl chloride in ionic liquid or PEG, and found that water had a remarkable rate accelerating effect on the Suzuki reaction and Suzuki-Type reaction when other reaction conditions were uniform.

研究了水对离子液体或聚乙二醇中Pd2催化的卤代苯或苯甲酰氯与苯硼酸的Suzuki和Suzuki-Type偶联反应收率的影响。

Chelator-assisted hydrothermal method for growing ZnO nanopricks ZnO nanopricks were formed while 0.3 mol/L diaminoethane, 3 mol/L butylamine and 0.25 mol/L EDTA were used as chalators to react with zinc foil at 100℃ for 12 h.

络合物水解法制备ZnO球形颗粒利用酒石酸锌的水解反应,在水溶液中制备了由超细颗粒组装的ZnO球形颗粒,XRD、HRTEM检测结果表明颗粒为纤锌矿ZnO多晶结构,在溶液中添加乙二醇,产物的尺寸和分散性得到了改善。

It was increased ethyl hexanoate synthesis substrate concentration mediated by Rhizopus chinensis 2113 whole-cell lipase after improved synthetic activity and optimized reaction condition. The reaction condition were: caproic acid concentration 2.4mol/L, substrate molar concentration ratio 1:1.1, initial water content ≤0.2%, lipase water activity 0.3~0.66, enzyme amount 16%, reaction temperature 30℃, agitation speed 150 r/min.

通过合成酶活的提高及反应条件的优化,提高了华根霉2113全细胞脂肪酶催化己酸乙酯合成的反应底物浓度,其反应条件为:己酸浓度为2.4mol/L;酸醇摩尔浓度比1:1.1;反应体系含水量≤0.2%;脂肪酶水活度0.3~0.66;加酶量16%;反应温度30℃;150r/min振荡反应。

As concerning synthesis of 2-ethylhexyl chloroacetate, effects of catalyst dosage, molar ratio of 2-ethylhexanol to chloroacetic acid, reaction time, dosage of water entrainer on esterification rate were studied.

将此固体超强酸酯用于氯乙酸和异辛醇合成氯乙酸异辛酯的酯化反应,考察了异辛醇和氯乙酸的摩尔比、催化剂用量、反应时间、带水剂环己烷的用量对酯化反应的影响。

Cycloalkylation of diethyl malonate and ethyl cyanoacetate with alkyl halide was investigated in the presence of toluene.

以甲苯为溶剂及带水剂,用粉末K2CO3代替常规使用的乙醇钠,在季铵盐和聚乙二醇混合相转移催化剂的存在下,含有活泼氢的丙二酸二乙酯和氰乙酸乙酯与二卤代物进行缩合反应,得到相应的环化物。

The composition of the equilibrium mixture is the same no matter whether one has started from an equimolar mixture of acid and alcohol or ester and water.

起始的等摩尔混合物无论是羧酸和醇还是酯和水,平衡混合物的组成都是相同的。

The volume ratio of furaldehyde to acetic anhydride is 1∶2; the mole ratio of furaldehyde with anhydrous potassium carbonate is 1.00∶0.54. The best phase transfer catalyst is PEG1000, the mass ratio of PEG1000 with furaldehyde is 4.3%, the reaction time is 11 min, the reaction power of microwave is 260 W. The yield ofα-furanacrylicacid is up to 72.3% under these reaction conditions.

研究结果表明:在微波辐射功率为260 W、微波反应时间为11 min、以聚乙二醇1 000(PEG1000)为相转移催化剂,糠醛与乙酐的体积比为1∶2,糠醛与无水碳酸钾的量比为1.00∶0.55时,α-呋喃丙烯酸的产率为72.3%。

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