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When the sodium lauryl sulfate and p-octyl polyethylene glycol phenyl ether is used and its level in 3% and 6: 4 ratio, the polymerization process has the lowest coagulum and the highest monomer conversion. Higher reaction temperature and more level hydroxyl value lead to more coagulum, the latter also lead to larger particle size. The acid value has larger influence on viscosity and coagulum, there exist a best range. The emulsion particle size is larger for its hydrophilicity, most of its particles are connected together.

在含较高亲水单体的乳液聚合体系中,难以制得稳定的预乳化液,不能采用工业生产中常用的预乳化工艺,而只能采用混合单体直接滴加的方法;由于单体混合物的亲水亲油值较高,用阴离子型乳化剂十二烷基硫酸钠和非离子型乳化剂聚乙二醇辛基苯基醚混合,用量为单体总量的3%,且比例在6:4时,乳液聚合时具有最低的凝聚物含量和最高的单体转化率;乳液聚合反应温度升高,可以提高单体转化率,增加反应速度,但凝聚率相应提高;随着羟基单体含量的增加,聚合过程中凝聚率增加,聚合物乳胶粒平均直径增加;羧基单体有一个最佳的用量(2.6%),过高或过低凝聚率均提高;羧基含量对乳液的粘度有较大的影响,当羧基含量较低时,羧基含量增加,乳液粘度增加明显;含羟基乳液粒子由于含亲水基团较多,使得乳胶粒径增大,乳胶粒子大多数互相凝聚在一起,处于凝聚态。

Effects of reaction temperature, volume ratio of water to isobutylene and linear flowrate of Ca raffinate on activity of the catalyst were studied.

试验结果表明,异丁烯催化逆流水合制叔丁醇的适宜操作条件为:反应温度80~90℃,水油体积比为4~5,抽余C4烃的流速为0.45~0.55mm/s。

The experimental results showed that under the reaction temperature of 80℃,using catalyst 5 % of the mass of turpentine,reaction time of 10 h,turpentine:solvent:assistant:water of 1∶1∶1∶2,the conversion ratio of 90 %,the selection of α-Terpineol production was 64.96 %,and ΔHφf,g and Sφg were estimated as well...

实验结果表明,在反应温度80℃,催化剂用量为松节油质量的5%,反应时间10 h,松节油∶溶剂∶助剂∶水为1∶1∶1∶2时,其α-蒎烯的转化率为90%,生成α-松油醇的选择性为64.96%。并对α-蒎烯和松油醇理想气体的△Hfφ,g、Sgφ进行了估算,为今后的理论研究提供了数据支持。

The effects of reaction temperature, space velocity, molar ratio of water to methanol, and reaction time on the performance of the micro reactor were investigated.

试验研究分析了反应温度、进料速度、水醇比(水和甲醇的物质的量的比)、反应时间对甲醇水蒸气重整制氢微型反应器性能的影响。

The results show that myristic acid radical anion of precursor Zn0.78 Al0.2220.22c13h27COO0.81H2O can be almost completely replaced by complex anion [La(TiW11 O39)2]^3- under special controlled reaction conditions.

结果表明,该产物中[La(TiW11O39)2](上标 13-)配阴离子沿其长轴垂直于层板的方向分布于水滑石层板间,产物有规整的层状结构、大的层间距(d003=3.29nm)、良好的结晶度和热稳定性,产物对二甘醇与苯甲酸的酯化反应、二甘醇的脱水环化反应和苯甲醛的氧化反应具有良好的催化性能。

Under optimal conditions: reaction temperature 80-90 ℃,V ∶V 4-5 ,linear flowrate of C4 raffinate 0.45-0.55 mm/s, conversion of isobutene can ...

试验结果表明,异丁烯催化逆流水合制叔丁醇的适宜操作条件为:反应温度80~90℃,水油体积比为4~5,抽余C4烃的流速为0.45~0.55mm/s。

A novel combination of PVA and polystyrene sulfonic acid is also realized by blending method.

在乙醇—水混合物的渗透蒸发分离中,PVA表现出良好的阻醇性能,这意味着PVA本身可能具有与我们的要求相近的亲、憎水比例。

The effects of different of categories surfactants, the proportion of surfactant and cosurfactant , the chain lengths of alcohol and alkane, temperatures and pH values on the W/O microemulsion phase areas are systematically studied in the dissertation. SEM and laser scatting techniques are used to verify particles'sizes of W/O microemulsion. Consequently, a system TritonX-100/n-C〓H〓OH (weight ratio 1: 1)/C〓H〓/H〓O is obtained which is a stable system with relatively large W/O microemulsion phase area.

本文系统研究了表面活性剂种类、助表面活性剂的链长、表面活性剂和醇的配比、烷烃的链长以及温度、pH值等对W/O微乳液相区域的影响,并用SEM、激光光散射等对微乳液粒度进行了表征,从而获得一种稳定的、W/O微乳液区域较大的体系:壬基苯酚聚氧乙烯醚(TritonX-100)/正戊醇(质量比1:1)/环己烷/水体系。

In the end, the synthesis condition and influential factors of PU-titania (TiO2) process, such as manufacturing sol (including the amount of water, the amount of PU/Titanium butyrate, the concentration of the solution, the pH value, the kind of alcohol), aging process, theoretical analysis of the dipping process, dry and heat treatment of the gelation, were also discussed especially. FT-IR、SEM、TEM、DLS techniques were applied to analyze and study the reaction mechanism and watch the surface and section of the PU-TiO2 membrane. According to above, it was inferred that PU-TiO2 membrane (containing K600) was better composite.

本文采用原位合成法制备了聚氨酯-二氧化钛水分散复合体,并着重对影响制备稳定透明的复合体的因素(包括加水量、醇的加入量、pH值、聚氨酯/钛酸四丁酯投入量、醇种类)进行讨论,利用红外光谱技术分析聚氨酯-二氧化钛分散复合体的结构,动态光散射技术与扫描电镜分别表征复合分散体的粒径大小与分布及复合膜的表面形态,结果显示含K600的聚氨酯-二氧化钛体系复合情况良好。

The synthesization technics of MPEG- MAA was studied in this paper,which is an important intermediate used for preparation of polycarboxylate superplasticizer.

本文对制备聚羧酸系减水剂的重要中间体——甲基丙烯酸聚乙二醇单甲醚酯的合成工艺进行了研究,考察了反应时间、催化剂对甲苯磺酸的用量、阻聚剂对苯二酚的用量、反应温度及甲基丙烯酸与聚乙二醇单甲醚的用量比对酯化率的影响。

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