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水解催化剂

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Acrylonitrile or methacrylonitrile is hydrolyzed in a suitable aqueous reaction mixture by an enzyme catalyst characterised by a nitrile hydratase and amidase activity of Comamonas testosteroni 5-MGAM-4D, producing the corresponding acid.

在合适的含水反应混合物中通过催化剂使丙烯腈或甲基丙烯腈进行水解生产对应的酸,催化剂的特征在于具有睾丸酮假单胞菌5-MGAM-4D的腈水合酶和酰胺酶活性。

The copperas, a raw material, was oxidized by the oxidant under certain temperature, and then the sulfuric acid and the catalyst were added to the mixture. After the hydrolisis polymerization curing, the polymeric ferric sulfate was prepared.

采用钛白生产中的副产品绿矾(FeSO47H2O)为原料,在一定的温度下经氧化剂氧化,再加入硫酸和一定量的催化剂经水解聚合、静置熟化制备固体聚合硫酸铁。

Combining ion exchange process and silicon hydrolyze process Silicon dioxide mother nuclide with a specific particle size was prepared from sodium silicate through the dropwise technique , then the large particle size , high concentration and stable silica sol was prepared . The stability of silica sol also can be improved by enwrap .

和"单质硅一步溶解法"相结合的方法,用离子交换法制备晶种,并采用滴加工艺制备一定粒径大小的二氧化硅作为母核,在催化剂和分散剂共同作用下水解单质硅的方法使二氧化硅母核颗粒进一步增长成大粒径的二氧化硅颗粒,并另外还采用水溶性高分子对纳米SiO_2粒子进行"原位表面包覆"提高其稳定性,制备了大粒径,高浓度,稳定的纳米硅溶胶。

The experiment gone in a hermetical batch reactor,in this paper cellulose was hydrolyzed with extremely low acid as the catalyst in the high-temperature and high-pressure condition. Factors influencing the sugar yield and cellulose conversion ratio by hydrolysis including reaction time and the concentraction of the acid were studied systematically.

本实验是在密封性良好的间歇反应器中,以生物质的主要成分纤维素为原料,在高温高压条件下进行了极低浓度硫酸为催化剂的均相水解反应研究,系统研究了停留时间、酸浓度对水解糖产率和纤维素转化率的影响规律。

The new technology of hydrolysis of methyl acetate reaction can simplify procedure and improve operational behavior.

开发了一种适用于醋酸甲酯水解的催化反应精馏塔,具有催化剂装填量大、不易泄漏、更换方便等优点,通过实验验证,发现其反应过程与分离过程耦合良好,易于调整,开发了醋酸甲酯反应精馏水解新工艺,简化了流程,提高了过程的可操作性。

After hydrolysis of TEOS for some time,〓 was added to the sol solution.

它是即在用盐酸作为酸性催化剂水解一定时间的溶胶中,加入六次甲基四胺作为碱性催化剂。

The factors,including triphenyl phosphate content, hydrolization time,the volume of water and catalyzer concentration,affecting degree of substitution of cellulose triacetate in hydrolization are studied.

研究了增塑剂磷酸三苯酯含量、含水量、催化剂的比例以及水解时间对三醋酸纤维素水解产物取代度的影响。

The yield was 84%. With OP-10, NPE as the the catalyzer for the diazo reaction, the use of hydrolyzed propenenitrile instead of propenoic acid, and OP-10 as the catalyzers of the aminate reaction, these experiments showed the feasibility of industralization, due to the much reduced costs, shortened reaction time and a higher yield.

采用壬基酚聚氧乙烯醚(OP-10)、萘磺酸甲醛缩合物作重氮化反应催化剂,丙烯腈加成、水解替代丙烯酸,OP-10做氨化反应催化剂,通过四因子三水平正交试验法实验,得到较佳反应参数,反应时间、收率、成本都大大降低,适宜工业化生产。

Results show that acid value of carboxylic wood powder from alkaline hydrolysis is higher,but its yield is lower than that from acid hydrolysis. The adsorption capacity of carboxylic wood powder for basic pink dye increased with increase of the initial concentration of the adsorbate,and could be kept over 500mg/g after repeated use and regeneration for 4 times.

实验结果表明:(1)在适量引发剂(FeSO4 * 7H2O=1g)和适当温度(60℃)作用下,可得到较高接枝增量和接枝率的PANW;(2)在PANW的水解反应中,在碱性催化剂作用下,可得到羧基含量高的产物,但收率较低;而在酸性催化剂作用下,则得到羧基含量低的产物,但收率较高;(3)羧基木粉对阳离子型染料--碱性桃红的吸附容量与起始浓度有关,本实验中,羧基木粉对碱性桃红的吸附容量最高可达500mg/g,对Cu2+的吸附容量最高可达39mg/g;(4)经0.3mol/LHCl再生4次后,羧基木粉对碱性桃红的吸附容量保持在440mg/g以上,在含有多种金属离子的溶液中,羧基木粉优先吸附Fe3+等硬酸型离子。

Near-critical water is a promising reaction medium for conducting the hydrolysis of nitriles without the addition of any additives.

亚氨基二乙腈在没有外加催化剂的近邻界水中可以顺利发生水解。实验测定了亚氨基二乙腈在近临界水中(压力10MPa,温度200~260℃,反应时间10~60min)的水解反应动力学数据并考察了时间、温度、压力和初始反应物/水比对反应物转化率和产物产率的影响。

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