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水生成

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With the characterization of NMR and IR, combining with the synthesis of active species and studies of their structures, it is suggested that the hydride [RuHCl(PPh3)3], being favorably formed in the acid media, exhibited higher activity in the reduction of the C=C bond, while the hydride [RuH4(PPh3)3], being preponderantly formed in the basic media, showed activity and higher selectivity towards the C=O reduction.

通过核磁、红外等表征手段,并结合可能催化活性配合物的合成和结构研究,推测了在非水介质中对C=C和C=O双键起到活化作用的催化剂活性物种和可能的选择加氢反应机理,即,催化剂[RuCl2(PPh3)3]在酸性环境下倾向于生成[RuHCl(PPh3)3]物种,该Ru-H物种对C=C双键加氢反应表现出较高的活性;而碱性环境下则易于生成[RuH4(PPh3)3]物种,该Ru-H物种对C=O双键加氢具有较高的催化活性。

objective to investigate the effect of angelica extract on the content of sorbitol in red blood cell and the synthesis of glycated protein in vitro.

目的观察当归水提取液对红细胞内山梨醇生成及糖化蛋白生成的影响。

As for pock s exist on the surface of the plates,I ve taken multi-angle analyse and study about this kind of defect, among clearing exterior steel billet,heating technics,forming oxidation steel iron,in addition,influence elements,the results of removing squama through high pressure water and factors about removing squama.

针对南钢中板厂中厚钢板表面麻点缺陷的特点,对其产生原因从钢坯表面的清理、加热工艺、氧化铁皮的生成和影响生成的因素、高压水除鳞的效果和影响除鳞效果的因素等多方面进行了分析和研究。

Naphthalene acetyl chloride was prepared firstly by the reaction between α-naphthylacetic acid and SOCl2 in anhydrous benzene,then reacted with potassium thiocyanate to obtain α-naphthalene acetyl isosulfocyanate,as taking an addition reaction with p-chloro benzoyl hydrazine the novel compound N-naphthalene acetyl-N'-p-chloro benzoylamino thiocarbamide was finally synthesized.

通过α-萘乙酸和SOC l2在无水苯中反应制得α-萘乙酰氯,然后与硫氰酸钾反应生成α-萘乙酰基异硫氰酸酯,再与对氯苯甲酰肼进行加成反应,生成新型化合物N-萘乙酰基-N'-对氯苯甲酰氨基硫脲。

Naphthalene acetyl chloride was prepared firstly by the reaction betweenα-naphthylacetic acid and SOCl2 in anhydrous benzene, then reacted with potassium thiocyanate to obtainα-naphthalene acetyl isosulfocyanate, as taking an addition reaction with p-chloro benzoyl hydrazine the novel compound N-naphthalene acetyl-N'-p-chloro benzoylamino thiocarbamide was finally synthesized.

通过α-萘乙酸和SOCl2在无水苯中反应制得α-萘乙酰氯,然后与硫氰酸钾反应生成α-萘乙酸基异硫氰酸酯,再与对氯苯甲酰肼进行加成反应,生成新型化合物N-萘乙酰基-N'-对氯苯甲酰氨基硫脲。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

In comparison with the organic solvents as reaction medium, higher conversion was achieved the tert-ethyl valerate could be formed in the ionic liquid medium.

当反应体系中存在水时,有特戊酸生成。表明反应中2,2,4-三甲基戊烷首先发生β-断裂反应,生成叔丁基正碳离子和异丁烯。

The presence of Mg〓 will change the crystallization process of calcium carbonate and produce aragonite scale. The presence of Zn〓 can prevent the formation of the crystal nucleus of calcium carbonate and then prevent the scale.

当水的硬度、温度增加时,水的结垢速率增加;SO〓和NaCl含量增加,能使水的结垢速率略有增加;Mg〓能改变碳酸钙的结晶过程并产生文石状的水垢;Zn〓的参与能明显阻碍碳酸钙微晶核的生成,从而达到阻垢的目的。

The water-scaling rate will increase when the water hardness or temperature is increased. The water-scaling rate will increase slightly when the concentration of SO〓 or NaC1 is increased. The presence of Mg〓 will change the crystallization process of calcium carbonate and produce aragonite scale. The presence of Zn〓 can prevent the formation of the crystal nucleus of calcium carbonate and then prevent the scale.

当水的硬度、温度增加时,水的结垢速率增加;SO〓和NaCl含量增加,能使水的结垢速率略有增加;Mg〓能改变碳酸钙的结晶过程并产生文石状的水垢;Zn〓的参与能明显阻碍碳酸钙微晶核的生成,从而达到阻垢的目的。

The phenomenon is caused by the control of formation water on the hydrogen sulphide formation and by the incomplete separation of water and gas due to strong heterogeneity of reservoirs.

结果表明,地层水对硫化氢生成的控制作用和储层强非均质性导致的气水分离不彻底是&硫水耦合&的关键。

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