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Three isomorphic pendant derivatives based on monovacant Keggin heteropolytungstate [SiW11O39]8- as building block have been synthesized through the decoration of Co-Im complexes using bench method:5Na_4H_2[SiW_(11)O_(39)CoIm]_(0.63)[SiW_(11)O_(39)Co(H_2O)]_(0.37)·7H_2O (1)_6[SiW_(11)O_(39)NiIm]_(0.8)[SiW_(11)O_(39)Ni(H_2O)]_(0.2)·7H_2O (2)_4Na_6[SiW_(11)O_(39)MnIm]_(0.69)[SiW_(11)O_(39)Mn(H_2O)]_(0.31)·7.5H_2O (3) Complexes 1–3 are the first examples of crystallographically characterized 3d-transition metal mono-substituted POMs with an antenna organic ligand synthesized under normal bench conditions.

以单缺位Keggin型杂多钨硅酸盐[SiW11O39]8-为建筑单元,在水溶液中通过过渡金属-咪唑配合物的修饰,成功地获得了三个同构的悬臂式衍生物:5Na_4H_2[SiW_(11)O_(39)CoIm]_(0.63)[SiW_(11)O_(39)Co(H_2O)]_(0.37)·7H_2O (1)_6[SiW_(11)O_(39)NiIm]_(0.8)[SiW_(11)O_(39)Ni(H_2O)]_(0.2)·7H_2O (2)_4Na_6[SiW_(11)O_(39)MnIm]_(0.69)[SiW_(11)O_(39)Mn(H_2O)]_(0.31)·7.5H_2O (3)它们是第一例在常规水溶液条件下合成得到的X-射线表征的3d-过渡金属取代的悬臂式多酸衍生物。

The sodium dihydroxy phosphate solution was added 0.4% triethylamine and adjusted its pH to 6.0 by adding 20% phosphate acid. The electrodes potential were set at 300mV, 400mV, 550mV and 650mV.

液相色谱的流动相为30mmol/L磷酸二氢钠水溶液:甲醇=90:10(其中水溶液中加入0.4%三乙胺,并用20%磷酸调pH至6.0);四组电极的检测电势分别为300mV、400mV、550mV和650mV。

The interfacial tension between ABEPS solution and crude oil had been investigated. It was shown that ABEPS not only displayed outstanding salt resistance, but also good hard-water endurability, furthermore ultra low interfacial tension could be achieved without alkaline but proper amount NaCl in the water-crude oil system, which proved its excellent interfacial performance and better application prospects.

本论文还通过对ABEPS水溶液与原油之间的界面张力测定,发现ABEPS不仅具有出众的耐盐性能,而且具有良好的抗钙镁性能,合适的盐浓度下,表面活性剂水溶液与胜利原油之间可以在没有外加碱的情况下形成超低界面张力,说明这类表面活性剂具有良好的界面活性和潜在的应用前景。

The characteristics of the AP include (1) in addition to the formation of hydrogel in aqueous alkaline or polar organic solution, AP can form carbonaceous hydrogel in neutral and acidic aqueous solutions, which extents the application of carbonaceous sol-gel;(2) AP contains a large amount of nitric groups which decomposes quickly by thermal initiation, releasing a large amount of gases and heat, indicating explosive properties of the AP;(3) metal salt-containing AP is also explosible by thermal initiation, and the metal in AP promotes the explosion.

以沥青为碳源,用氧化法制备水性沥青过程中,浓硫酸和浓硝酸的比例、用量、氧化温度及氧化时间对水性沥青的收率皆有影响。经过氧化后,沥青上含有许多含氧官能团,导致水性沥青溶于水。含氧官能团越多,水性沥青越易溶于水。调节制备条件,可使水性沥青不仅可以在碱性水溶液中形成凝胶,而且可以在中性和酸性水溶液中形成溶胶、凝胶,从而拓宽了炭基溶胶—凝胶法制备炭基纳米材料的应用范围。

Methods The influences of temperature and pH on the stability of baicalin aqueous solution were investigated by classic homoiothermic acceleration test, and the pH for the most stable solution was determined.

采用经典恒温加速试验考察了温度对黄芩苷水溶液的影响,并测定了黄芩苷水溶液的最稳定pH。

First, this research developed a set of simple and effective technologies for preparative extraction and separation of flavonoid and phloridzin from Lithocarpus polystachyus, which includes:(1) Microwave-assisted extraction of flavonoid f...

本研究首先研发出一套简单、有效的制备性提取分离多穗柯黄酮类及其根皮苷工艺,这套工艺包括:(1)微波辅助氢氧化钙水溶液提取多穗柯黄酮,最佳工艺条件为用1.2 %氢氧化钙水溶液为提取液,料液比1:12,预煮时间5min,微波功率800W处理25min。

First, this research developed a set of simple and effective technologies for preparative extraction and separation of flavonoid and phloridzin from Lithocarpus polystachyus, which includes:(1) Microwave-assisted extraction of flavonoid from tender leaves of Lithocarpus polystachyus Rehd. The extraction conditions are as the follows, 1.2 % of Ca2 water solution, solid-liquid ratio of 1:12, pre-boiling for 5 min, 800 W of microwave treating for 25 min.

本研究首先研发出一套简单、有效的制备性提取分离多穗柯黄酮类及其根皮苷工艺,这套工艺包括:(1)微波辅助氢氧化钙水溶液提取多穗柯黄酮,最佳工艺条件为用1.2 %氢氧化钙水溶液为提取液,料液比1:12,预煮时间5min,微波功率800W处理25min。

Using the improved method, the standard molal enthalpies of solution =-29.18 kJ·mol-1 in pure water and =-25.79 kJ·mol-1 in aqueous sulfuric acid were obtained, respectively.

借助VOSO4水溶液的离子缔合平衡和硫酸的二级解离平衡,改进了Archer方法,并用这种改进的方法分别估算了VOSO4·2.76H2O在水中的标准摩尔溶解焓=-29.18 kJ·mol-1,以及在0.5 mol·kg-1硫酸水溶液中的标准摩尔溶解焓=-25.79 kJ·mol-1。

The densities for HNO3-UO2(NO3)2,NaCI-Na2SO. and KCI-Na2SO4 aqueous ablutions were measured with a high precision densimeter at 25℃. The apparent molal volumes were obtained from the measured densities. An empirical equation is introduced to correlate densities for mixed electrolyte aqueous solutions.

用高精度密度计测量了25℃下 HNO3-UO2(NO3)2, KCI-Na2SO4和NaCl-Na2SO4水溶液的密度从而求出了相应的表观摩尔体积;建立了用于混合电解质溶液密度关联的经验方程,用此方程对9个混合电解质水溶液体系的密度进行了关联,精度较高。

The Fine-Chemical Team, Kunming University of Science and Technology, adds some purifying agents into the solution of fertilizer-grade monoammonium phosphate, and makes it conform to the necessity of aluminium dihydrogen tripolyphosphate synthesis.

特别提到昆明理工大学精细化工教研室,开展了肥料级磷酸一铵水溶液添加一定的净化剂,可使磷酸一铵水溶液达到合成三聚磷酸二氢铝的要求。

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This paper demonstrated the impact on the environment today, an important factor is Education.

本文主要展示了当今影响环境的一个重要因素——教育。

Article 16 The power to interpret these Procedures shall remain with the Ministry of Agriculture and CAA.

第十六条本程序由农业部、国家认证认可监督管理委员会负责解释。

I am not quite sure if you can overcome the inertia.

我不确定你能否克服自己的惰性。