水溶液

Trisodium salt of N,N,N'-ethylenediamine triacetic acid was prepared by hydrolyzing 2-oxo-1, 4-piperazine diacetic acid(3-KP) in the strong base solution. Then it was combined with lauroyl chloride, hexadecanoyl chloride and benzoyl chloride respectively. N-lauroyl-ED3A and N-hexadecanoyl-ED3A were prepared in succsess. The molecular structure of N-lauroyl-ED3A was characterized by ~1HNMR and ~(13)CNMR. The molecular structure of N-hexadecanoyl-ED3A was characterized by 1HNMR.

将3-KP 在强碱性条件下水解，生成ED3ANa3 的水溶液，然后分别与月桂酰氯、棕榈酰氯和苯甲酰氯反应，成功制得N—月桂酰基ED3A 和N—棕榈酰基ED3A，并用~1HNMR 和~(13)CNMR 对N—月桂酰基ED3A 的分子结构进行了表征，用1HNMR 对N—棕榈酰基ED3A 的分子结构进行了表征。

The self-assembled supramolecular nanostmctures of a bolaamphiphilic diacid, 1, 20-octadecanedicarboxylic acid, on the subphase containing various metal ions have been investigated.

研究了ODA在含有Ag〓，Zn〓，Cd〓和Eu〓等金属阳离子的亚相水溶液表面上的铺展行为。

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是，超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解，这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

Experiments were carried out by using the membrane sheet made of cellulose ester as a permeable barrier to dialyze urea from the aqueous solution. Theoretical predictions are in good agreement with the experimental results.

而本实验是以纤维酯为材质的薄膜做为阻隔膜将尿素由单行程装置水溶液端透析到薄膜的另一端，而理论的预测值与实验的结果相当吻合。

After the click reaction of the SCL micelles and azide-terminus PNIPAM homopolymer, the novel PNIPAM-functionalized SCL micelles with pH-responsive cores and outer thermosensitive coronas were prepared, which was investigated act as excellent candidate of nanosized drug delivery vehicles. Finally, two types of novel shell cross-linked micelles in aqueous solution were prepared from these remarkable PMEO_2MA-b-P(DMA-co-QDMA)-b-PDEA triblock copolymers by cross-linking the inner P(DMA-co-QDMA) shell of micelles upon the addition of diazide tetra derivative in the presence of copper catalyst using click chemistry.

另外，还可以使用溴丙炔对ATRP聚合出的PMEO_2MA-b-PDMA-b-PDEA三嵌段的中间PDMA嵌段进行部分季胺化，这样可以利用两端叠氮化的四甘醇来交联由PMEO_2MA-b-PDMA-b-PDEA在不同条件下形成的两种分别以PMEO_2MA或PDEA为核的胶束，从而实现了从同一个聚合物直接在水溶液中得到两种内核不同敏感的壳交联胶束。

A novel method for determination of benzoyl peroxide with spectrophotometry was developed. Inclusion ratio of β cyclodextrin to dibenzoy peroxide and benzoic acid is obtained with spectrophotometry.The mechanism of the inclusion was studied,too. The results showed that β-CD react with dibenzoyl peroxide to form a 1:1 or 2:1 host-guest complex, with the apparent formation constants of 5.0× 10~2and 2.5× 10~4 , respectively.β-CD reacts with benzoic acid to form a 1:1 host-guest complex with the apparent formation constant of 6.9 × 10~2 after the dibenzoyl peroxide was reduced by hydroxyl ammonium chloride.

建立了用β环糊精测定过氧化苯甲酰的分光光度法，并测定了β环糊精与过氧化苯甲酰和苯甲酸的包结比，随着β-CD浓度的增大，可与BPO分别形成1：1或2：1的包容络合物，包结常数分别为5.0×10~2和2.5×10~4，与苯甲酸形成1：1的包容络合物，包结常数为6.9×10~2；由于包结物的吸光度值比过氧化苯甲酰的吸光度值大大增加，建立了一种当β-CD存在下，在水溶液中测定过氧化苯甲酰的方法。

The cage effect of Gn potassium aqueous solution calculated by theα-cleavage photoreaction product distribution of substituted dibenzyl ketone was 14%, 18%, 22% and 42% for generations 1-4, respectively, which indicates that G4 takes a more close spherical shape with strong confine ability.

研究结果表明，羧基为末端基团的芳醚树枝形聚合物Gn (n = 1-4)钾盐水溶液笼效应随代数增加而增大，从G1到G4，笼效应分别为14%、18%、22%和42%，树枝形聚合物3代到4代从开放结构变为近乎球形的封闭结构的显著变化使G4表现出明显高于其他三代的笼效应。

Through the study on the crystallization process of aqueous solution of amino acids,dicarboxylic acids and complexes by streaming potential method,that will helps to further study on the crystallization or the precipitation process of amino acid complexes and the electrical characteristics on the solid-liquid interface.

通过流动电位法对水溶液体系中氨基酸、二元羧酸和配合物结晶过程的研究，有助于进一步研究氨基酸配合物结晶和沉淀过程相界面的动电现象。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

A kind of intramolecular charge transfer compound——3 methoxy 4' N,N dimethylamino flavone derivateves was used to detect collagen association in aqueous solution.

利用一种分子内电荷转移化合物3-甲氧基-4'N，N-二甲氨基黄酮作为荧光探针，研究了胶原蛋白在水溶液中的聚集状态。

This paper analyzes the compound attractor structure of a new three-dimensional autonomous chaotic system.

分析了一种新的三维自治混沌系统吸引子的复合结构。

ON shut rivals out of their transmission systems and shy away from reinvesting their profits in network improvements.

ON将竞争者挡在了其输送体系之后，并不愿将其收益再投资于网络改建工作。