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The influence of acidity and concentration on fluorescence and absorption spectra were investigated. Using quinine bisulphate as a reference, fluorescence quantum yield of aesculetin in the condition of pH=9.32 was determined to be 0.13 at excitation wavelength 365nm.

考察了酸度与浓度对其荧光性质和吸光性质的影响,以硫酸奎宁为参比,测得秦皮乙素水溶液在pH=9.32,激发波长365nm条件下的荧光量子产率为0.13。

The influence of acidity on fluorescence and absorption spectra were investigated. Using quinine bisulphate as a reference, fluorescence quantum yield of aesculin in the condition of pH=4.96 was determined to be 0.76 at excitation wavelength 335nm, and in pH=9.40 was 0.80 at 375nm.

探讨了酸度与浓度对其荧光和吸光性质的影响,以硫酸奎宁为参比,测得秦皮甲素水溶液的两种强荧光型体的荧光量子产率,在pH=4.96,激发波长335nm条件下,荧光量子产率为0.76;在pH=9.40,激发波长375nm条件下,荧光量子产率为0.80。

After nucleosides were extracted from urine on phenyl boronic acid affinity chromatography, the analysis was performed on a column (4.6 mm i.d.X250 mm, 5 μm) at 22 ℃ using a lineargradient elution comprising 25 mmol/L KH2PO4 solution (pH 4.55) and 60% methanol in water with UV detection at 260 nm.

通过苯基硼酸亲和色谱法提取尿中核苷,在色谱柱(4.6 mm i.d.X250 mm, 5 μm)上以25 mmol/L磷酸二氢钾溶液(pH 4.55)和60%的甲醇水溶液作为流动相进行二元梯度淋洗,于22 ℃下进行反相色谱分离,260 nm处紫外检测。

On the condition of using fatty acids of rapeseed oil as raw material,85% acetic acid as solvent, pelargonic acid as recrystalization solvent, this paper prepared azelaic acid and brassylic acid by ozonolysis ,oxidation decomposition ,recrystallization etc.

以蓖麻油酸为原料、85%醋酸水溶液为溶剂,经臭氧化、氧化分解、沸水萃取等过程制备壬二酸的最佳反应条件为:m:m(85%醋酸)=1:4,臭氧化温度20-25℃;氧化分解温度90-95℃,催化剂醋酸锰/醋酸铜用量为原料蓖麻油酸质量的0.09%,氧化分解4h,壬二酸的收率为62.5%。

The results show that in the presence of NaHCO3 as base and DMF-H2O (volume ratio 2∶1) as solvent, the complex could catalyze not only iodobenzene but also non-activated bromobenzene quantitatively at 90 ℃ without the inert gas protection, and furthermore the catalyst could be recovered and reused more than eight times.

结果表明,在没有惰性气体保护的情况下,以NaHCO3作碱,以DMF水溶液(体积比为2∶1)作溶剂,在90 ℃时,该配合物不仅对活性较高的碘代苯能够定量地催化,对未活化的溴代苯也能定量地催化,并且催化剂能够回收再利用8次以上。

Color reaction was performed in organic solution-salt solution biphasic system. The organic solution was 1,2-Dichloroethane-Isoamyl alcohol mixture (V/V=96:4) added Bromophenol blue (per 100 mL added 0.05 g). The salt solution was 55%K2HPO4 aqueous solution added Na3CO3 (per 100 mL added 14 g), under the temperature of color reaction between 12℃ to 25℃.

显色反应在有机溶液-盐溶液两相体系中进行,有机溶液为每100 mL 1,2-二氯乙烷-异戊醇混合溶液(体积比96:4)加入0.05 g溴酚蓝,12~25℃显色反应条件下,盐溶液为每100 mL 55%K2 HPO4水溶液加入14 g Na2CO3。

The determination of MD1 concentration in aqueous solution by using bromthymol blue indicator method is described and a linear relationship is observed between absorbance and solution concentration ranged in 10-300 mg/L.

介绍了溴百里酚蓝为指示剂测定水溶液中MD 1质量浓度的方法,在10~300mg/L范围内溶液吸光度与浓度之间有良好的线性关系。

Results: The best formulation of Picamilon sodium dispersible tablets was composed of Picamilon sodium 50mg, brushite 120mg, Ldisplace-hydroxypropyl cellulose and sodium carboxymethyl starch 16mg and 2% polyvidone k30 queous solution quantity sufficient.

结果:优化处方组成:主药匹卡米隆50mg、磷酸氢钙120mg、崩解剂羧甲基淀粉钠和低取代羟丙基纤维素分别为16mg,粘合剂2%聚维酮K30水溶液适量。

Chelator-assisted hydrothermal method for growing ZnO nanopricks ZnO nanopricks were formed while 0.3 mol/L diaminoethane, 3 mol/L butylamine and 0.25 mol/L EDTA were used as chalators to react with zinc foil at 100℃ for 12 h.

络合物水解法制备ZnO球形颗粒利用酒石酸锌的水解反应,在水溶液中制备了由超细颗粒组装的ZnO球形颗粒,XRD、HRTEM检测结果表明颗粒为纤锌矿ZnO多晶结构,在溶液中添加乙二醇,产物的尺寸和分散性得到了改善。

Experiment showed that the hydrolysis product of chloroisopentene in sodium hydroxide solution was mixture of isopentenol and methyl butenol , which indicated that displacement reaction of chloroisopentene was accompanied by isomerization reaction of carbonium ion.

在以氢氧化钠水溶液进行氯代异戊烯水解时发现,水解产物为异戊烯醇和甲基丁烯醇的混合物,这说明氯代异戊烯在进行取代反应的同时,伴有正碳离子的异构化反应,由此开发了一条全新的由氯代异戊烯生产甲基丁烯醇和异戊烯醇的新的工艺路线。

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