水成作用

Hydrocyanic acid and water proceed via a five-centred transition states then transformed by its exterior hydrogen-bond; The results show that the activation energy of the isomerizing reaction in the aqueous phase is lower than that in the gas phase. It is likely that the hydrogen bonds formed in the complexes and the solvent effect play an important role.

计算结果表明，在水相中异构化过程的活化能比在气相中低，无论在气相还是在水相中异氢氰酸通过水氢键转化成氢氰酸容易些，而氢氰酸由水氢键转化成异氢氰酸相对要困难些，分子间氢键和溶剂化效应在异构化反应过程中起到重要的作用。

We have successfully synthesized hydrocarbonbearing inclusions in carbonate at the temperature and pressure of 150 ℃ and 40 MPa, which are near the condition of natural reservoir underground 4 kmAll synthetic hydrocarbonbearing inclusions have been analyzed by microscope and microfluorescence and fourier transform infrared spectroscopyThe results show that the synthesized hydrocarbonbearing inclusions are very similar to those in real reservoirsOur experiments give us four important insights, including:(1) immiscibility of oil and water is the main reason for hydrocarbonbearing inclusions and aqueous inclusions distributed in different fractures;(2) rapid accumulation of oil and gas can be recorded by fluid inclusions;(3) the study of synthetic hydrocarbonbearing inclusions at the temperature and pressure of real reservoir will offer references and standards for the analysis of fluid inclusions in reservoirs;(4) experiment of synthetic hydrocarbonbearing inclusions is a good method for understanding the mechanism of oilwaterrocks interreaction in reservoirs.

文中报道在实际储层温压条件下(150 ℃，40 MPa，大约4 km深度)成功合成了碳酸盐岩烃类包裹体。通过对合成烃类包裹体的显微观察、荧光分析和傅里叶变换红外光谱分析，证实合成了烃类包裹体，且与真实储层中的包裹体具有相似特征，探讨了油水不混溶条件下的流体包裹体捕获机制。实验研究给出4点重要启示：(1)油水不混溶是造成烃类包裹体和水溶液包裹体分带的主要原因；(2)油气快速成藏过程可以被流体包裹体记录；(3)实际储层温压条件下，合成烃类包裹体实验研究有望为储层包裹体分析提供依据和标准；(4)人工合成烃类包裹体为研究含油气条件下储层水岩作用机理提供了一种有效手段。

Combined analysis of sedimentary environment,diagenesis and tectonic evolution has been applied to obtain the origin characteristics of low resistivity contrast pay.

通过建立低阻油层各种岩石物理成因与地质成因之间的关系，结合沉积环境、成岩作用、构造特征和成藏动力因素等综合分析低阻油层的发育特征，提出了5种具有典型意义的低阻油层有利勘探目标区带：（1）小规模、低幅度构造发育区，（2）天然水淹等构造运动活跃、流体非均质严重的区带，（3）岩性细、粘土矿物组合中蒙脱石含量高的区带，（4）弱水动力环境下砂泥岩薄互层发育区，（5）与火山碎屑沉积演化有关的黄铁矿等导电性矿物富集区。

Base on above studies, some conclusions were obtained as follows:(1) ore-forming background of the studied ferromanganese crusts are mainly controlled by intensity of Antarctic Bottom Waters and variations of material source;(2) it is confirmed that the ferromanganese crusts are mainly hydrogenetic and their composition are affected by volcanic and continental material simultaneously; there are no obvious phosphatization reconstruction and element reaction occurred in them, so they have important paleoceanological significance;(3) from researches on element occurrence modes in the new-type ferromanganese crusts and the lying sediments, it is proposed that there is no great biological affection on the crusts formation and their composition mainly came from the adsorptive action of the ferromanganese oxides in them;(4) two major types of ore-controlling factors are identified through compilation of ore-controlling factors, which are geological and oceanic factors;(5) considering the long-term variation trends of the crusts composition, combing the U-series and 10Be isotope dating results, it is proposed that the ore-forming processes of ferromanganese crusts in the studied areas can be divided into three major stages (5.6~2.8 Ma, 2.8~2.7 Ma and since 2.7 Ma), and then the activities of AABW since the Late Miocene, changes of input flux coming from volcanic and continental material are confirmed.

通过研究，得出如下结论：(1)研究区铁锰结壳的成矿背景主要受控于南极底流强弱及物源供给的变化；(2)证实铁锰结壳主要为水成成因，同时其物质组成也受一定程度的火山和陆源物质的影响；结壳自形成以来没有遭受到明显的磷酸盐化等成岩后期改造和元素再迁移，具有重要的古海洋学意义；(3)通过新型铁锰结壳及下伏沉积物元素赋存状态的研究，认为生物作用对研究区结壳的形成并没有很大的直接影响，其物质成分主要来自于结壳中铁锰氧化物的吸附作用；(4)在控矿要素的研究中，归纳出了地质与海洋两大类结壳控矿要素；(5)根据结壳成分长周期变化趋势，结合铀系和10Be测年结果，将研究区结壳的形成过程划分为三个主要阶段(5.6~2.8 Ma，2.8~2.7 Ma和2.7 Ma以来)，并确定了晚中新世以来研究区南极底流的活动情况、火山和大陆来源物质输入量的变化。

Through the experiments on hydration of AH in the following sulphate（Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4）, dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程，以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究，说明复盐理论不正确；CaSO_4在（Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4）溶液中水化，水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化，与激发剂阳离子Z/R值大小无关，阳离子的Z/R参数影响水化率的规律并不存在； 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行，CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度，CaSO_4·2H_2O获得结晶的驱动力，可溶性硫酸盐起到形成晶核的作用：水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相，作为异质微粒使母相中存在不均匀性，这些不均匀性有效地降低成核时的表面能位垒，使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成，因此这些物质起成核催化剂作用。

On the other hand, Cu, Co and Ni are all present in manganese phase in the hydrogenic nodules.

这些过渡金属元素在成岩作用形成的结核中的存在与铁锰结核中锰矿物和铁的氧化物、氢氧化物的晶体化学特征密切相关，而在水成作用形成的铁锰结核中的富集与锰矿物和铁的氧化物、氢氧化物的晶体化学特征关系不大。

Through authority's test, after water stored in energy mug, it can reach 45.79 Hz but under the standard of 50Hz.(50~100 Hz is subset water; Over 100 Hz is big hydrone group water); It can also change acid, alkalescence water into alkaline water. Moreover, Biologic activity function energy sheets have very good function of adsorption and degradation, which will help to improve the taste of drinks and cleanse water quality.

经权威部门测试，水经能量杯盛装之后，半高宽达到45.79Hz，低于50Hz的标准（50~100Hz为小分子团水，大于100Hz为大分子团水）；能将酸、碱性水转变成弱碱性水，而且生物活性功能能量片有很好的吸附和降解功能，对改善饮水的口感，净化水质起到良好作用。

The multiphase tectonic activities above clearly controlled the move and gather of salifying brine, the strongth of salt-forming and the deposition of salt-bearing strata. With the pass of time, the salt-bearing strata thickened gradually from northwest to east and southeast, and the distribution of the thickness trended towards complicated; the measurement of the halite deposition extended towards east too; in the early Palaeogene and the Neogene, strong multiphase tectonic activity was a disadvantage to salt-forming, but in the middle and late Palaeogene, weak multiphase tectonic activity, which resulted in slow and sustained subsidence of the basin, was greatly advantaged to it, especially to potash-forming.

古近纪和新近纪成盐卤水的迁移和聚集、成盐作用的强弱以及整个含盐系的沉积发育明显受到上述构造活动的控制：含盐系的厚度随时间由北西向东、向南逐渐增厚，且厚度分布逐渐趋于复杂化；石盐岩的沉积规模和范围也逐渐向东扩大；古近纪早期和新近纪强烈的构造活动对于成盐作用而言是一种干扰因素，而古近纪中、晚期相对较弱、导致盆地缓慢持续沉降的构造活动对成盐，尤其对成钾作用则极为有利。

In order to investigate how randomness of concrete had effects on structural responses by means of experiments,authors carried out a pseudo static experiment on the same four-story 1∶3 scaled model of short-leg shear wall structure.

0引言混凝土是一种由水泥、粗骨料、细骨料及各种外加掺和料混合在一起，并在水的作用下发生一定化学反应集结而成的多相复合材料。

The new ideas from this paper: using mechanics principle study of soil, create a practical test to prove that it could change the physical mechanics character of base soil completely, reducing distortion, improving strength, and eliminating wet or sinking of base soil by seal extrusion during hole formation process at certain replacement rate; it could strengthen the loessial soil base to high bearing capacity to standard value of 300 to 400kPa through seal extrusion to hole formation technology together with rammed cement soil pile. Some value of the parameters adopted by bearing capacity calculation of the composite base of rammed cement soil pile with seal extrusion to hole formation exceeded the criteria of 'Technical Regulation on Building Ground Treatment'.(JGJ79-2002) This technology meet the design requirements and save investment.

本课题的创新点：1 利用土力学原理进行研究及理论推导，并经实践：证明了在置换率为某一定值的情况下，在成孔过程中通过挤密作用可以从根本上改变地基土的物理力学性质，使地基土的变形减小，强度提高，湿陷性消除；2 挤密成孔工艺与夯实水泥土桩的组合，可使低强度的湿陷性黄土地基变成高强度的复合地基，其承载力特征值可达 300~400kPa；3 挤密成孔法夯实水泥土桩复合地基承载力计算所采用的有关参数取值范围超出了《建筑地基处理技术规范》JGJ79-2002 中的有关规定；4 在节省投资的前提下，解决了地基高承载力、低变形及黄土湿陷性问题，达到了设计要求。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。