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It is a highly effective and multifunctional waterborne intumescing fire-retardant coatings for wood structure,and accords with the way of the development of the coatings industry, and possess the good foreground of development and application.

实验表明:以硅丙乳液为基料的木结构水性膨胀型防火涂料具有良好的防火性能、优良的理化性能、生产工艺简单、施工方便和装饰效果较好的优点,符合防火涂料工业发展方向的多功能高效的水性膨胀型防火涂料,具有很好的开发应用前景。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15~4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1~2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓~IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯,甲基丙烯酸-β-羟乙酯,丙烯酸及苯乙烯合成厂丙烯酸共聚树脂,并与含-NCO端基的聚氨酯丙烯酸酯接枝反应,经水性化后,得到两个系列(Acr-g-TPU-PETA和Acr-g-PPU-PETA)各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系,粘度与水相近,为牛顿流体,固含量30%左右。光固化前干燥涂膜的玻璃化转变温度在-15℃~4℃之间,有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料,接枝样dTG峰明显宽化,表明接枝样中链段之间的相互作刚有多重性,丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50%~30%者相对较好,且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1~2级,冲击强度为50kg·cm,柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团,碳—碳双键密度太低,光固化膜交联点太少,硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中,不出现色斑,光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜,光泽度及耐丁酮溶剂性能均有所提高,不会诱导铁基生锈,钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色,对光固化涂层的颜色干扰较小,为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出,且对所附着的铁基有诱导锈蚀作用。

Water-based ink business card printing and membership card making products completely post-drying, has a strong water resistance and scuffing.

水性墨制卡和会员卡制作品彻底干燥后,具有很强的抗水性和耐摩擦性。

The results show sheafing strength of wood glued-product produced by adhesive prepared with the optimal formulation of six starch-based API wood adhesive can completely meet requirement of JIS K6806 and each property indices of adhesive satisfy demand for the practical process technology.

其次,以复合变性玉米淀粉、乙二酸、聚乙烯醇、P-MDI为影响因素,按照日本JIS K6806标准中关于水性高分子-异氰酸酯木材胶粘剂胶接木材时的不同耐水性要求,通过正交试验,分别优化出Ⅰ型、Ⅱ型中Ⅰ、Ⅱ类的常态胶接、热水浸渍、反复煮沸胶接强度的六种淀粉基API的配方,并在对实验结果进行了验证性试验的基础上,进行了工业化生产试验。

Two-component waterborne polyurethane paint composed of acrylic dispersion and hydrophilically-modified polyisocyanate has fast dry time, good adhesion, flexibility, impact resistance, but poor water and chemical-resistance. The dry time becomes shorter with the increase of glass transition temperature and the decrease of acid value; the gloss of the film decreases with the increases of hydroxyl value, acid value and Tg of emulsion polymer; higher Tg polymer leads to harder film.

将制得的丙烯酸分散体与亲水改性多异氰酸酯组分配制水性双组分聚氨酯涂料,发现漆膜表干和实干比较快,干燥时间随玻璃化温度升高而缩短,随酸值的增加而增加;附着力、柔韧性和冲击强度比较好;光泽随分散体羟值、酸值的增加和玻璃化温度升高而降低;硬度随玻璃化温度升高而升高;较高的酸值使涂料的耐化学品性和耐水性较差,羟值在100mgKOH/g时较好,而酸值应尽可能低。

In this paper,the capabilities and demands of water-based coating used for tipping paper are analyzed.

对水松纸涂层专用水性涂料的性能要求和试验原理进行了分析,并通过大量探索性实验和正交实验对水松纸涂层专用水性涂料的性能进行优化,得出了性能比较优异的涂料。

The General requirements for water-based inks, the following points are confecting corrugated business card printing and membership card when you check to water-based ink.

在具备了普通水性油墨的要求之外,以下几点是配制瓦楞纸制卡和会员卡制作用水性油墨时要重点考虑的。

In this study, the experimental work heavy metals removal from aqueous solution by floating macrophytes could divide into two parts. In one set of the experiments, plants were exposed to heavy metals solution.

本研究利用浮水性植物去除水中重金属可分为两个部份;一为盆栽试验乃利用浮水性植物以栽种方式去除水中重金属的实验。

In order to study the preparation, the characterization and the performance on bond, ultraviolet curable water-borne polyurethane resin and electrorheological systems of waterborne polyurethane composites, the structure-property relationships of polyurethane ionomers and their nanocomposites were studied carefully by difference modified measurements.

本文研究了水性聚氨酯基纳米复合物的制备、表征及在粘合剂、光固化树脂以及在电流变液领域的应用,研究对比了不同改性方法制备的水性聚氨酯基复合物的不同性质。

Organics which could be volatilised easily or difficultly decreased fast at the early days, then decreased slow, but the organics which can volatilised easily decreased faster. Hydrophilic organics in the raw water decreased , while hydrophobe organics incresed. 4 Stainless steel and acid-resistant keramics showed less effect on the water's qulity, while the fiber steel which had used for storage in the experiment showed great effect.

随着贮存时间的延长,水中4KD~10KD所占比例升高,而4KD以下的有机物所占比例则下降;水中难吹脱性有机物与水中易吹脱性有机物都减少,且初期下降快后期下降慢,但易吹脱性有机物减少速度快于难吹脱性有机物;水中亲水性有机物所占比例下降,而疏水性有机物所占比例上升,发生了亲水性TOC向疏水性TOC转化。

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随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

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