水合离子

Solution chemistry and theoretical analysis indicated that the results of heavy metal ions adsorption upon brucite conformed with Langmuir and Freundlich isotherm. The conditional stability constants of surface complexation model of brucite adsorbing Cu〓 and Pb〓 were deduced.

通过水镁石吸附重金属离子的溶液化学和理论分析表明，其吸附结果符合Langmuir和Freundlich吸附等温式，并计算出水镁石吸附Cu〓和pb〓的表面络合条件稳定常数。

Quantitative analysis on the EXAFS spectra showed that Zn was adsorbed onto the solid surface in form of octahedral hydrated Zn ions, which were linked to the octahedral Mn06 of manganite by sharing oxygen atoms, with an average bond length R(subscript Zn-O)=(2.01±0.01)×10^(-10) m.

EXAFS结果表明，Zn主要是通过共用水合Zn离子的O原子及水锰矿表面上的O原子形成Zn-0键，从而结合到水锰矿固体表面上，其平均Zn-O原子间距为(2.01±0.01)×10^(-10)m。

Therefore, partial least square regression was conducted to distinguish these possible factors and to evaluate their relative importance.

上层土壤中，铝主要来源于有机键合铝，土壤水离子强度是造成铝浓度差异的主导因素。

Methods In the presence of sodium nitrate the ammonium thiocyanate ,malachite green and Co can form water-insoluble ion-association complexes.

方法在少量NaNO3存在下，向体系中加入硫氢酸铵和孔雀石绿，使其与Co形成不溶于水的三元离子缔合物浮于盐水相上。

The oil-displacing agents for crosslinked polymer oil-displacing system are mainly as follows:the polymer containing monomers with heat resistance and salt tolerance ,zwitterion polymer,hydrophobically associating water-soluble polymer,polymer complex system,and comb polymer.

用于交联聚合物驱油体系的驱油剂主要有含耐温抗盐单体的聚合物、两性离子聚合物、疏水缔合水溶性聚合物、聚合物复合体系和梳形聚合物。

The well-documented chelating properties of bipyridine and the sensitivity of the optical properties of AuNPs have been employed to detect low concentration of metal ions in water.

因为联吡啶具有好的钳合能力，加上金奈米粒子的灵敏的光学性质，所以可以用来侦测水中低浓度的金属离子。

In part 2, a colorimetric fluoride ion sensing in aqueous solution was investigated based on competitive-binding mechanism.

其次，研究了竞争络合的机理在水相氟离子显色传感研究中的应用。

In 0.015 mol/L NaOH medium, AuCl4(superscript -)reacted with hexadecyl trimethyl ammonium bromide, forming water soluble CTMAB-AuCl4 complex that exhibited a weak absorption peak at 400 nm. In the presence of hydrazine, the reaction produced orange-red nanogold particle and exhibited a surface plasma resonance absorption peak at 520 nm.

在0.015mol/LNaOH介质中，氯金酸根离子AuCl(上标-下标 4与阳离子表面活性剂十六烷基三甲基溴化铵反应生成水溶性的CTMAB-AuCl4缔合物，在400nm处产生一个很弱的吸收峰，当有肼存在时，反应生成橙红色的金纳米粒子，在520nm处出现一个表面等离子体共振吸收峰，从而可实现废水中微量肼的分光光度测定。

Based on the deterioration mechanism of corrosive medium, a lot of polymer such as ternary-polymer, adding-felt addition, hydrophobe and polypropylene fiber were added to enhance the performance of anti-corrosion, anti-penetration, conglutination and anti-cracking of original cementious material. The microstrure of cementious material was changed from the simplex hydration product of cement to the superposition structure of the hydrolysate of polymer and the hydration product of cement. A lot of the corrosive ions were prevented from the interior of concrete by this stable structure. The results of tryout indicated that the mending material has the good effect at the corrosion form of corrosive medium.

根据介质腐蚀形式的劣化机理，该文以提高修补材料耐腐蚀性能、抗渗透性能、粘结性能和抗裂性能为出发点，采用添加有机硅改性三元共聚物、增粘剂、孔隙憎水剂等多种聚合物和聚丙烯纤维对原水泥基材料进行改性，使得修补材料的内部微观结构从单纯的水泥水化产物转变成聚合物和水泥水化产物叠合的空间网状结构，这种稳定的结构能有效抵抗各种介质离子的侵蚀，在实际工程上的试用也显示出新修补材料良好的使用效果。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新