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The results show that 5% nucleating agent,twelve-hydrated disodium hydrogen phosphate,could reduce the supercooling degree of acetate hydroxide trihydrate to some extent but the supercooling degree was still large.However,the supercooling degree of sodium acetate trihydrate could decrease clearly by adding 3% thickener gelatin and 5% twelve-hydrated disodium hydrogen phosphate.

实验结果表明,质量百分比为5%的成核剂十二水磷酸氢二钠能一定程度上抑制无机水合盐三水醋酸钠的过冷度,但其过冷度仍然较大;使用质量百分比5%的十二水磷酸氢二钠和质量百分比3%的增稠剂明胶做添加剂后,三水醋酸钠的过冷性能得到明显改善。

The synthesis methods of dibutyl succinate catalyzed by p-toluene sulfonic acid, amino sulfonic acid,strongly acidic cationic exchange resin, ferric chloride hexahydrate, stannic chloride pentahydrate, copper sulfate , ammonium ferric sulfate dodecahydrate, titanium sulfate, sodium bisulfate monohydrate,and solid super acid et al were reviewed.

本文评述了对甲苯磺酸、氨基磺酸、强酸性阳离子交换树脂、六水三氯化铁、五水四氯化锡、十二水合硫酸铁铵、硫酸钛、一水硫酸氢钠和固体超强酸等催化剂催化合成丁二酸二丁酯的方法。

The tryptophan residues play important roles in DNA photoreactivation catalyzed by CPD photolyases. We have investigated the action mechanism concerning Trp in DNA photoreactivation, and obtained the results as follows: 1 We proposed a mechanism of photosensitized splitting of CPDs by Trp and Trp-containing peptides. 2 Quantum yields of splitting of the model compounds that a Trp linked covalently a CPD were obtained under 290 nm light in various solvents, these values changing with solvent, range from 0.01 to 0.5. 3 Utilizing pulse radiolysis technique, splitting processes were observed in aqueous solution of the CPDs with hydrated electron and some oxidative species (such as hydroxyl radical, bromic radical and azide radical), and obtained their rate constants. In the case of interaction between CPD and hydrated electron, splitting of the CPD anion, and pyrimidine anion transfer an electron to FAD or Rf, were observed. The process rate was slower one order more than that in photolyase. Minor, but highly mutagenic UV-light-induced lesions are (6-4) photoproducts, which are repaired by (6-4) photolyases. These enzymes, discovered in 1993, are not well characterized and their mechanism is still under investigation.

我们研究它的作用机理,获得以下结果:1)建立了色氨酸及其肽对嘧啶二聚体光敏化裂解的直接修复作用机理模型;2)获得了色氨酸共价键连接于嘧啶二聚体的化合物在多种溶剂中290nm光辐照裂解的量子效率,其值随溶剂而变化,范围在0.01-0.5;3)运用脉冲辐解观察到嘧啶二聚体与水合电子和一些氧化性的自由基作用裂解过程,得到相应速率常数;对二聚体与水合电子作用发生裂解以及向FAD返还电子的过程进行了体外模拟;4)(6-4)光解酶的作用机理中一个关键假定是氧杂环丁烷中间体在接受电子后能自发裂解,恢复二嘧啶的结构。

Experimental results showed that the relative average error of the proposed method, the hydrazine hydrate gravimetry and the ammonium chloroplatinate gravimetry is -0.14%~+0.13%,-0.21%~+0.21% and -0.13%~+0.14%, respectively, and the relative standard deviation of three methods is 0.05%~0.08%, 0.11%~0.14% and 0.08%~0.09%, respectively, for Pt content from 37% to 65%. Therefore, the accuracy and precision of the proposed method are almost the same with hydrazine hydrate gravimetry, and are a little better than ammonium chloroplatinate gravimetry. But it is rapid, economic, secure, easy to operate and environmental friendly.

结果表明:测定37%~65%的Pt含量,本法、氯铂酸氨重量法、水合肼还原重量法的相对平均误差分别为-0.14%~+0.13%、-0.21%~+0.21%、-0.13%~+0.14%,相对标准偏差分别为0.05%~0.08%、0.11%~0.14%、0.08%~0.09%,故本法的准确度和精密度与水合肼还原重量法的基本一致,较氯铂酸氨重量法的略好;但本法消解快速、节能、安全,操作简便,对环境污染程度小,适宜推广运用。

CoAPO-5 molecular sieve was hydrothermally synthesized using pseudo-boebmite, phosphoric acid (85%), tetrahydrate cobaltous acetate as raw material and N, N-diehtyl-ethanolamine as tern- plating agent.

以拟薄水铝石、质量分数85%的正磷酸、四水合醋酸钻为原料,N, N-二乙基乙醇胺为模板剂,水热法合成了CoAPO-5分子筛。

Therefore, the condition of formation of calcium hydrosilicate was tested in this investigation.

本文研究了水合硅酸钙的形成条件,表明随着溶液苛性比的增高、碱浓度的降低、温度的升高等,有利于水合硅酸钙的形成。

Based on this model, the pH value and the quantity of water are choused as the control variables and it is also found the influence of pH is bigger.

通过对模型的分析,发现可用化工易控的溶液的pH值和水量来准确控制水合过程,其中溶液的pH值对水合过程的影响更大。

Further, the method for producing acrylamide of the present invention is characterized by hydrating acrylonitrile having a concentration of acrolein of 1 ppm or less by a microbial cell containing a nitrile hydratase or a processed product of the microbial cell in an aqueous medium.; Furthermore, the method for producing an acrylamide-based polymer of the present invention is characterized by homopolymerizing the acrylamide or by copolymerizing the acrylamide and at least one unsaturated monomer copolymerizable with the acrylamide.

本发明的制备丙烯酰胺的方法的特征在于,用含有腈水合酶的微生物的菌体或该菌体处理物使丙烯醛浓度为1ppm以下的丙烯腈在水性介质中进行水合反应。本发明的制备丙烯酰胺类聚合物的方法的特征在于均聚所述丙烯酰胺,或共聚所述丙烯酰胺和能与丙烯酰胺共聚的至少一种不饱和单体。

Research results indicate that X FLOUR has notable effects of fluidizing and water reducing.

研究结果表明:X粉具有显著的流化与减水效应,其流化与减水效果与目前市售掺合料的最高水平相当,明显好于硅灰。X粉与硅灰复合后,仍具有流化效应。X粉产生流化效应的机理,一是增加水泥浆悬浮体系的分散性;二是通过填充效应减少填隙水,增加了用于混凝土流动性的水量;三是增加混凝土混合料的浆体体积。X粉流化与减水效应的发挥,以与高效减水剂双掺为前提。

The thermodynamic calculation results indicated that the formation of calcium aluminate hydrate from aluminate solution with CaO is easier than that with Ca2, and the value of αk is great at low temperature; the temperature rise leads to the reduction of stability of calcium aluminate hydrate in the aluminate solution, and it can be decomposed at high temperature, which can both substitute for Ca2 and recover alumina in the process of Bayer.

热力学计算结果表明,氧化钙较氢氧化钙更容易使铝酸钠溶液中的铝酸根离子转化为水合铝酸钙,使铝酸钠溶液的平衡苛性比能达到很高的值;水合铝酸钙随着温度的升高,稳定性降低,因而能在拜尔法高温溶出过程中分解以代替石灰,并回收其中的氧化铝。

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