水化合物

WO3, an interlayer compound prepared by J. W. Johnson (1981) using yellow tungstic oxide hydrate. Suspension of white powdery tungstic acid in anhydrous pyridine yields on standing for 2 wk whiteHW4O13.3H2O. IR and DTA studies revealed the connection between that pyridine polytungstate and white powdery tungstic acid (microcryst.), whose composition may thereby be assigned as H2W4O13.nH2O.

WO3。粉状白钨酸在无水吡啶中放置两周后可得到另一种化学式为(C5H5NH)HW4O13.3H2O的吡啶化合物，经IR和DTA研究可初步说明该化合物与粉状白钨酸之间的联系，并因此推测白钨酸的组成可能为H2W4O13.nH2O。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体，合成了七{2，6-二-O-[3-(1，3-二羟基丙氨酸)]}-β-环糊精，再用醋酸酐将其乙酰化，得到了一种淡黄色粘稠液体，合成了一种新型的环糊精衍生物；以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物，再将其烷基化和酰基化，合成了β-环糊精聚合物的不同衍生物，用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上，通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究，结果表明所合成的β-环糊精衍生物对各类化合物，特别是对位置异构体和对映异构体具有较好的分离效果，显示了很强的立体选择性。

Methods by using a broad pH range column(Gemini NX C18,4.6mm×150mm,5μm),basic mobile phase which was[H_2O-ammonia-glacial acetic acid] (96:3.6:0.4)-methanol,the related substances in etimicinsulfate were separated and detected by electrospray ionization and positive ion monitoring,the ESI ion source condition was following: temperature is 350℃,nebulizing pressure is 50 psi,dry gas flow is 10 L /min.some related substances in etimicinsulfate were identified by comparing the retention time in chromatography,~+ spectrum and MS~2 spectrum with reference substances\',the others which haven\'t reference substances were identified or speculated by analyzing their MS~2 fragmentation with the help of a rule summarized from the MS~2 fragmentation of gentamicin C1a,micronomicin and etimicin.Results nineteen related substances in etimicinsulfate were separated and detected.

方法利用宽pH范围的Gemini NX C18(4.6mm×150mm，5μm)色谱柱，在碱性条件下，以[水-氨水-冰醋酸(96：3.6：0.4)]-甲醇(70：30)为流动相，直接分离各组分；并用HPLC-ESI-MS~2检测样品中各组分，质谱条件：ESI离子源，离子源温度350□，雾化室压力50 psi，干燥气流速10 L/min，正离子检测方式；对有对照品的有关物质采用比对有关物质与对照品的色谱保留时间、准分子离子的质荷比及二级质谱方法进行鉴定，无对照品的有关物质，则是先通过解析庆大霉素Cla、小诺霉素、依替米星的二级质谱，对该类化合物的二级质谱裂解规律进行归纳，并以此推测未知新化合物进行结构，再用推测的结构对二级质谱进行解析，如所有的碎片离子均合理解释，表明推测合理。

The science team is trying to determine whether the water ice ever thaws enough to be available for biology and if carbon-containing chemicals and other raw materials for life are present.

这只科学团队尝试确定火星上的水冰是否曾经大量融化，从而能支持生物存在。同时，它还将寻找火星土中是否有以碳为基础的有机化合物，这些化合物是形成生命的&原材料&。

The impure carbon dioxide which can be obtained from any available source of carbon dioxide will typically contain as impurities sulfur compounds such as carbonyl sulfide, hydrogen sulfide, dimethyl sulfide, sulfur dioxide and mercaptans, hydrocarbon impurities such as aldehydes, alcohols, aromatics, propane, ethylene, and other impurities such as water, and carbon monoxide.

可由任何二氧化碳源得到的低纯度二氧化碳通常含有以下杂质：硫化合物，例如硫化羰、硫化氢、二甲硫、二氧化硫和硫醇；烃杂质，例如醛、醇、芳族化合物、丙烷、乙烯；以及其它杂质，例如水和一氧化碳。

A new quasi-oligosaccharide alpha-amylase inhibitor as alcaftadine compound is represented as the formula at right, wherein m is integer of 0-7, n is integer of 1-4 and q is integer of 0-3, The mixture and monomer of the alcaftadine compound are white amorphous powder which dissolves in water and DMSO easily, dissolves in methanol, alcohol and acetone slightly and not dissolves in other organic solvents.

一类新的拟低聚糖类α-淀粉酶抑制剂，阿卡他定系列化合物，具有如右通式的结构，其中，m为0～7的整数，n为1～4的整数，q为0～3的整数。所述通式所示的阿卡他定系列化合物的混合物和单体均为白色无定形粉末，易溶于水和DMSO，微溶于甲醇、乙醇和丙酮，不溶于其它有机溶剂。

The activation energy of B ring elementary reaction is between 16～20kJ/mol.

从IRC结果以及对过渡态结构的电子密度拓扑学分析结果可以确定，羟基自由基在反应过程之中抽取了黄酮类化合物A环上未参与分子内氢键结构的酚羟基上的氢原子形成水分子及稳定性更高的半醌式大环自由基，在整个过程之中羟基自由基从反应物一侧进攻并逐渐发生扭转，直至形成一个进平面结构的过渡态结构，这与上一章关于黄酮类化合物B环的研究结果基本一致。

Acids are chemical compounds that, in water solution, have a sharp taste, a corrosive action on metals, and the ability to turn certain blue vegetable dyes red.

酸是一种化合物，它在溶于水时具有强烈的气味和对金属的腐蚀性，并且能酸是一种化合物够使某些蓝色植物染料变红。

Two coordination polymers [Pb6(H2O)24]·3H2O(1)(H3cit=citric acid)and Pb(H2O)2(2)(tar=tartaric acid)were synthesized under hydrothermal conditions and characterized via IR,TG-DTA,C,H,N elemental analysis,XRD and single crystal X-ray diffraction analysis.

在水热条件下，合成了2个含柔性配体柠檬酸和酒石酸的二价铅配位聚合物[Pb6(H2O)24]。3H2O(1)(H3cit=citricacid)及Pb(H2O)2(2)(tar=tartaricacid)。用红外光谱、差热-热重、元素分析、粉末X射线衍射及单晶X射线衍射等手段对化合物进行了表征。化合物1属三斜晶系，P1空间群，a=0.97053(19)nm，b=0.9764(2)nm，c=1.0955(2)nm，α=109.016(3)°，β=98.380(3)°，γ=92.136(3)°，V=0.9671(3)nm3，Z=2，R1=0.0420，wR2=0.1049，GOF=1.064。

The Knoevenagel condensations of various carbonyl compounds with active methylene compounds were reported in water medium without adding any catalyst.

报道了水相中无催化剂下各种羰基化合物与活泼亚甲基化合物的Knoevenagel缩合反应。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐