水动力学

Another conclusion is that stability is better in accretion bank than in colluvial deposit bank.A comprehensive study has been made on the course of reservoir bank recession on the theory of fluvial and wave dynamic mechanics with a view of character of mountain land. Some appraise and rectifying suggestions for current methods are given by computing the scale of the bank recession in the area.

通过对河流水动力条件、水库波动动力学等几个方面并结合山区水库特点对水库岸坡的塌岸过程进行了系统的研究，并运用不同的方法对水库蓄水后的岸坡塌岸宽度进行了预测，从预测结果对不同的方法进行了评价，并对现有的方法和结果提出了修改建议。

On the basis of study on two projects:"10-DOF ultrasonic detection system for complex surfaces part" and "Ultrasonic water-logging automatic survey system for rods", this thesis studies the technologies of ultrasonic measurement, kinematic and dynamic modeling of 10-DOF ultrasonic system, real-time sensitivity auto-adjusting, integrated technology of ultrasonic measurement, surface construction and ultrasonic detection for complex surface parts and rods, thus improving the accuracy and efficiency of ultrasonic detection for parts of complex surfaces. Meanwhile, an auto-detection system for metal rods with rough surfaces and bad columniform accuracy is presented for the first time.

本文结合&10自由度复杂曲面超声检测系统&和&棒材水浸超声自动检测系统&两个项目的研究，主要开展了超声测量、检测机器人运动学和动力学建模、误差补偿、灵敏度自动补偿和曲面构件超声检测一体化技术和轴棒类构件超声检测一体化技术的研究工作，进一步提高了复杂型面构件超声检测的效率和精度，并首次针对表面粗糙、圆柱度较差的金属轴棒类构件开发出了高效率的自动化检测设备。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现；3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布；4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒；5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明：1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致；2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响；3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现； 3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布； 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒； 5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明： 1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致； 2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响； 3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Experimental results show that the water velocity is that when the BV ammonia concentration of 50 mg, L - 1 simulation wastewater and 98 mg, L - 1 point of industrial wastewater, penetrate respectively C/C0 = 0.3 and 0.15, water column of natural zeolite could handle respectively; 126 BV, 43 BV Modified zeolite column can handle respectively 157 BV, water, and with 46 BV hydraulic load increases, zeolite column can reduce water treatment, The experiment was found to leak after 8 NaCl solution with zeolite desorption regeneration effect is good, low cost, regeneration of zeolite adsorption capacity decrescent, Test through dynamics analysis found that zeolite column of ammonia nitrogen adsorption fast.

实验结果表明，进水速度为2.72 BV时，通入氨氮浓度为50 mg·L-1的模拟废水和98 mg·L-1的工业废水，此时穿透点分别为C/C0=0.3和0.15时，得到天然沸石柱可处理水量分别为126 BV、43 BV；改性后沸石柱可处理水量分别为157 BV、46 BV，且随水力负荷增大，沸石柱可处理水量减小；试验还发现对泄露后沸石用8%NaCl溶液解吸再生效果好，成本低，再生后的沸石吸附容量变小；试验通过动力学分析发现沸石柱吸附氨氮速度较快。

Keywords 1;5-naphthalene disulfonic acid;catalytic superitical water oxidation;degradation;kinetics

1； 5-萘二磺酸；催化超临界水氧化；降解；动力学

Surface coatings are open dynamitic systems in aquatic environments, in which various components could synthesize, accumulate, transform, and degradation.

生物膜在自然水体中是一个开放的动力学系统，水环境中的各种成分可以在生物膜上发生着合成、聚结、转化、降解等作用。

The changes of hemodynamics and extravascular lung water were observed.

注射内毒素制成感染性休克模型，分别使用不同液体进行复苏，使用脉波指示剂连续心排血量监测仪监测血流动力学指标和血管外肺水的变化。

Hot corrosion behavior of Na2SO_4 coated B-1900 alloy was studied in air at 827 and 750℃.Corrosion kinetics of the coated alloy was gravimetrically measured,and contents of water soluble ions in the reaction products were chemically analyzed.X-ray diffraction and EMP techniques were employed to determine the components and morphology of the corrosion product scale.

用涂 Na_2SO_4盐膜法研究高温合金 B-1900在827℃和750℃于空气中的热腐蚀行为，测定其腐蚀动力学曲线，用 X -射线衍射和电子探针元素面扫描方法分析腐蚀产物的相组成和成份，还对其中的水溶性离子进行化学定量分析。

Using the equipment set, the mean mass transfer migrate coefficient of aniline on the interface of kerosene/water and hendecane/water in the liquid membrane system has been determined.

本文建立了一套液－液界面传质速度测定的简易装置，用於笨胺－煤油－盐酸液膜体系中苯胺在油／水界面传质动力学的研究。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。