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Meanwhile, several physicochemical descriptors of xanthone molecules were calculated by using quantum chemistry method.

同时,运用量子化学计算了山酮分子的物化参数,并选择相互作用能、疏水常数(log P;其中P为正辛醇-水分配系数)和山酮分子总能量作为分析结构-电泳迁移定量关系的物化参数,用以研究分离机制及在毛细管区带电泳分离中山酮类化合物与β-CD 和磺酸化β-CD间的分子识别过程。

Meanwhile, several physicochemical descriptors of xanthone molecules were calculated by using quantum chemistry method. Among the physicochemical parameters, interaction energy, the logarithms of octanol-water partition coefficient and total energy of xanthone molecules were selected to investigate the separation mechanism and describe molecular recognition process between the xanthones and the CDs in CZE by means of quantitative structure-electromigration relationships.

同时,运用量子化学计算了山酮分子的物化参数,并选择相互作用能、疏水常数(log P;其中P为正辛醇-水分配系数)和山酮分子总能量作为分析结构-电泳迁移定量关系的物化参数,用以研究分离机制及在毛细管区带电泳分离中山酮类化合物与β-CD 和磺酸化β-CD间的分子识别过程。

In this paper the emulsion of polyacrylamide was synthesized in the polyglycol solutions, acryl amide and acrylic acid sodium was used as the monomer. In more detail, we investigated the effect of the concentration of the monomers, the ratio of monomer and PEG, the ratio of monomers, temperature, and emulsifier on the stability of the HPAM emulsion and the molecular weight of the HPAM.

为了提高聚丙烯酰胺相对分子质量,以丙烯酰胺与丙烯酸钠为原料,在聚乙二醇水溶液中合成了聚丙烯酰胺水包水乳液,考察了初始单体质量分数、共聚单体与聚乙二醇摩尔比、共聚单体摩尔比、聚合反应温度、乳化剂种类及其浓度对HPAM水包水乳液稳定性及相对分子质量的影响,所得共聚产物相对分子质量可达1.5×10^7。

The bathochromic shift was mainly due to the limitation of rotational movements of the dye. The rigidity of the silica surface restricted the freedom of the molecules. The lower polarity of microenvironment at the silica/water interface than that in aqueous environment should also make a contribution to the phenomenon.

通过对其本体、界面荧光光谱的分析,观察到R6G分子在亲水石英/水界面上出现5 nm红移,红移的原因主要是染料分子旋转运动受到限制,石英表面的刚性限制了分子的自由度,同时,石英/水界面更低的极性也对红移产生影响。

High magnetic filter: Use KLQ unique high magnetic field E + E, complexification of magnet technology, so that has been activated small molecules of water with stronger activity, more time to maintain the water activity that was called not reducing property small molecules of water , constant magnetic field of 10,000 gauss systems, instantaneous release of 9600-10300 gauss of magnetic field lines, so that an orderly arrangement of small molecules of water take of various trace elements needed by human body,delay cell senescence, activation of T cell growth, modulation of human blood fat, improve body microcirculation, reducing blood vessel wall fat deposition, improve immunity, have a preventive of hyperlipidemia and other kinds of chronic diseases, diabetes, high blood pressure.

高磁化过滤器:使用KLQ独特的E+E高磁场,复化磁钢技术,使已经活化的小分子团水活性更强,具有磁记忆能,更长时间维持水的活性被称为不还原的小分子团水,10000高斯生物恒磁场系统,瞬间释放9600-10300高斯的磁力线,使小分子团有序排列摄取人体所需的各种微量元素,延缓细胞衰老,激活T细胞生长,调节人体血脂,改善身体微循环,减少血管壁脂肪沉积,提高免疫能力,可保健肝胃具有预防高血脂高血压糖尿病等种慢性疾病。

Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.

全文共分8章:第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述;第二章研究了磷脂-桐酸脂质体的稳定性,通透能力及桐酸的聚合对这些性质的影响;磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体,〓的作用首先是使脂质体集聚然后使脂质体融合,并加速内包荧光物的释放;第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA,DDOL,研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响,聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性;第四章合成了两类氨基酸为极性基团的双亲分子,它们均可以在超声下形成稳定的脂质体结构;氨基酸基团可以在脂质体上进行缩聚反应,若聚合后脂质体表面仍有足够的亲水能力,则可得到稳定的多肽型脂质体;聚合后脂质体的相变温度降低,通透能力增加;第五章合成了四种亲水基团为单糖基的双亲分子GL-l,GL-2,GL-3, GL-4,研究了它们在水中的分散情况、集合体形态与分子结构的关系;在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高,阻止脂质体在低温放置时的集聚与融合;第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1,CL-2,CL-3;它们可以象胆固醇一样与磷脂混合形成稳定脂质体,胆甾环基团位于脂质体双分子层膜的中间;与胆固醇的作用相反,它们可以增加磷脂双分子层膜的流动性,降低混合脂质体的相变温度;三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关,比膜厚度短的分子影响最大。

Aimed at the study of Lauraceae system classification in domestic and overseas,genetic diversity and genetic variation between Cinnamomun micranthum Hayata natural populations and Ex-situ conservation poputations and relationship among Its Close Relative Species of Cinnamomum camphora Presl,Cinnamomum burmannii(C.G.etTh.Nee) Bl,Phoebe bournei Yang. Litsea subcoriacea Yang et P.H.Huan. Neolitsea aurata Koidz,Lindera communis Hemsl and Persea Americana Mill.were studied by inter-simple sequence repeats molecular marker.The research aimed at genetic variation between Cinnamomun micranthum Hayata populations,so that can offer the molecular theoretic and practical method for conservation and utilization of Cinnamomun micranthum Hayata populations.

针对目前国内外对樟科植物系统分类的研究现状,本研究采用ISSR分子标记技术对樟科沉水樟天然居群和迁地保护居群的遗传多样性进行研究,从分子水平上分析沉水樟种群的生态遗传及其遗传变异规律;同时利用ISSR分子标记技术比较沉水樟及其近缘种香樟、阴香、闽楠、桂北木姜子、新木姜子、香叶树、鳄梨在分子水平上的亲缘关系,揭示这些树种在樟科植物系统进化中的作用与地位,探讨沉水樟及其近缘种的遗传多样性及其分化格局,为樟科植物的系统分类提供分子水平的依据。

The flocculated decolorization of dyes has something to do with their structure.

染料分子的结构对其絮凝脱色的影响研究显示:从能量相互作用来看,染料分子中磺酸基个数越多,其与聚合物絮凝剂PAN-DCD的键合程度越高,染料的脱色率越大;从疏水相互作用来看,染料分子中疏水基团越多,其与PAN-DCD的相互作用越大,疏水基团的体积越大,染料的脱色效果越好。

The results of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L,there existed some stable hydrophobic regions,which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid,in the partially folded intermediate of Bacillus amyloliquefaciensα-amylase;with the denaturation concentration increasing,the stable hydrophobic regions disappered.the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed that using acrylamide as quenchers,with the protein denaturation extent increasing,the number of Trp that can be quenched increased untill all the Trp residues were quenched;Using potassium iodide as quenchers,with the maximum number(8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciensα-amylase molecule could be quenched by potassium iodide;with the denaturation concentration increasing,the number of Trp that can be quenched decreased to 5.the results of their protein electrophoreses and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciensα-amylase formed during the whole unfolding/refolding procedure of Bacillus amyloliquefaciensα-amylase induced by guanidine hydrochloride or urea.

ANS外源荧光探针结果表明:盐酸胍诱导的芽孢杆菌α-淀粉酶分子去折叠过程中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域;而随着芽孢杆菌α-淀粉酶分子在盐酸胍溶液中变性程度的加深,这一疏水区域逐步被瓦解。丙烯酰胺和碘化钾猝灭结果表明:在盐酸胍溶液中,随着芽孢杆菌α-淀粉酶分子变性程度的进一步加深,其分子内能够被丙烯酰胺接近的色氨酸残基逐渐增多,直至全部被猝灭。但位于芽孢杆菌α-淀粉酶分子表面的能够被碘化钾猝灭的色氨酸残基,在中间态芽孢杆菌α-淀粉酶分子中数目达到最大的8个,而随着其分子变性程度的进一步加深,反而减少至5个。

"On Earth, microorganisms thrive about 1.2 to 1.9 miles beneath the Witwatersrand basin of South Africa, where natural radioactivity splits water molecules into molecular hydrogen and oxygen," Mumma said.

&在地球上,活跃在南非Witwatersrand盆地下面1.2到1.9英里的微生物将水分子分解成氢和氧,&MUMMA说。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力