氰醇

In particular, when the Knoevenagel condensation of 2-hydroxybenzaldehyde was conducted with ethyl 2-cyanoacetate, 3-ethoxycarbonylcoumarin was obtained by simultaneous cyclization and alcoholysis of cyanide.

当反应底物为水杨醛与氰基乙酸乙酯的时候，产物为3-乙氧基羰基香豆素，这是水杨醛和氰基乙酸乙酯缩合关环，再发生氰基醇解的产物。

When the concentration of alcohol is same with the water, there is 77.89% consumed isocyanate reacted with water. When the concentration of water is 2 times as alcohol, more than 90% isocyanate reacted with water.

当体系中醇与水的浓度相同时，反应了的异氰酸酯基中有77.89%与水反应；当体系水的浓度是醇的2 倍以上时，将有90%以上的异氰酸酯基与水反应。

G. the perfumes. The wall forming materials were TDI (2, 4-toluene diisocyanate) or 80/20TDI, triphenyl methane triisocyanate and biphenyl methane-4, 4-diisocyanate , Poly vinyl alcohol was used as protective colloid and GPE2040 was used as the emulsifier.

壁材单体分别使用了2，4-甲苯二异氰酸酯、80／20-甲苯二异氰酸酯、三苯基甲烷-4，4′，4-三异氰酸酯和二苯甲烷-4，4′-二异氰酸酯；保护胶体是聚乙烯醇；乳化剂是聚醚2040；催化剂使用二月桂酸二丁基锡。

A polyurethane which is obtained from ingredients comprising a high-molecular polyol, an organic polyisocyanate, and a chain extender comprising a specific trifunctional isocyanurate compound having an aromatic hydroxyl group and/or a benzylic hydroxyl group, and which has a crosslinked structure due to the isocyanurate compound.

从包含高分子量多元醇、有机聚异氰酸酯和扩链剂的成分得到的聚氨酯，所述扩链剂包括含芳羟基和/或苄羟基的特定三官能团异氰脲酸酯化合物，并且其由于异氰脲酸酯化合物而具有交联结构。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法，其反应混合物包括：一种含至少85重量％的4，4′－二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分，一种多元醇组合物，其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量％之间的聚氧亚烷基多元醇，水，一种平均羟基当量为15至250之增链剂，以及视需要使用的交联剂，该硬性嵌段－含量（hardblock-content）大于45重量％。

A series of polyether based polyurethaneurea aqueous dispersions with well-defined hard segments were prepared by fractional steps with polyether polyol, 4,4'-diphenylmethane diisocyanate, dimethylolpropionic acid, 1,4-butanediol, isophorone diisocyanate and ethylenediamine.

以二苯基甲烷二异氰酸酯、二羟甲基丙酸、1，4-丁二醇、异佛尔酮二异氰酸酯和乙二胺为硬段，聚醚多元醇为软段，通过分子设计采用分步合成法，制备了具有规整硬段和良好分散性能的聚醚型聚氨酯脲水分散液。

A series of polyether based polyurethaneurea aqueous dispersions with well-defined hard segment s were prepared by fractional steps with polyether polyol, 4,4′-diphenylmethane diisocyanate,dimethylolpropionic acid,1,4-butanediol,isophorone diisocyanate and ethylenediamine.

以二苯基甲烷二异氰酸酯、二羟甲基丙酸、1，4-丁二醇、异佛尔酮二异氰酸酯和乙二胺为硬段，聚醚多元醇为软段，通过分子设计采用分步合成法，制备了具有规整硬段和良好分散性能的聚醚型聚氨酯脲水分散液。

Isocyanurate based on TDI was synthesized and the heat-resistance property of casting polyurethane elastomer which synthesized using isocyanurate based on TDI and PEPA was obviously enhanced compared to polyurethane elastomer which did not introduce the isocyanurate by the TGA under the different temperature and the mechanics performance maintenance rate at high temperature.

在催化剂作用下，合成了TDI-100型异氰脲酸酯，并与己二酸乙二醇丙二醇酯合成了浇注型聚氨酯弹性体，通过不同温度下的热失重分析和弹性体的力学性能高温保持率对比分析表明，在TDI型聚氨酯弹性体中引入异氰脲酸酯基团，可明显提高弹性体的耐热性能。

The reaction kinetics of poly urethane formation and that of trimerization of isocyanate in a system of modified by urethane were studied by FTIR.

采用傅里叶快速红外光谱技术研究了氨酯改性聚异氰脲酸酯反应体系中氨酯、聚异氰脲酸酯生成的反应动力学，结果表明，在该反应体系中，氨酯反应和异氰酸酯的三聚反应是同步发生并同步进行的，其中三聚反应是一级反应；氨酯对异氰酸酯是一级反应，对聚醚二元醇为0级反应。

The reaction kinetics of polyurethane formation and that of trimerization of isocyanate in a system of polyisocyanurate modified by urethane were studied by FTIR. The results show that the two competing reactions occurred and progressed simultaneously, and the trimerization was found to be first order, and the polyurethane formation was first order with respect to the isocyanate concentration and zero order with respect to the polyol concentration.

采用傅里叶快速红外光谱技术研究了氨酯改性聚异氰脲酸酯反应体系中氨酯、聚异氰脲酸酯生成的反应动力学，结果表明，在该反应体系中，氨酯反应和异氰酸酯的三聚反应是同步发生并同步进行的，其中三聚反应是一级反应；氨酯对异氰酸酯是一级反应，对聚醚二元醇为0级反应。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。