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氰化钾

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The structures were identified by IR, UV,〓 NMR and element analyses. 2. Free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation eighteen semicarbazides to N-Aryl-2-Phenyl diazenecarboxamide with a solution of potassium ferricyanide in 2N aqueous sodium hydroxide and dichloromethane is described for the first time.

利用2,2,6,6-四甲基-4-羟基-1-哌啶氮氧自由基为相转移催化剂,在饱和铁氰化钾的2N氢氧化钠溶液与二氯甲烷的两相反应液中,催化氧化十八个取代氨基脲得到十八个相应的新型偶氮化合物N,2-二芳基二氮亚烯甲酰胺,均获得了较高的产率。

In weak alkaline medium, the ECL intensity of luminol could be sensitized by potassium ferricyanide. The mechanism of the sensitization is revealed as the oxidation of the luminol by potassium ferricyanide concomitant with the ECL reaction.

在弱碱性介质中,铁氰化钾对鲁米诺具有氧化作用,因而对鲁米诺的电化学发光产生增敏,提高了鲁米诺电化学发光检测的灵敏度,讨论了这一增敏作用的机理。

Methods Sea sand were added into samples-distill by water in the condition of alkalescence vibratedly-add potassium ferrocyanide and zinc acetate (to deposit protein, faecula,fat.)-determination by HPLC after filtration.

样品加入海砂分散黏稠成块的样品,在碱性条件下用水振荡提取,加入亚铁氰化钾和乙酸锌沉淀蛋白质、淀粉和脂肪等,滤膜过滤进行液相色谱分析。

The high potassium ferrocyanide solution was added to CAM homogenates and the absorbance was detected by ultraviolet spectrophotometer. The hemoglobin content of CAM homogenates was obtained by reference standards.

分离发育期鸡胚尿囊膜并将其匀浆,加入高铁氰化钾溶液,用紫外分光光度计测量A值,通过标准品计算样品中血红蛋白的含量。

The protein and the fatty compounds in the sample are precipitated by zinc acetate and potassium ferrocyanide, then the chromogenic reaction of acetylacetone with formaldehyde released from the sample in weak-acid medium and boiling bath takes place immediately.

提出了一种用於现场测定水发食品中甲醛含量的样品快速前处理新方法,采用乙酸锌和亚铁氰化钾沉淀样品中的蛋白质和脂肪,在弱酸性介质和沸水浴条件下提取了样品中的甲醛,并与乙酰丙酮立即发生显色反应。

Chicken chorioallantoic membrane ; angiogenesis ; hemoglobin ; potassium ferrocyanide

鸡胚尿囊膜;高铁氰化钾法;新生血管;血红蛋白

A HPLC method for determination of sorbic acid,benzoic acid and sodium saccharin in dairy drink was studied.The comparison of five methods of precipitating protein showed that the solution of potassium ferrocyanide and zinc sulfate as protein's precipitant was appropriate.

探讨含乳饮料中山梨酸、苯甲酸、糖精钠的HPLC含量测定方法,在比较5种沉淀样品中蛋白质的方法后,确定以亚铁氰化钾与硫酸锌溶液为沉淀剂,采用C18反相柱,以甲醇:乙酸铵溶液(0.02 mol/L)=15∶85为流动相,紫外230 nm检测,结合保留时间及二极管阵列检测器光谱分析信息定性。

In this bath, maleic acid was an inhibitor, when its concentration was kept at 20 mg/L, the deposition rate could reduce to 6.17μm/h, the content of nickel decreased to 1.74% and the resistivity was 7.51μΩ·cm; Potassium ferrocyanide inhibited deposition of copper, when its content was 0.5 ppm, the deposition rate decrease to 3.38μm/h, the content of nickel was 2.03%, the resistivity can reduced to 5.41μΩ·cm, the copper deposits also had higher (111) plane orientation. Thiourea was also an inhibitor in this system, when its concentration was kept at 0.8 ppm, the deposition rate was 4.72μm/h, the content of nickel in the film was 1.20%, the resistivity can reduced to 5.46μΩ·cm, at the same time, the deposition at (111) plane orientation become more favorable.

结果表明,马来酸在该体系中是抑制剂,当其浓度为20 mg/L时,镀速降为6.17μm/h,镀层镍含量降为1.74%,表面电阻率降为7.51μΩ·cm,铜层颗粒细小均匀,更有利于在(111)面上的结晶;亚铁氰化钾的加进可以明显降低镀,当其浓度为0.5 ppm时,镀速为3.38μm/h,镀层镍含量降为2.03%,表面电阻率降为5.41μΩ·cm,铜层颗粒细小均匀,(111)晶面衍射峰增强;硫脲在体系中也显示为抑制剂,当其浓度为0.8 ppm时,镀速降到4.72μm/h,镀层镍含量为1.20%,表面电阻率降为5.46μΩ·cm,形成的铜颗粒很小,同时(111)晶面衍射峰增强,有利于铜在(111)面上结晶。

Methods: The protein and other impurity in the sample were precipitated by zinc acetate and potassium ferrocyanide after dipping of the sample. N,N-dichlorocyclohexylamine derived from sodium cyclamate by sodium hypochlorite in the filtrate was extracted by hexane. The HPLC separation was carried out with a phenomenex Gemini-C18 column using acetonitrile-water(7+3) or methanol-water (8+2) as mobile phase and detected by UV monitor at 314 nm. External standard method was used for quantification.

样品中甜蜜素浸提后,用乙酸锌和亚铁氰化钾试剂沉淀蛋白质等干扰杂质,过滤,用次氯酸钠将样品溶液中的甜蜜素转化为N,N-二氯环己胺经正己烷萃取后,在phenomenex Gemini-C18柱上,以乙腈-水(7+3)或甲醇-水(8+2)为流动相进行分离,HPLC-UV检测器在314 nm测定,外标法定量。

Potassium ferrocyanide, sodium

73亚铁氰化钾,亚铁氰化钠

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