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氯醛

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UV 254nm, 366nm and anisaldehyde as a chromogenic agent were used for detecting compounds of these strains. Results indicate that the metabolites of these strains were the most abundant when these strains were fermented in No.1 and No.4 media, and only few in No.2 and No.3. Metabolites of each strain were different in different media.

实验结果表明,用1号和4号培养基发酵产生的次生代谢产物的种类最丰富,2号和3号培养基产生的较少;用II号展层系统(氯仿∶甲醇=4∶1)和III号展层系统(正丁醇∶乙酸∶水=4∶1∶5)作TLC层析,检测到的产物最多;3种检测方法以茴香醛检测到的代谢产物最丰富。

Part two reports that a glucose oxidase electrode is made of a platinum electrode modified by glucose oxidase in polyvinyl butyral membrane and tris(2,2-bipyridyl)cobalt perchlorate as an electron mediator in the solution.

其次,研究了以聚乙烯醇缩丁醛为固定GOD的载体,将GOD附在铂丝电极上并采用高氯酸三-2,2'-联吡啶合钴[Co_3(ClO_4)_3]作为电子媒介体制得电流型葡萄糖酶电极。

Our company adopt advanced production technology and equipment, to paint in different modified resin system pre-dispersion, used for high-grade inks, paints and coatings production, the main products are lipid soluble and alcohol soluble nitrocellulose pre-dispersed pigment-based color films, water-based acrylic paints pre-dispersed color tablets, chlorine vinegar pre-dispersed pigment color polymer films, cellulose acetate butyrate pre-dispersed pigment color films, polyvinyl butyral pre-dispersed pigments, such as color film.

本公司采用先进的生产技术和设备,把颜料在不同的改性树脂体系中进行预先分散,用于高档油墨、油漆和涂料的生产,主要产品有脂溶和醇溶型硝化棉预分散颜料色片、水性丙烯酸预分散颜料色片、氯醋聚合物预分散颜料色片、乙酸丁酸纤维素预分散颜料色片、聚乙烯醇缩丁醛预分散颜料色片等。

Currently 14 existing products, according to campaign is divided into four categories: one category is phosphorus chemical series, to yellow phosphorus, phosphoric acid, sodium tripolyphosphate-based, phosphoric acid, sodium tripolyphosphate of the 50,000 tons / Year; second category is the chlor-alkali series, caustic soda, hydrochloric acid, liquid chlorine, hydrazine hydrate, polyethylene butyral mainly three types of products is manganese, manganese powder, manganese ingots, mainly Electrolytic Manganese, One Electrolytic Manganese annual production capacity of 10,000 tons, manganese ingot processing capacity 15,000 tons / year; four other products, including oxygen, acetylene, such as selenium dioxide.

目前现有产品14个,按系列分为四大类:一类是磷化工系列,以黄磷、磷酸、三聚磷酸钠为主,其中磷酸、三聚磷酸钠各5万吨/年;二类是氯碱系列,以烧碱、盐酸、液氯、水合肼、聚乙烯缩丁醛为主;三类是锰产品系列,以锰粉、锰锭、电解锰为主,其中电解锰年生产能力为1万吨,锰锭加工能力1.5万吨/年;四类是其他产品包括氧气、乙炔、二氧化硒等。

In my opinion, Cu complexes with unsaturated alcohol to form a complex compound; the nitrogenous compound introduced serves as the complex compound's stabilizing agent and reduces activation energy of reaction; TMPO serves as oxygen carrier and displays it's selective oxidation function. This new method and mechanism also demonstrates significance to other similar organic reactions.3 In the chlorohydrin reaction, NaCIO is replaced by Ca2see Chapter4.4.3.4(2 .A, this method hasn't been reported in previous literature,which exerts more buffer action to the react system, the yield increased from 52% to 88.6%; at the same time it solve the problem of poor stability and low percentage composition of NaCIO.

认为:CuD与烯醇形成络合物:含氮有机物的引入起到稳定络合物,降低活化能的作用:而TMPO则充当携氧子起传递氧的作用,并具有选择氧化功能:这种新的方法和理论对类似的反应(不饱和醇类在络合体系下选择性催化氧化为对应的醛也具有重要的指导作用。3在异戊二烯的氯醇化反应中,用次氯酸钙代替次氯酸钠见第4章4.3.4(2.A,本方法未见文献报道,使反应系统更加温和,收率由52%提高到88.6%:并解决了次氯酸钠稳定性差、有效氯含量低的实际问题,具有重要的实用意义。

Main business scope: polyformaldehyde methylal methanol sodium nitrite sodium sulfide protopine xylene glacial acetic acid soda ash Ethyl acetate ion-exchange membrane caustic soda Chloromethane AEO-9 polyethylene glycol and other major raw materials and products.

多聚甲醛甲醇甲缩醛亚硝酸钠硫化碱片碱二甲苯纯碱冰醋酸醋酸乙酯离子膜烧碱 AEO-9 氯甲烷聚乙二醇等主要原料和产品。

The productions of glycin oxidation are complicated and the cost is high. The cyanogenesis is poisonous and unsafe.

国内外合成羟基乙酸的方法主要有甘氨酸氧化法、氰化法、醛类羧化法、甲醛和甲酸甲酯偶联法、草酸电解法、氯乙酸水解法等。

Herein, we report the enantioselective total syntheses of slagenins A-C and their antipodes. Starting from readily available ethyl -4-chloro-3-hydroxy-butanonate, elongation of the carbon chain with diazomethane, followed by oxidation of the given α-diazoketone using distilled DMD, afforded a key intermediate α-ketoaldehyde .

本文从方便易得的-4-氯-3-羟基-丁酸乙酯出发,经重氮甲烷延伸碳连、DMD氧化相应的α-重氮酮,制得α-酮醛;该化合物与尿素在氢氟酸作用下,以协同方式非对映选择性的直接构建了cis-四氢呋喃并[2,3-d]咪唑啉-2-酮双环结构,进而合成了天然产物slagenins A、B、和C的对映体。

On the basis of insoluble hydantoin bactericide prepared,the hydrophilic groups,such as trimethylamine group and triethylamine group,were introduced to the loading resin,such as chloromethyl polystyrene and formyl polystyrene.

在制成水不溶性海因类杀菌剂的基础上,在其载体树脂如氯球和醛基树脂上引入亲水基,如三甲胺基或三乙胺基。

In the presence of NaH and in DMF, the acyclic crown ethers 1a and 1b were synthesized by the reaction of di-or triethyleneglycol ditosylate and o-methoxymethoxybenzyl alcohol, which was obtained from salicylaldehyde via the protection of the hydroxyl group with chloromethyl methyl ether followed by the reduction of the formyl group with NaBH4. The hydrolysis of 1a and 1b with dilute hydrochloric acid provided the diphenolic type acyclic crown ethers 2a and 2b respectively in good yield.

将水杨醛与碱和氯甲基甲基醚反应,再经过NaBH4还原,即制得邻苯甲醇,然后将其在DMF中与NaH和二甘醇二对甲苯磺酸酯反应,得开链冠醚1a和1b.1a和1b经稀酸水解,即脱保护而分别生成新的酚型开链冠醚2a和2b。

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