氯醛

Using o-nitrotoluene as an oxidant,the improved preparation of 7-chloroquinldine was studied by classical Skraup reaction of m-chloroaniline and crotonaldehyde.

研究了以邻硝基甲苯为氧化剂，间氯苯胺和巴豆醛通过经典的Skraup反应制备7-氯喹哪啶的改进方法。

The main products are lndustrial Crotonaldehyde,Mixture of Organosilicon Monomer,Industial Sodium Polyacrylate and acrylate bond.

目前，主要产品有松江牌丁烯醛、有机硅混合单体、甲基氯硅烷等系列产品、工业聚丙烯酸钠、丙烯酸酯类粘合剂等系列产品。

Using o-nitrotoluene as an oxidant, the improved preparation of 7-chloroquinldine was studied by classical Skraup reaction of m-chloroaniline and crotonaldehyde.

研究了以邻硝基甲苯为氧化剂，间氯苯胺和巴豆醛通过经典的Skraup反应制备7-氯喹哪啶的改进方法。7-氯喹哪啶的收率为46.7%，质量分数99.2%；副产物为二氯喹哪啶，收率13.4%。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能，通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应，合成了聚噻吩对二甲氨基偶氮苯甲烷，再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

The results show that among the acetoacetonate complexes,Co_3 has the best catalytic activity.The optimum reaction conditions were as follows:0.764 mmol of Co_3,mole fraction of ethanal 10%based on the substrate,room temperature,oxygen pressure 2 MPa,reaction time 11h and solvent acetonitrile.Under these conditions,13.3%p-chlorobenzaldehyde was obtained with 15.3%conversion and 87.2%selectivity.The oxidation can also be carried out without solvent with 8.1%conversion,89.1%selectivity and 7.2%yield respectively.

在金属配合物中Co_3的催化性能最好，在其用量为0.764 mmol、乙醛用量为反应物物质的量的10%、氧气压力为2MPa时，以乙腈为反应介质，室温下反应11h，反应的转化率和选择性可达15.3%，87.2%，对氯苯甲醛收率可达13.3%；反应也可在无溶剂时进行，此时反应的转化率、选择性及醛的收率分别为：8.1%，89.1%，7.2%。

In this work , 1,8-octodiol, the starting material, reacted with 40% hydrobromic acid to produce 8-bromooctan-1-ol, with the catalytic action of PPTs, its hydroxyl group was protected by 2,3-dihydropyran. Then it coupled with 1-heptaalkyne, by means of P-2 nickel as catalyst, stereoselectivity catalysis hydrogenated, with the catalytic action of acid to take off extremital 2, 3-dihydropyran which protected hydroxy group, then used PCC to oxidize alcohol into corresponding aldehyde.

以1，8-辛二醇为原料，与40%氢溴酸进行单溴代反应，得到8-溴-1-辛醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应，保护分子中的羟基，再与1-庚炔进行偶联，以P-2镍为催化剂立体选择性催化加氢，酸性条件下脱末端的2，3-二氢吡喃对羟基的保护，使用氯铬酸吡啶盐将醇氧化成醛。

Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先，分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料，经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物，将它们与乙二胺缩合生成希夫碱配体，得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

Furoin was synthesized with furfural as raw material in the presence of Vitamin B1(VB1) as a catalyst.

以糠醛为原料，经维生素B1(VB1)催化合成糠偶姻。糠偶姻与不同的酰氯反应生成糠偶姻单酯。

Glyoxylic acid was prepared by reaction of sodium hydroxide surplus with methyl dichloroacetate in methanol solution via neutralization of filtrate with 50 percentage sulfuric acid to pH 2～3 and hydrolyzation after separation of salts.

二氯乙酸甲酯和过量的氢氧化钠在甲醇溶液中反应，滤出氯化钠后，直接加入适量的 5 0 %的硫酸调 pH值为 2～ 3，滤出硫酸钠，蒸馏回收甲醇，水解、浓缩，得到不含乙二醛的 4 0 %乙醛酸溶液。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。