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氯酸酯

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The main photoproducts in dioxane and hexane are 2-chloro benzamide and 4-chlorophenyl isocyanate.

在二氧六环及正己烷中的主要光解产物为邻氯苯甲酰胺和对氯苯基异氰酸酯。

Using the method of tosylation, tosylate terminated epichlorohydrin polymer as intermediate was synthesized by PECH and 4-toluenesulfonylzchloride in pyridine,azido terminated glycidyl azide polymer was obtained by the reaction of intermediate and sodium azide.

采用磺酸酯法,首先PECH与对甲苯磺酰氯在吡啶介质中反应形成端磺酸酯基氯化聚醚中间体,然后中间体经叠氮化作用形成端基为叠氮基的叠氮缩水甘油醚聚合物。

Treatment of 3-amino-4-chlorobenzoic acid with trimethoxymethane generated methyl 3-amino-4-chlorobenzoate in 80.0% yield.2-ethyl pivalate was oxidized by sulfuryl chloride,an...

所得中间体2-乙基特戊酸酯低温下经磺酰氯氧化,与中间体3-氨基-4-氯苯甲酸甲酯反应,所得产物经重排、水解和酰化反应得到目标化合物,总产率25.8%。

The Applications of Samarium Diiodide and Ytterbium Trifluoromethethanesulfonate in Organic Synthesis, the Applications of Bis Carbonate in Sythesis of Chloroformates

论文标题:二磺化钐及三氟甲磺酸镱在有机合成中的应用,双碳酸酯在氯甲酸酯合成中的应用

Part two: Using chloroformic ester reacted with potassuim thiocyanate to get thiocyanic esters. Then reacted with biological substituted pyrimidinamine to synthesize forty two thiourea compounds, thirty eight of them are new compounds. Their structures have been charactered by IR, 1H NMR and elemental analysis.

第二部分:先以氯甲酸酯和硫氰酸钾为原料合成异硫氰酸酯,再与有生物活性的取代氨基嘧啶反应,合成了一系列新的取代嘧啶基硫脲类化合物,合成的42个化合物中有38个为首次合成的新化合物,结构经元素分析、IR及~1H NMR得到确证。

Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.

以季戊四醇为起始剂,三氟化硼乙醚为催化剂,1,2—二氯乙烷为分散剂,环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇,A在N,N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇,B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。

The coating composition comprises, in a specific proportion, a vehicle ingredient comprising in a specific proportion an oligomer having at least twoacrylate groups and an ethylenic monomer copolymerizable with the oligomer, aacrylic-modified chlorinated polyolefin having a specific chlorine content, an organic peroxide polymerization initiator, and a polyisocyanate compound.

该涂料组合物含有特定比例的由至少具有两个丙烯酸酯基的低聚物和可与该低聚物共聚的乙烯性不饱和单体形成的媒介物成分、特定氯含率的丙烯酰基改性氯化聚烯烃、有机过氧化物聚合引发剂、和聚异氰酸酯化合物。

Cefixime open side chain acid was prepared by oximation,etherification,chlorination,ester decomposition using t-butyl acetoacetate as starting material.

以乙酰乙酸叔丁酯为原料,经过肟化、醚化、氯代酯解反应合成了头孢克肟开环侧链酸。

Tri-cyanurate as a excellent additional retardant was synthesized by using cyanuric chloride_3,tribromophenol as main materials and under the condition of sodium hydroxide,dichloromethane,toluene as solvent respectively.

以三聚氯氰3和三溴苯酚为主要原料,在碱性条件下,分别以二氯甲烷、甲苯作为溶剂,合成了一种性能优良的添加型阻燃剂三三聚氰酸酯。

Study on technics of synthesize dimethyl fumaricate, firstly prefabricated fumaric acid, with furfural as raw material, V2O5 as catalyst and potassium chlorate as oxidizer then synthesized dimethyl fumaricate through esterication of fumaric acid and methanol with phosphor tungstenic acid as catalyst.

研究了以糠醛为原料,V2O5作催化剂,用氯酸钾氧化制取富马酸,然后以磷钨酸为催化剂,用甲醇进行酯化合成富马酸二甲酯的合成工艺。

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