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氯酸盐

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Linear alkyl benzenes and linear alkyl dimethyl benzenes, prepared by the alkylate reaction of linear alpha olefin with benzene or dimethyl benzene which were sulfonated by chlorosulfonic acid and then neutralized to produce linear alkyl benzene sulfonates and linear alkyl dimethyl benzene sulfonates.

本文以一定链长的直链α-烯烃分别与苯和混合二甲苯为原料制备了直链烷基苯和烷基二甲苯,经氯磺酸磺化,中和可得到具有一定链长的直链烷基苯磺酸盐和直链烷基二甲苯磺酸盐。

For colour ed fire, potassium chlorate or perchlorate is combined with a metal salt that determines the colour .

对于带色彩的烟火,可由氯酸钾或高氯酸钾与确定颜色的金属盐配合。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分,我们研究了α,α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应,发现全氟苄基碘或溴及α,α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐;全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴;在烯烃存在下,全氟苄基碘则与烯烃发生加成反应,生成相应的1:1加成产物;在三价醋酸锰的作用下,部分芳香化合物如茴香醚,二甲氧基苯,吡啶,喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应,反应表现出一定的区域选择性,产率良好。

New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物:含五元膦-氧螯合环的1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明,配合物46、47都为变形的四方锥构型,膦-氧与钌形成螯合配位,其中苯亚甲基与钌的配位得以加强。

The complex kinetics of ClO2(superscript -) S2O3(superscript 2-) nonlinear reaction system in an unbuffered solution has been investigated in a CSTR.

研究了亚氯酸盐-硫代硫酸盐反应体系在非缓冲条件下的复杂动力学行为。

Two complexes of alkaline-earth metals perchlorate with phenyl-acetylmethylene sulfoxide(C6H5SOCH2 COCH3) have been synthesized and characterized by elemental analysis and IR spectra.

本文选取苯基乙酰甲基亚砜(C6H5SOCH2COCH3)作为配体与碱土金属的高氯酸盐反应得到配合物的单晶,对它们进行了元素分析及红外光谱表征,它们的化学式为[ML6](ClO4)2(M=Ca、Sr;L=C6H5SOCH2COCH3)。

Wastewater effluent has also caused environmental concerns because it contains high biological oxygen demand, lignins from the trees, and dissolved organic carbon, as well as heavy ls, alcohols, chelating agents, and chlorates.

废水污水也造成环境的关注,因为它含有高生物需氧量,木质素的树木,溶解有机碳,以及重金属,醇类,螯合剂和氯酸盐

CHLORATES, INORGANIC, N.O.S.

无机氯酸盐,未另作规定的

CHLORITES, INORGANIC, N.O.S.

无机亚氯酸盐,未另作规定的

Subsequently, chlorate-resistant experiment and growth experiment were used to verify the stability of their NR deficiency.

然后用氯酸盐抗性实验和不同氮源生长实验验证其NR突变的稳定性。

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