氯酸

Tebufenpyrad, a new high effective pyrazoleamide acaricide , was synthesized from 1-methyl-3-ethyl-4-chloro-5-pyrazolecarbon acid and 4-t-butylbenzylamine, the raw material are propionyl pyruvic ethyl ester and 4-t-butyl benzylchloride.

吡螨胺是一种新型、高效的吡唑酰胺类杀螨剂，本文以中间体1-甲基-3-乙基-4-氯-5-吡唑甲酸和4-叔丁基苄胺合成，起始原料丙酰丙酮酸乙酯和4-叔丁基苄氯，总收率为61.23%。

The results indicate that the optimized sulfonylation reaction time is 4 h, the materiel rate of chlorosulfonic acid and 2-chloroimidazo[1,2-α]pyridine is 1.2 : 1, with ethylamine the yield increasing from 15.4% to above 70%; the optimized ammonolysis reaction time is 3 h and the reaction temperature is 27℃, with the acetonitrile yield increasing from 60.1% to above 79.6%.

实验结果表明，磺酰化反应的最佳反应时间为4 h，氯磺酸与2-氯咪唑并[1，-α]吡啶的用量比为1.2：1，加入三乙胺可将收率由15.4%提高到70%以上；氨解反应的最佳反应时间为3 h，反应温度为27 ℃，加入乙腈可将收率由60.1%提高到79.6%；方案经改进后，总反应时间缩短3 h，收率提高了5.5%。

Some materials were synthesized in this paper at first, 1-nitro-2-pentanol was synthesized with nitromathane and butyraldehyde and the yield was 70.2%; l-nitro-2-pentanol was reduced to 1 -amino-2- pentanol with iron and the yield was 65.2%.

分别用氢氧化钠、三乙胺为缚酸剂，2-氨基-1-丁醇、1-氨基-2-戊醇、环己酮和二氯乙酰氯为原料，采用一步法和分步法合成了两种潜在除草剂安全剂。

Result:Together use of azone 2%,menthol 2% and camphol 1% has the best transdermal enhance effect of the absorption of diclofenac sodium, of which azone has the strongest effect on percutaneous absorption of diclofenac sodium.

氮酮是目前应用最广泛的透皮吸收促进剂之一，薄荷醇和冰片是近年研究较多的萜类透皮吸收促进剂的代表［1］，薄荷醇和氯酮对双氯芬酸钠的促透作用已有研究［2，3］，但三者联用的促透效果未见文献具体报道。

Insecticidal sucrose octanoate and sucrose caproate were synthesized by transesterification method or reaction of acid chloride with sucrose.

分别以酯交换法和酰氯法合成了辛酸蔗糖酯和己酸蔗糖酯两种杀虫活性蔗糖酯，其中酯交换法产物单酯含量高，而酰氯法反应速度快。

Chapter two 4-Hydroxybenzoic acid is connected with PEG6000 through defoliant DCC at rooom temperature, then the product is refluxed with chloroacetic acid in acetone to afford PEG-bound phenyloxyacetic acid, which is reacted with thionyl chloride, ammonium thiocyanate and arylamines in turn to give PEG-bound disubstituded thioureas. After the cleavage with sodium methoxide in methanol, the eleven disubstituted thioureas are obtained.

第二章 利用PEG6000作载体，通过脱水剂DCC在室温下将对羟基苯甲酸以酯键连接在PEG6000上，再与氯乙酸在较温和的条件下生成PEG6000支载的芳氧乙酸，然后，依次与亚硫酰氯、硫氰酸铵、芳胺反应，生成PEG6000支载的硫脲，最后用甲醇钠的甲醇溶液切割PEG，得到了十一种1，3-二取代硫脲。

Industrial coatings are colored ACID, amino, nitro, alkyd, a vinyl chloride, such as epoxy primer, Ciqi, hammer paint, paint orange-shaped, metal flashlight paint, paint road lines such as midrange products; Lacquer coating for the vehicle, ship paint, paint bridges, electrical insulation paint, and so on; special coating that HCPE high-chlorinated polyethylene special rust paint and rust-proof, anti-corrosion series of high temperature silicone paint; decorative paint a high-polyester, dumb Light-finish, Seqi, crystal floor paint, primers, and other ancillary products transparent and within the external walls of the High ACID latex paint products.

工业涂料有各色丙稀酸、氨基、硝基、醇酸、过氯乙烯、环氧等底漆、磁漆、锤纹漆、桔形漆、金属闪光漆、道路划线漆等高中档产品；专用涂料有汽车漆、船舶漆、桥梁漆、电工绝缘漆等；特种涂料有HCPE高氯化聚乙烯特种带锈防锈防腐系列漆和有机硅耐高温漆；装饰涂料有聚酯高光、哑光清面漆、色漆、水晶地板漆、透明底漆等配套产品和丙稀酸高级内外墙乳胶漆系列产品。

The degradation of 2, 4-dichiorophoxyacetic acid (2, 4-D) by ozonation combined with sonication (03/US) was investigated. Based on the authors' first paper about the synergistic effect of ozone and US, this paper presents intermediate products of 2, 4-D degradation. The main intermediates were 2, 4-dichiorophenol, benzopuinone, hydroquinone and organic acids, such as maleic acid and oxalic acid and soon.

利用臭氧超声波联合工艺对苯氧羧酸类除草剂2，4-D进行降解研究，在前文探讨臭氧超声波之间协同效应的基础上，确定其中间产物种类主要有2，4-二氯苯酚、苯醌、氢醌以及小分子酸如顺丁烯二酸、草酸、甲酸、乙酸等。

The heaxamethylene-diamine, 2-chloroethylene-sulfonate, fatty acid and Phosphorus trichloride are used as raw materials and a series of Gemini products are synthesized.

并以己二胺、2-氯乙基磺酸钠、脂肪酸和三氯化磷等为原料合成了一系列的双酰胺双磺酸盐表面活性剂N，N＇-双脂肪酰基己二胺二乙基磺酸钠。

Glycidyl benzoate,glycidyl propionate,glycidyl acetate were obtained respectly through a phase-transfer catalytic methodology using sodium benzoate, sodium propionate, sodium acetate and epichlorohydrin as raw materials, and pure products were obtained though vaccum distillation.β-cyclodextrin and glycidyl benzoate, glycidyl propionate, glycidyl acetate, reacted in organic solvent and goal product were

先以苯甲酸钠、乙酸钠、丙酸钠和环氧氯丙烷为原料在相转移催化剂的作用下分别合成了苯甲酸缩水甘油酯、乙酸缩水甘油酯和丙酸缩水酯，经过减压蒸馏，得到相应的纯品；β-环糊精和苯甲酸缩水甘油酯、乙酸缩水甘油酯、丙酸缩水甘油酯在有机溶剂中反应，经过硅胶色谱柱分离，得到了相应的产品，产品经过TLC、IR、1H NMR、MS表征，并研究了温度、反应时间、催化剂等几个因素对反应工艺的影响，结果表明温度和催化剂对反应的快慢有较大影响。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。