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The change of Ortho chlorophenol and pyrocatechol, which were used as models of chlorophenol compounds and polyphenol compounds respectively during the electroanalysis process was also investigated in order to find degradation mechanism.

实验中以邻苯二酚和邻氯苯酚作为多酚类化合物、木素衍生物和氯酚类化合物的模型物,探讨了多酚类化合物和氯代酚在电化学处理过程中的降解机理。

Several strains capable of degrading chlorophenol was isolated from contaminated soil using chlorophenol as sole carbon source, some of them were identified based on 16S ribosomal-DNA sequences.

在受氯酚污染的土壤样品中,以氯酚为唯一碳源和能源,分离出了多株对氯酚具有较高降解能力的微生物,利用16S rDNA序列分析方法对部分微生物进行了种属鉴定。

Chlorophenol and 4-chlorophenol can be transformed to phenol and chloride ion and 2, 4-dichlorophenol to phenol, chloride ion and a small amount of 2-chlorophenol and 4-chlorophenol.

2-氯酚和4-氯酚被还原脱氯生成苯酚和氯离子,2,4-二氯酚被还原脱氯生成苯酚、少量的2-氯酚和4-氯酚以及氯离子。

The indigenous microorganisms existed in the contaminated soil could degrade low concentration of chlorophenol 00mgg^(-1, however, their degradative capacity was limited when chlorophenol concentration was high about 500mgg^(-1, which may be caused by the toxic effect of high concentration of chlorophenol on the indigenous bacteria.

土壤中存在的土著的氯酚降解菌可以对低含量的氯酚100mgg^(-1进行降解;但是当土壤中氯酚含量较高500mgg^(-1时,土著微生物的降解能力受到限制,这可能是高浓度的氯酚对土著的氯酚降解菌会产生毒性作用。

Chlorophenol(2-CP) and 4-chlorophenol(4-CP) were treated respectively in coupled ultrasound/ electrocatalysis systems.

采用超声波-电催化联合技术处理2-氯酚(2-CP)和4-氯酚(4-CP),探讨了电催化氧化和超声氧化的协同效应,考察了影响声电联合降解氯酚化合物的条件因数。

And the culturable bacterial degraders were increased from 10^6CFUg^(-1) soil to 10^8CFUg^(-1) soil after inoculating with the degrader. Moreover, the bacterial population increased faster in 100mgg^(-1) microcosoms than in 500mgg^(-1) microcosoms, revealing that the inoculated bacteria could survive and enhance the biodegradation of chlorophenol in cuntaminated soil.

接种外来微生物后,土壤中可以培养的氯酚降解菌的总数从开始的10^6CFUg^(-1)增加到10^8CFUg^(-1),并且,在氯酚含量为100mgg^(-1)的土壤样品中,微生物数目的增加比在氯酚含量为500mgg^(-1)土壤样品中更快。

In the detection experiments, the scan rate is set at 0.3 V/s under the analysis of linear sweep voltammetry. On the cyclic voltammetry plot, each pair of clear redox peaks was observed for 4-chlorophenol (4-CP), 2,4-dichlorophenol (2,4-DCP), and penta- chlorophenol. The potentials of the redox pairs were 1.218 and -0.460 V for 4-CP, 1.128 and -0.448 V for 2,4-DCP, and 1.037 and -0.473 V for PCP.

在侦测污染物的实验之中,使用0.3 V/s做为线性扫描伏安法的最佳扫描速度,利用循环伏安法扫描可测得4-氯酚、2,4-二氯酚及五氯酚水溶液中氧化与还原波峰,4-氯酚的氧化与还原电位为1.218与-0.460 V、2,4-二氯酚之氧化与还原电位为1.128与-0.448 V及五氯酚之氧化还原电位为1.037与-

Ozonation could not reduce TOC completely, the results of HPLC and GC-MS showed that p -CNB was mainly transformed into p -chlorophenol, p -nitrophenol, 2-chloro-5-nitrophenol, etc ., and carboxylic acids with low molecular weight.

HPLC和GC-MS结果表明,ClNBs主要被转化为氯酚、硝基酚、氯代硝基酚、硝基苯、氯苯和低分子的羧酸等物质。

More and more attention is focusing on the safty of drinking water suply. In this paper, firstly, chloramine formation and the characteristics and kinetics of monochloramine autodecomposition were studied. Secondly, considering the high concentration of ammonia and the complication of organic matters in Shanghai Huangpu River, formation characteristics and rules of disinfection byproducts were reviewed during the breakpoint chlorination process, and on the basis of grading and clssification of organisms, the control effects of chloramination on DBPs formation were studied. Finally, the formation rules of 2-monochlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol from phenol chlorination were investigated, and related influencing factors and kinetics were analysed.

饮用水的安全供给受到越来越多的重视,本文首先进行了氯胺形态以及一氯胺自降解特性及其动力学研究;然后结合上海黄浦江水源氨氮浓度高、有机物成分复杂的特点,研究折点加氯过程中消毒副产物的生成特性和规律,以及在将有机物分级和分类的基础上,研究氯胺消毒对不同类别有机物生成消毒副产物的控制效果;最后考察了氯化苯酚生成2-一氯酚(2-MCP)、2,4-二氯酚(2,4-DCP)及2,4,6-三氯酚(2,4,6-TCP)的规律,并进行了影响因素和动力学分析。

This paper reviews pathways of aerobic and anaerobic microbiological degradation of PCP. It can be concluded that reductively dechlorination prior to ring cleavage plays a key role in mineralization of PCP.

文章通过综述好氧与厌氧微生物降解五氯酚的降解菌和降解途径,认为五氯酚首先通过脱氯转化为低氯代化合物后再开环,因此脱氯就成为五氯酚降解的关键步骤。

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