氯甲烷

Carbon Tetrachloride; Tetrachloro

四氯化碳；四氯甲烷

The experimental results indicated that the yield of 2,6-DMN can reach above 38%, when the usage of dimethylnaphthalene was 2g, the temperature reached 18℃, the reaction time was 2.5h, the mole ratio of water-free aluminum trioxide to dimethylnaphthalene was 0.8, the mole ratio of transmethylation agent tetramethylbenzene to dimethylnaphthalene was 1.0, the usage of methane trichloride was 15mL.

结果表明，2-甲基萘(2-MN)使用量为2g时，反应温度为18℃、时间为2.5h、n：n（2-甲基萘）=0.8、n：n（2-甲基萘）=1.0、二氯甲烷用量为15mL时，2，6-DMN的收率可达38%。

Extraction rate of artemisinin increased obviously with the decrease of dielectric constant of the mixed trichloromethane and dichloromethane, which was opposite to the results of mixed solvent of hexane and cyclohexane.

用正己烷、环己烷以及它们的混合溶剂作溶剂时，青蒿素的提取率随着溶剂的介电常数的增大而增大，而用二氯甲烷、三氯甲烷以及它们的混合溶剂作溶剂时，青蒿素的提取率随溶剂的介电常数的增大而减小。

Acetonitrile-sodium chloride, trichloromethane and acetone-dichloromethane were used to extract organophosphorous pesticides respectively. Pulsed-flame photometer detector was used to analyze the extraction rate of these three solvents. Flame ionization detector was used to analyze the content of impurity in the samples extracted by those three solvents.

分别采用乙腈－氯化钠法、三氯甲烷法和丙酮－二氯甲烷法提取蔬菜样品中残留的有机磷农药，使用带脉冲式火焰光度检测器的气相色谱法比较了三种提取方法有机磷农药的提取效率，使用带火焰离子检测器的气相色谱法分析了三种提取方法杂质溶出量。

Triphenylmethyl chloride can react selectively with the 30-hydroxil group of glycyrrhetol under the catalyzing effects of three ethyl amine and dimethyl amino-pyridine.This condition of the reaction has an important value for the selective protection of 30-hydroxil group of glycyrrhetol.

三苯氯甲烷在三乙胺和二甲氨基吡啶等碱性催化下与甘草萜醇的C30-位羟基进行选择性缩合反应，此反应产率较与C3-位羟基化反应的要高，此种反应条件在甘草萜醇C30-位羟基的选择性保护中具有重要的价值。

This is the first report of pectenolone and pectenoxanthin, two types of carotenoid, in the muscle of the Yesso scallop.3 Roles of the carotenoids composition and accumulation in Yesso scallopThe method for detecting carotenoids using reverse phase high performance liquid chromatography was developed. The conditions of RP-HPLC analysis were an analytical scale (200×4.6 mm, inner diameter 5μm) Eclipse XDB-C18 column of Agilent corporation; 10μl injection volume; 25°C column temperature; acetonitrile, methanol and methylene dichloride mobile phase (40:56:4, V/VV) with 0.1% BHT; 1.0 ml per minute flow rate; 450 nm UV-VIS detector; 8 minutes elution.The carotenoids from orange muscle of Yesso scallop of 7, 10, 12, 15, 18, 22 months old was detected using the method refered above.

通过柱层析、高效液相等手段对橘红色闭壳肌中的主要类胡萝卜素进行了提取分离，分离提纯得到两种类胡萝卜素，并通过MS、~1H-NMR和~(13)C-NMR对其进行结构鉴定，结果表明(3S，3\'R)-3，3\'-dihydroxy-7\'，8\'-didehydro-β，β-Caroten-4-one和(3S，3\'S)-7，7\'，8，8\'-tetradehydro-β，β-Carotene-3，3\'-diol，俗称pectenolone和pectenoxanthin是橘红色闭壳肌中的主要类胡萝卜素，这是国内外首次对虾夷扇贝闭壳肌中的类胡萝卜素进行提纯及结构鉴定。3虾夷扇贝类胡萝卜素的种类组成和累积变化规律建立了橘红色闭壳肌中类胡萝卜素的HPLC分析定量检测技术：色普柱为Agilent公司的Eclipse XDB-C18柱200mm×4.6mm，i.d.5μm进样体积，5μl ；流速1ml/min；检测波长450nm；柱温25℃；流动相为乙腈：甲醇：二氯甲烷(V/V/V=40：56：4并加入0.1%的BHT；分离时间为8min。

Conductivity of Polyoxyethylene/Poly (2-vinyl pyridine)Blend and Compatibilizing Effect of Lithium Perchlorate;2. Graft terpolymerization of polyoxyethylene macromer with acrylates;3. Then multiblock copolymers was obtained by condensing polyoxyethylene and poly(2 vinylpyridine)with dichloromethane in the presence of potassium hydroxide.

甲基萘锂作为引发剂利用阴离子聚合得到 2 乙烯基吡啶的遥爪双羟基低聚物(P2VP)，然后以二氯甲烷作偶联剂与聚环氧乙烷反应制备P2VP和PEO多嵌段共聚物，考察了反应时间对偶联反应的影响，并对共聚物进行了IR和1H NMR表征，由1H NMR谱的积分曲线得到了共聚物中PEO链段质量分数。

Defatting with different solvents had no effect on the activity of ricin, but the average lethality of the ricin obtained from defatting with methylene chloride was relatively slowly.

采用不同溶刺脱脂对蓖麻毒蛋白的活性没有影响，但二氯甲烷脱脂的蓖麻粗毒蛋白平均致死速度相对较慢。

Methylimidazole in soy sauce was extracted with methylene chloride,diazotized to forms a red colored azo-compound with the highly absorbance at the wave length of 440nm and determined by ultraviolet-visible spectrometry.

酱油样品在层析柱中用二氯甲烷洗脱，经重氮化后在波长440nm处具有最大吸收，据此建立了紫外可见光谱法测定酱油中4-甲基咪唑的方法。

According to the Box-Benhnken design principle,the method of response surface method with 3 factors and 3 levels was used. The factors influencing the technological parameters were determined by means of regression analysis. Response surfaces were finally graphed with the yield as the response value. The synthesis conditions were optimized as follows:reaction reagent was NBS,stoichiometric proportion between NBS and anhydrovinblastine was 1.07; the dosage of TFA was 22 mL/L; reaction temperature was －68 ℃ and duration was 90 min.

在单因素实验基础上，根据Box-Benhnken实验设计原理，采用三因素三水平的响应面分析法，研究了各个因素及其交互作用后，得到了合成7′-Br-脱水长春碱的最佳工艺条件：以二氯甲烷为溶剂，采用NBS为溴代剂，其用量与底物的物质的量比为1.07∶1，TFA的加入量22 mL/L，在－68 ℃下反应90 min，终止反应后，得到卤代产物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。