氯化磷

The forming mechanism of dihydrophenophosphazine by the interaction of Ph〓NH and PCl〓 was studied, and the possible forming mechanism of spiro phosphonium chloride in the same reaction system was also proposed.

讨论了二苯胺与三氯化磷的成环机理以及反应过程中螺磷杂环化合物的形成机制，提出5，10-二氢磷杂吖嗪-10-氧化物存在类"烯醇—酮式"互变异构现象。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

Company and the Chinese Academy of Sciences Institute of Chemistry, Nanjing University of Technology Institute of Chemical Technology has a good technical cooperation, product quality can meet the needs of different customer requirements, in particular, high content, low-arsenic, low lead, low-iron phosphorus trichloride, oxychloride P-selling more than a dozen provinces and cities nationwide, autonomous regions and exported to Europe, Southeast Asia and Taiwan, production and sales and market share in the same industry in the country ranked the top three, Jianping people adhere to the "credibility first, customer first, service first" operating purposes, warmly welcome customers at home and abroad to discuss cooperation with our company.

公司与中科院化学研究所、南京工业大学化工学院有着良好的技术合作，产品质量能满足不同客户的要求，尤其高含量、低砷、低铅、低铁的三氯化磷、三氯氧磷畅销全国十几个省市、自治区及出口到欧洲、东南亚和台湾地区，产销量和市场占有率在全国同行业中居前三甲，建平人恪守"信誉第一、顾客至上、服务至上"的经营宗旨，热忱欢迎国内外客户与我公司洽谈合作。

The novel title compound was synthesized with benzaldehyde, isobutyraldehyde, phosphorus trichloride as raw materials. The total yield was 40.8%. The structure was confirmed by 1H NMR, 31P NMR and elemental analysis.

摘要以苯甲醛、异丁醛、三氯化磷为原料合成了新型的1，3，2-氧磷杂环类化合物2-苯羟甲基－5，5-二甲基－4-苯基－2-氧代－1，3，2-二氧磷杂环己烷，总收率为40.8%，并对其进行了NMR研究和结构表征。

Methyl-5-ethyl-2-thiouracil,m.p.211°,was prepared according to the direc- tions of Johnson and Baily.4-Methyl-5-ethyl-uracil,m.p.236°,was formed in a 81% yield from 4-methyl-5-ethyl-2-thiouracil by boiling the latter with an aqueous solution of monochloroacetic acid.4-Methyl-5-ethyl-uracil reacted with phosphorous oxychloride and phosphorous pentachloride,giving 4-methyl-5-ethyl-2,6-dichloropy- rimidine in a 79% yield.

14-甲基5-乙基-2，6-二氯代嘧啶曾用磷醯氯和五氯化磷与其相应的2，6-二羟基嘧啶作用制取。(2)4-甲基-5-乙基-2，6-二氯代嘧啶与醇钠作用，极易转变成4-甲基-5-乙基-2，6-二烷氧基嘧啶。(3)4-甲基-5-乙基-2，6-二甲氧基嘧啶和2-氧代-3，4-二甲基-5-乙基-6-甲氧基嘧啶在高温时重排成其稳定构型的的异构体：1，3，4-三甲基-5-乙基-2，6-二氧代嘧啶。

Through Friedel-Crafts reaction, We have prepared highly purified triphenylphosphine sulfide by using benzene, phosphorus trichloride, sulfur, and aluminum trichloride, which is desulfurized with metal powder to produce triphenylphosphine.

实验方法为以苯、三氯化磷、硫和三氯化铝为原料，利用Friedel-Crafts反应，合成三苯基硫膦，收率为79.4％；然后用金属将三苯基硫膦还原制得三苯基膦，收率为80％。

It was found that the Beckmann rearrangement of cyclohexanone oxime could be performed smoothly in the catalytic media consisting of room temperature ionic liquid and acidic phosphorated compounds, and excellent conversion and selectivity were achieved under mild conditions without any additional organic solvents.

发现酸性含磷化合物，如五氯化磷等在离子液体中可以高效地实现环己酮肟重排制己内酰胺，具有不需另加有机溶剂，选择性高等优点。

Company and the Chinese Academy of Sciences Institute of Chemistry, Nanjing University of Technology Institute of Chemical Technology has a good technical cooperation, product quality can meet the needs of different customer requirements, in particular, high content, low-arsenic, low lead, low-iron phosphorus trichloride, oxychloride P-selling more than a dozen provinces and cities nationwide, autonomous regions and exported to Europe, Southeast Asia and Taiwan, production and sales and market share in the same industry in the country ranked the top three, Jianping people adhere to the "credibility first, customer first, service first" operating purposes, warmly welcome customers at home and abroad to discuss cooperation with our company.

公司与中科院化学研究所、南京工业大学化工学院有着良好的技术合作，产品质量能满足不同客户的要求，尤其高含量、低砷、低铅、低铁的三氯化磷、三氯氧磷畅销全国十几个省市、自治区及出口到欧洲、东南亚和台湾地区，产销量和市场占有率在全国同行业中居前三甲，建平人恪守&信誉第一、顾客至上、服务至上&的经营宗旨，热忱欢迎国内外客户与我公司洽谈合作。

Is located in Xuzhou City, Jiangsu Province, Wu Jiawang District, the territory of the Beijing-Shanghai Expressway, Xuzhou east exit to the east, that is 5 kilometers, the transportation is very convenient, covers an area of 130,000 square meters, there are a two decades the history of phosphorus chemical production of medium-sized enterprises, as a national phosphorus trichloride, phosphorus oxychloride, deputy head of industry collaboration group units in 2005 through the ISO9000, ISO14000, ISO18000 system certification, enterprise for many years been rated as "heavy contract , and keeping promises "enterprise, financial credit AAA level enterprise.

徐州市建平化工有限公司，位于江苏省徐州市贾汪区大吴镇境内，京沪高速公路徐州东出口向东5公里即到，交通十分便捷，占地十三万平方米，是一家有着二十年历史的中型磷化工生产企业，为全国三氯化磷、三氯氧磷行业协作组副组长单位，2005年通过ISO9000、ISO14000、ISO18000体系认证，企业连续多年被评为&重合同、守信用&企业，金融资信AAA级企业。

An organophosphorus flame retardant,10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide was synthesized from phosphorus trichloride,o-phenylphenol and p-benzoquinone through three-step process.

以三氯化磷、邻苯基苯酚和对苯醌为主要原料，通过三步反应合成了含磷阻燃剂10-(2，5-二羟基苯基)-9，10-二氢-9-氧杂-10-膦菲-10-氧化物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。