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氯乙酸

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A strong acid made by chlorinating acetic acid .

用氯处理乙酸而制成的一种强酸。

Samples were saponified with 20 g/L sodium hydroxide. The sexual hormones were then extracted with dichloromethane-acetic acetate (40∶1, v/v) under acidic conditions (pH 3, adjusted with 1 mol/L HCl ). An XTerraTMRP18 column was employed and a mixture of water-methanol-acetonitrile (50∶32∶18, v/v) was used as mobile phase. The seven sexual hormones were detected at 230 nm. The average spiked recoveries for the seven sexual hormones ranged from 75.6% to 97.8% with relative standard deviations of 1.9% to 7.2%. The linear ranges of determination were from 5 to 50 mg/L with correlation coefficients of 0.9999, and the limits of detection were from 3.7 to 12 ng.

先在试样中加入20 g/L氢氧化钠溶液与油脂进行皂化反应,然后用二氯甲烷-乙酸乙酯(体积比为40∶1)混合液在酸性条件下(pH 3)萃取,选择XTerraTMRP18色谱柱,以水-甲醇-乙腈(体积比为50∶32∶18)混合液为流动相,在波长230 nm处检测。7种性激素分离良好并排除了样品中杂质峰的干扰,低、高浓度平均回收率范围为75.6%~97.8%;相对标准偏差为1.9%~7.2%;检出限为3.7~12 ng。

Using of HCl solution substituting acetate buffer as analytical solution, not only would reproducibly renew the electrode surface with an electrochemical clear procedure, but also could eliminate effect of hydrolysis of bi species. At the same time, the square wave anodic stropping method of BiFEs could be extended to analyze sample containing chloride anion, such as sea water.

以稀HCl作为分析基础溶液替代传统的乙酸缓冲溶液,不仅可采用简单的电化学清洗方法高重现性地再生活化玻碳电极表面,并且,可消除金属离子的水解反应对检测结果产生的不利影响,同时可将铋膜电极SWAV检测方法拓展至分析检测海水等含氯离子样品。

The solubility of the novel polyamides are greatly improved compared with the conventional aramids, especially the polyamide with dendritic blocks of the second genernation as side chains are soluble in most of the common organic solvents such as ether, ethyl acetate, chloroform, acetone, tetrahydrafuran etc.

树状片段的引入大大地改善了聚酰胺的溶解性,特别是以第二代树状片段为侧基的聚酰胺的溶解性得到了很大的改进,可以溶于大部分常见的有机溶剂,如乙醚、乙酸乙酯、氯仿、丙酮、四氢呋喃等。

At last, the effective approach was found that the 024-antibiotic can be purified by freez-dry, methyl alcohol soaking, acetone, chloroform, and methyl alcohol continuously washing, alumina and silica gel column chromatography.

粗提制品的理化性质研究表明,024放线菌所产抗生素为无色晶体,易溶于水,可溶于甲醇和乙醇,且在甲醇中的溶解度较大,不溶或难溶于丙酮、氯仿、正丁醇、乙酸乙酯与苯。

Compared the extraction effects of yellow pigment from the corn protein powder by 95 %ethanol,isopropanol,chloroform,acetone,ac-Etylace,petroleum benzene,distilled water.

利用索氏提取法比较95%乙醇、异丙醇、氯仿、丙酮、乙酸乙酯、石油醚和蒸馏水提取玉米粗蛋白粉黄色素的效果,结果发现95%乙醇为最佳溶剂,95%乙醇提取液λmax为446nm。

The main reasons were that the algae and organism in the water decreased the ability of removing pollutants by coagulations, the algae which grown again in the open sedimentation tank weakened the removal effect of algae by coagulation; because of the accumulation of algae and algae toxin in the filtration tank, the concentration of algae toxin in the effluent increased; by the function of fluid chlorine, the algae and organisms after the filtration will release microalgae toxin and produce a lot of byproduct such as microalgae toxin, sobomyl and so on, meanwhile, the chlorination produce considerable halide and halo-acetic acid and other disinfection byproduct.

主要表现在藻类和溶解性有机物的存在降低了混凝去除污染物的能力;藻类在露天平流沉淀池中再生长,抵消了混凝除藻效果;藻类和藻毒素在滤池中积累,导致滤后藻毒素升高;穿透滤池的藻类和有机物在液氯作用下,释放微囊藻毒素、土臭素和二甲基异冰片等胞内物质,同时生成数量可观的卤代烃和卤乙酸等消毒副产物。

Fluoroalkyl acetic acids were converted to their corresponding carbonyl chlorides, and the latter reacted with o-aminpbenzyl aldehyde and ammonia gas to give 3-(1-imino-fluoroalkyl)-1H-quinolin-2-ones in moderate yields.

将2-氟烷基乙酸转化成相应酰氯,后者与邻氨基苯甲醛在通氨气条件下以较高产率转化为相应的3-(1-亚胺基-氟烷基)-1H-喹啉-2-酮。

The photophysical property of the complex is investigated by means of IR spectra, Raman spectrum and laser excited, high-resolved luminescence spectra which indicates one kind of Eu site with local symmetry of C 2v in the complex.

合成了植物生长素对氯苯氧乙酸和 1,10 邻菲罗林与铕的三元配合物Eu 3·Phen 。对所合成化合物进行了元素分析和热谱分析。通过测定配合物的红外光谱、拉曼光谱和激光激发高分辨荧光光谱研究了配合物的光物理性质。荧光光谱表明配合物中Eu离子只具有一种化学环境,Eu格位的局部对称性是C2v

The asymmetric reduction of prochiral P-oxo ester, aromatic ketone and aliphatic ketone to its corresponding chiral alcohol by yeast cells were studied respectively in this work when ethyl 4-chloro-3-oxobutyrate, acetophenone and 2-octanone were as the model substrates.

本文以4-氯乙酰乙酸乙酯、苯乙酮和2-辛酮分别为β-羰基酯、芳香酮和脂肪酮的模型底物,研究了利用活性酵母细胞催化这三类前手性酮不对称还原合成相应手性醇的反应特性。

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