氯乙酸

It,s allelchemicals were isolated through extraction, thin-layer chromatography, and column chromatograpathy. After the white clover was infused in ethanol and evaporation, the leavings was dissolved by water. The aqueous extract was extracted by petroleum,chloroform, ethyl acetate and n-Butanol successively, and the bioassay showed that the chloroform phase has obvious inhibitory effect, the inhibitory rate was 44.32%,88.08% on Abutilon theophrasti M., seedling length and root length, 82.08%,92.16% on Echinochloa crusgalli L., seedling length and root length, and the Amaranthus retroflexux L., germination rate is 0, the secondly was ethyl acetate phase.

运用萃取、薄层层析、柱层析等方法对白三叶草地上部分的化感物质进行初步分离，结果表明，白三叶草经乙醇浸提旋转蒸发后用蒸馏水溶解，依次用石油醚、氯仿、乙酸乙酯、正丁醇萃取，生物测定表明氯仿组分对杂草的抑制作用最强，对苘麻芽长和根长抑制率分别为44.32%、88.08%，对稗草芽长和根长的抑制率分别为82.08%、92.16%，反枝苋的发芽率为0；其次是乙酸乙酯相。

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

A method used to simutaniously analyze the residues of herbicides (4-chloro-2-methylphenoxy) acetic acid, 2-(4-chloro-2-methylphenoxy) propanoic acid and 4-(4-chloro-2- methylphenoxy) butanoic acid in garlic was developed.

建立了基质固相分散－高效液相色谱法同时测定大蒜中2-甲基－4-氯－苯氧乙酸、2-甲基4-氯－苯氧丙酸、2-甲基－4-氯－苯氧丁酸3种苯氧羧酸类除草剂残留的方法。

Reductive dechlorination of chlorinated Endocrine Disrupting Chemicals in Water by metallic catalytic reduction was studied for further understanding the application of palladiumized iron-scrap bimetallic catalytic reduction technology in treating high molecular weight and structure complicated refractory chlorinated organic pollutans, especially, the reductive dechlorination reaction of the three chlorinated EDCs: 2,4-dichlorophenoxyacetic acid(2,4-D), Hexachlorocyclohexane, and chlordane.

通过研究水体中有机氯类环境内分泌干扰物在金属催化还原体系中的还原脱氯反应，考察了铁屑镀钯双金属催化还原技术在处理水体中大分子量复杂结构的难降解氯代有机污染物的应用，着重研究了水体中2，4-二氯苯氧乙酸(2，4-D)、六六六和氯丹三种有机氯类环境内分泌干扰物在Pd/Fe催化还原体系中的还原脱氯行为。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

Sodium 2-Acrylarnido-Acetate has been synthesized through the reaction of Aminoacetic acid with acryloyl chlorine, then Copolymer of sodium 2-acrylamido-acetate and dimethyl diallyl ammonium chloride with acrylamide had been prepared by free radical polymerization using (NH4)2S2O8 and NaHSO3 as the free radical initiator in water solution.

本论文首先以氨基乙酸和丙烯酰氯为原料制备丙烯酰胺基乙酸钠单体，然后以丙烯院胺丙烯酰胺基乙酸钠和二甲基二烯丙基氯化铵为单体，(NH4)2S2O8和NaHSO3为自由基引发剂，采用水溶液聚合法合成丙烯酰胺／丙烯既胺基乙酸钠／二甲基二烯丙基氯化铵共聚物。

Amino-6-methoxy Benzothiazole 99%、2-Amino Benzothiazole 99%、Veratraldehyde 99%、Veratric Acid 99%、1,2- Dimethoxy Benzene 99%、6-Nitroveratric Acid 97%、2,5-Dichlorobenzoic Acid 99%、4-Chloro-3-Nitrobenzoic Acid 99%、 3-Nitrobenzole Acid 98%、p-Methoxybenzoie Acid 99%、Anisole 99.5%、p-Methoxyacetophenonc 99%、(2'-Chloroethyl) Benzene 99%、(2'-Bromoethyl) Benzene 99%、N,N-Diethyi-m-Toiuamide 99%、Aminoacetonitrile Hydrochloride 98%、 Alkyl Diphenyl Phosphate Estrel 98%、5-Chloro-2-benzothiazolone 99%、6-bromo-2-naphthol 98%、6-Nitro-Veretric Acid Estrel 97%、4-chloro phenoxyaeetic 99

2-氨基-6-甲氧基苯骈噻唑、2-氨基苯骈噻唑、藜芦醛、藜芦酸、藜芦醚、6-硝基藜芦酸、2，5-二氯苯甲酸、3-硝基-4-氯苯甲酸、3-硝基苯甲酸、对甲氧基苯甲酸、苯甲醚、对甲氧基苯乙酮、β-氯代苯乙烷、β-溴代苯乙烷、N，N-二乙基间甲苯甲酰胺、氨基乙腈盐酸盐、磷酸二苯月桂酯、5-氯-2-苯骈噻唑酮、6-溴-2-萘酚、6-硝基藜芦酸甲酯、4-氯苯氧乙酸

Objective To establish a HPLC method for the determination of aceclofenac in human plasma.Methods Acidified samples of plasma (500μL) were extracted with 4 mL of ethyl acetate. The organic phase was evaporated to dryness by nitrogen at 40℃ water bath. The residue was redissolved in mobile phase and then was determined.

醋氯芬酸是一种具有镇痛作用的非甾体类抗炎药物[1]，化学名为[邻-(2，6-二氯苯基)氨基]苯乙酰乙酸，l992年首先于西班牙上市，具有明显广泛的抗炎作用和强力的解热镇痛作用，其生物半衰期较双氯芬酸长，胃肠耐受性较双氯芬酸好，抗炎活性优于萘普生和保泰松[2]。

Purified sucralose-6-acetate which had been recrystallized was hydrolyzed in th system of sodium methoxide/methanol solution, and the mixture was quenched with H+ ion exchange resin, and cake was washed with methanol. The eluate was concentrated to remove methanol and methyl acetate. The aqueous solution was decoloured with active carbon. The filtrate solution was concentrated and crystallized above 38℃for sever hours, the product sucralose was collected.

重结晶的三氯蔗糖-6-乙酸酯于CH3ONa/CH3OH体系中醇解，用H+型阳离子交换树脂中和，蒸去甲醇、乙酸甲酯等，在水相中用活性炭脱色，水溶液经浓缩，在38℃以上结晶数小时，分离得三氯蔗糖。

Glycidyl benzoate,glycidyl propionate,glycidyl acetate were obtained respectly through a phase-transfer catalytic methodology using sodium benzoate, sodium propionate, sodium acetate and epichlorohydrin as raw materials, and pure products were obtained though vaccum distillation.β-cyclodextrin and glycidyl benzoate, glycidyl propionate, glycidyl acetate, reacted in organic solvent and goal product were

先以苯甲酸钠、乙酸钠、丙酸钠和环氧氯丙烷为原料在相转移催化剂的作用下分别合成了苯甲酸缩水甘油酯、乙酸缩水甘油酯和丙酸缩水酯，经过减压蒸馏，得到相应的纯品；β-环糊精和苯甲酸缩水甘油酯、乙酸缩水甘油酯、丙酸缩水甘油酯在有机溶剂中反应，经过硅胶色谱柱分离，得到了相应的产品，产品经过TLC、IR、1H NMR、MS表征，并研究了温度、反应时间、催化剂等几个因素对反应工艺的影响，结果表明温度和催化剂对反应的快慢有较大影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。