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The influences of reaction temperature and sulfuric acid concentraction on trichloroethylene conversion and chloroacetic acid recovery have been investigated.

研究了三氯乙烯水解法生产氯乙酸的工艺,并在两种不同的实验方案中考察了反应温度、硫酸浓度对三氯乙烯转化率和氯乙酸收率的影响并确定了适宜的工艺参数,可作为工业化生产研究的基础。

The mechanism for chlorinate acetic acid to monochloroacetic acid by using acetic anhydride or sulfur as catalysts respectively was studied.

通过对硫磺和乙酐催化氯化制备氯乙酸反应机理的分析研究,采用硫磺及乙酐复合催化剂,并且对氯化温度、氯化气氛、尾气回收等进行了过程优化,实现了乙酸氯化反应工艺条件的重大突破,使得氯乙酸的收率达到92.1%。

Kinetics of photo-chlorination of acetic acid to form monochloroacetic acid ;2. The mechanism for chlorinate acetic acid to monochloroacetic acid by using acetic anhydride or sulfur as catalysts respectively was studied.

通过对硫磺和乙酐催化氯化制备氯乙酸反应机理的分析研究,采用硫磺及乙酐复合催化剂,并且对氯化温度、氯化气氛、尾气回收等进行了过程优化,实现了乙酸氯化反应工艺条件的重大突破,使得氯乙酸的收率达到92。

With the yield of methyl monochloroacetate as evaluating standard,the synthesized condition of methyl chloroacetate was optimized through orthogonal experiment.

氯乙酸母液和甲醇为基本原料,固载磷钨酸为催化剂,通过连续酯化的方法制备了氯乙酸甲酯;以氯乙酸甲酯的质量收率为基准,采用三因素三水平正交实验的方法对酯合成的条件进行了优化。

As concerning synthesis of 2-ethylhexyl chloroacetate, effects of catalyst dosage, molar ratio of 2-ethylhexanol to chloroacetic acid, reaction time, dosage of water entrainer on esterification rate were studied.

将此固体超强酸酯用于氯乙酸和异辛醇合成氯乙酸异辛酯的酯化反应,考察了异辛醇和氯乙酸的摩尔比、催化剂用量、反应时间、带水剂环己烷的用量对酯化反应的影响。

Chloroacetic acid is a very important intermediate of Pharmaceuticals, dyes, pesticides, cellulose derivatives.

为了控制二氯乙酸的生成,降低氯乙酸的物料消耗,本论文采用连续法合成氯乙酸

The silk-protein-like polymers could be dissolved in hexafluroisopropanol and strong organic acid (e. g., formic acid, dichloroacetic acid and trifluroacetic acid), while they showed a poor solubility in common solvents.

所合成的模拟聚合物难溶于通常溶剂,但可以溶解在强酸溶剂(甲酸、二氯乙酸及三氟乙酸)和六氟异丙醇中;通过在二氯乙酸中25℃下的特性粘度测定而估算出聚合物的分子量在2~5万之间。

A method for synthesizing sodium sulfoacetic is discussed,which sodium sulfoacetic is synthesized with sodium sulfite and ethyl monochloro acetate,with sodium sulfite and chloroacetic acid.

主要分别介绍用亚硫酸钠与氯乙酸乙酯合成磺酸乙酸钠和亚硫酸钠与氯乙酸合成磺酸乙酸钠。

Monochloroacetic acid is a rather important chemical raw material and organic intermediate product, which is mainly manufactured by chloride of acetic acid using sulfur and anhydride acetic acid as catalyst.

氯乙酸是一种及其重要的化工原料和有机中间体,目前氯乙酸主要以硫磺或醋酐为催化剂进行乙酸氯化生产而得。

The influence of reflux rate at the top of tower, light density, ratio of feed and discharge, content of water and ferrous iron in the raw materials were investigated. The output of column was also inspected.

大量二氯乙酸的生成不仅增加了原料消耗,提高了成本,而且由于后续分离困难,使氯乙酸产品质量较低,加之二氯乙酸的用途很少,造成资金和设备的巨大浪费。

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