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氯乙酰苯

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Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水,甘油,氢化聚异丁烯,液体石蜡/矿油,丁二醇,环己硅氧烷,鲸蜡醇,甘油硬脂酸酯,棕榈油,玉米胚芽油,PEG-100硬脂酸酯,白蜂蜡/蜂蜡,肉豆蔻醇肉豆蔻酸酯,石蜡,香精,腺苷,苧烯,山梨醇,CI 14700,CI 19140,稻糠油,杏仁油,EDTA二钠,羟丙基四氢吡喃三醇,苯氧乙醇,聚乙二醇-14M,异十六烷,氢氧化钠,辛基十二醇,季戊四醇四(双-t-丁基羟基氢化肉桂酸)酯,山梨坦三硬脂酸酯,水解大豆蛋白,卡波姆,鸡蛋果籽油,苹果果实提取物,欧洲栗籽提取物,异山梨醇酐二甲醚,聚山梨醇酯-80,辛酰水杨酸,2-油酰胺基-1,3-十八烷二醇,氯苯甘醚,麦芽糖醇,香豆素,黄原胶,微晶蜡,丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物,丙二醇,芳樟醇,香茅醇,玉米油,羟苯丙酯,羟苯甲酯

P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.

丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物,用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2,4-二硝基氟苯2,4-dinitrofluorobenzene,二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应,生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid, DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate, PITC)在弱碱性条件下,与氨基酸反应在弱碱性条件下,生成苯乙内酰硫脲 PTH衍生物,(phenylthiohydantoin, PTH)衍生物,即PTH-氨基酸,此反应又称之Edman反应,该反应是蛋白质或多肽氨基酸序列测定常用的反应。

By using the a device being similar to water segregator and by controlling the temperature, cyclization of the intermediate product in chloroform reduced carbonization and gave 2-dodecaneanthraquinane in 68.1% yielding.

以十二烷基苯和苯酐为起始原料,经酰基化、关环和磺化三步反应合成了3-十二烷基蒽醌磺酸;并进一步改进和优化了合成工艺条件:即在催化剂三氯化铝过量50%并有三乙胺存在的条件下,中间体2-(4-十二烷基苯甲酰基)苯甲酸收率为72.45%;关环反应采用氯仿作溶剂,利用类似分水器的装置有效控制反应温度以减少碳化,2-十二烷基蒽醌的收率为68.1%。

Acylamino acid-5-fluorouracil were prepared from acylamino acid chlorides and 5- fluorouracil in the presence of 〓.

邻苯二甲酰氨基酸酰-5-氟尿嘧啶则由邻苯二甲酰氨基酸酰氯与5-氟尿嘧啶在三乙胺的存在下制得。

Bromo-2′,4′-dichloroacetophenone was synthesized in three steps,w hich were bromization ,chlorination and acylation,from glacial acetic acid and m -dichlorobenzene.

以冰乙酸和间二氯苯为原料,经溴化、氯化、酰化三个步骤,制得 2—溴- 2′,4′-二氯苯乙酮,产率达 70 %。

Purified water, euphorbia cerifera wax, glyceryl stearate, ammonium acrylates copolymer, butylene glycol, copernica cerifera wax, stearic acid, sucrose acetate isobutyrate, acrylates copolymer, bentonite, tromethamine, hexylene glycol, silk amino acids, cholesterol, glycine, synthetic wax, ethylhexyl glycerin, alanine, PEG-9 dimethicone, nylon-6, lecithin, silica, simethicone, caprylyl glycol, xanthan gum, propylene glycol, isostearic acid, sodium laureth-12 slfate, ceteareth-20, polyvinyl alcohol, sodium chloride, sodium acetate, disodium EDTA, benzyl alcohol, chlorphenesin, phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben, isobutylparaben, may contain /- mica, iron oxides (CI 77491, CI 77492, CI 77499), titanium dioxide (CI 77891), ferric ferrocyanide (CI 77150), ultramarines (CI 77007), blue 1 lake (CI 42090), bronze powder (CI 77400), aluminum powder (CI 77000), bismuth oxychloride (CI 77163), carmine (CI 75740), chromium hydroxide green (CI 77289), chromium oxide greens (CI 77288), yellow 5 lake CI 19140

水,小烛树蜡,硬脂酸甘油酯,丙烯酸铵共聚物,1,3-丁二醇,巴西棕榈蜡,硬脂酸,异丁酸醋酸蔗糖酯,丙烯酸酯共聚物,蒙脱土,二吡喃乙酸乙酯胺,已烯醇,丝氨酸,胆固醇,甘油,合成蜡,异丁基甘油,丙胺酸,PEG-9二甲基硅油,尼龙-6,卵磷酯,硅粉,硅氧烷,癸酰基乙二醇,汉生胶,丙二醇,异硬脂酸,月桂基醚-12硫酸钠,十六十八醇醚-20,聚乙烯醇,氯化钠,醋酸钠,EDTA二钠,苯氧乙醇,氯代苯酚,卞醇,尼泊金甲酯,尼泊金乙酯,尼泊金丙酯,尼泊金丁酯,尼泊金异丁酯,[可能还含有云母,铁黑(CI 77491, CI 77492, CI 77499),钛白粉(CI 77891),氰化亚铁(CI 77150),靛蓝(CI 77007),蓝1号(CI 42090),青铜粉(CI 77400),铝粉(CI 77000),氯氧化铋(CI 77163),洋红色素(CI 75740),氢氧化铬绿(CI 77289),氧化铬绿(CI 77288),黄5号(CI 19140)]文章来自网络,不代表本网站立场,版权归原作者所有,转载请注明出处!

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能,共由以下六部分组成:1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应;2、亚甲基环丙烷类化合物开环产物的偶联反应;3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应;4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应;5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应;6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1,3-偶极环加成反应。

Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.

2以邻氨基苯甲酸、草酸乙酯酰氯和乙二胺(或1,2-丙二胺)缩合制得了两种具有不对称草酰胺结构配体N-(2-苯甲酰基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲酰基)-N&-(2-氨丙基)草酰胺(H3oxbt),并得到了它们的单核配合物:Na·1.5H2O和Na·1.5H2O。

Tris-(1-aziridinyl)- phosphine oxide and 2-[bis-(2-chloroethyl)-amino]-tetrahydro-1, 3, 2-oxazaphospholidine-2-oxide(Ⅲ, B-518) possess inhibitory action against a variety of animal tumours and have been used clinically. Recently, bis-(1-aziridinyl)-phosphinyl carbamic acid ethyl ester(Ⅱ, AB-100) was found to possess significant activity with low toxicity on experimental animal tumours.

双(2-氯乙基)氨基磷酰二氯与乙烯亚胺在脱水苯或对氧六环中并在三乙胺的存在下进行缩合,生成N,N-双(2-氯乙基)-N′,N-二乙烯基-磷酰胺;与双巯基或双氨基化合物作用,则生成相应的环状磷酰胺、磷酰胺酯以及磷酰胺硫代酯氮芥类化合物。

In the third step, when the ratio of racemic ester to benzenesulfonyl chloride to triethylamine to catalyst 4-DMAP is 1:1:1:0.1 in 10℃, the yield is 82.9% and high purity is obtained by crystallisation.

在第三步磺酰化反应中,得到合成消旋2-苯磺酸基-2(2-氯苯基)乙酸甲酯的较佳反应条件为邻氯扁桃酸甲酯:苯磺酰氯:三乙胺=1:1:1,催化剂4-DMAP用量为摩尔反应物的10%,反应温度为10℃,收率为82.9%,同时用结晶方法获得高纯度的产物。

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