氮苯酰胺

Electron-withdrawing groups (F, CF 3 ) decreased the efficiency of the transformation, which has as byproducts benzonitrile and phenethyl N -acetamide.

电子集团撤回(六，比照3)转换效率降低，而作为副产品和苯氮苯甲-乙酰胺。

To improve the cyano reactivity, cyano-terminated PPENs were prepared by the end-capping reaction of PPEN-OL with CBN; benzonitrile terminated polys were also prepared by the polycondensation of excess 4,4'-oxydianiline with 1,2-dihydro-2-(4-carboxyphenyl)-4-[4-(4-carboxyphenoxyl)phenyl]-phthalazinone, followed by end-capping with CBA. The polymers synthesized exhibited good solubility in NMP, DMAc and DMF, and were crosslinked to afford phenyl-s-triazine-containing polymers under the similar conditions.

为提高氰基活性，以对氯苯腈为原料，对PPEN-OL进行封端，设计合成了含氰端基的聚芳醚腈；以含二氮杂萘酮联苯结构二酸单体与4，4'-二氨基二苯醚为原料，经Yamazaki膦酰化缩聚，并用对氰基苯甲酸进行封端，合成了含氰端基的聚芳醚酰胺。

The results indicate that the carbon and the oxygen in the —COOH group,and the nitron in —2—NH group come into formation of different large π bonds with the benzene rings,and there is a dihedral angle of 63.2° because of place blocking and conjugate effect.

结果显示，该分子羧基的碳氧原子、磺酰胺基的氮原子与苯环形成不同的离域大π键，空间位阻效应和共轭效应使两个苯环不在同一平面，二面角为63.2°。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

This paper describes the photochromism and thermal back-isomerization of 4-undecylen-[10]-amidoazobenzene and its homo-and copolysiloxanes in solution and solid film.

本文研究了对十一烯酰胺基偶氮苯及其硅氧烷均聚、共聚的梳状聚合物在溶液或薄膜状态下的光致变色性和热回复性。

P-π conjugated polyamic acid was synthesized by the poly-condensation of benzoguanamine and pyromellitic dianhydride under microwave irradiation. Then PAA was grafted with different side-chain containing azobenzol groups through azo coupling reaction.

选取苯代三聚氰胺和均苯四酸二酐为单体进行微波辐射溶液聚合反应，所得的聚酰胺酸与对位取代基不同的苯胺重氮盐偶合接枝，从而合成了一系列新的具有三阶非线性光学活性的侧链型聚合物。

In the fifth chapter, six compounds formed between nitrogen-containing ligands such as 2, 2'-bipyridyl, isonicotinamide and 1, 4, 8, 11-tetraazacyclotetradecane and the solution cadmium sulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate, 4, 4'-bipenyldisulfonate and 4, 4'-penyletherdisulfonate have been synthesized and structurally characterized. Besides, another compound has been synthesized with cadmium carbonate reacting with 1, 5-naphthalenedisulfonate acid.

第五章以2，2'-联吡啶、异烟酰胺和1，4，8，11-四氮杂环十四癸烷与含有Cd〓和1，5-萘二磺酸根离子、2，6-萘二磺酸根离子、4，4'-联苯二磺酸根离子和4，4'-苯醚二磺酸根离子的水溶液反应，合成了六个化合物，另外以1，5-萘二磺酸与碳酸镉反应合成出一个化合物。

Polyelectrolyte hydrogels based on n -alkyl methacrylate esters,acrylic acid and acrylamide cross-linked with 4,4′-diazobenzene were prepared.

合成了不同疏水链长的甲基丙烯酸酯、甲基丙烯酰胺及丙烯酸与 4 ，4′-二偶氮苯交联共聚的聚电解质凝胶。

A plausible process of this reaction is as following: Aldehyde was in equilibrium with the enol form, aldehyde reacted with aniline catalyzed by 2,2,2-trichloroacetic acid to afford imine, the generated imine immediately reacted with enol to form intermediate via intramolecular cyclization.

我们发现一分子芳基叠氮和一分子三苯基磷反应生成一分子磷亚胺，后者与由两分子取代的苯氧乙酰氯原位生成的烯酮反应生成4-亚烷基-β-烷基-内酰胺，其串联过程涉及烯酮亚胺的形成及其与烯酮的[2+2]的环加成反应。

The results show that during the development of the oriental tobacco leaves, the activity of acid invertase was decreased; the changes of GS reached its peak in the 20dans in Samsun, but in the 30dans in Basma and Canik ;the activity of PAL was decreased in the 30dans; The content of total nitrogen was decreased with the mature leaves, but nicotine、total carbon and soluble total sugar were increased. Different varieties, carbon and nitrogen metabolism key enzyme activity and the content of metabolites were different.

结果表明，在香料烟叶片发育过程中，酸性转化酶的活性均呈下降趋势；谷氨酰胺合成酶的活性Samsun品种在20d叶龄时最高，而Basma和Canik在30d叶龄时最高；苯丙氨酸解氨酶的活性均表现为30d时最低；随着叶片成熟总氮含量降低，烟碱含量升高，总碳、可溶性总糖随着叶片成熟其含量呈升高趋势；品种不同，碳氮代谢关键酶的活性及代谢产物的含量变化均有很大差异。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。