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In a DMF solution of CuCl〓-ethanolamine-acetic acid (1: 2: 2), 27 formed a highly oxidized heterocyclic compound 2-hydroxymethyl-naphtho [1, 2-a] oxazole (30) by the carbon-nitrogen coupling and carbon-oxygen coupling with the ligand of ethanolamine, which brings a chance to develop a novel approach to this heterocyclic compound via one-pot reaction of phenols under mild condition.

在氯化铜—乙醇胺—乙酸(1:2:2)的DMF溶液中,27与配体乙醇胺发生碳氮偶合与碳氧偶合,生成深度氧化的杂环化合物:2-羟甲基-萘并[1,2-a]〓唑(30)。这可望为酚类一锅化直接转化为30及其类似物提供一种简便的新合成路线。

Piperidine oxoammonium salts oxidize aromatic amines and N, S-containing heterocycles to the corresponding radical cations, and the isotope effects in electron transfer reactions between thianthrene and N-methylphenothiazine radical cations and their respective neutral parent molecules have been reported for the first time.

啶氧铵盐氧化芳95胺和含氮、硫芳杂环为相应的自由基正离子,首次报道了及甲基吩自由基正离子与其中性母体之间电子转移的同位素效应。

Piperidine oxoammonium salts oxidize aromatic amines and N, S-containing heterocycles to the corresponding radical cations, and the isotope effects in electron transfer reactions between thianthrene and N-methylphenothiazine radical cations and their respective neutral parent molecules have been reported for the first time.

哌啶氧铵盐氧化芳香胺和含氮、硫芳杂环为相应的自由基正离子,首次报道了噻蒽及甲基吩噻嗪自由基正离子与其中性母体之间电子转移的同位素效应。

Amphiphilic graft copolymers were synthesized by the copolymerization of polyoxyethylene macromer with butyl acrylate and methyl methacrylate in benzene using azobisisobutyronitrile as initiator.

以偶氮二异丁腈为引发剂,将大单体聚环氧乙烷与小单体丙烯酸丁酯、甲基丙烯酸甲酯在苯溶液中进行共聚,合成了两亲性接枝共聚物。

Agriculture maize as Indicator plant, by raising it in soil with acetochlor, to study the herbicide antidote N-dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane on protect maize residual damage from acetochlor.the result of experiment is: the growths of maize is lower than comparison value.

以垦玉6号玉米为指示材料,采用土培法研究了除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷减轻除草剂乙草胺对玉米产生的残留药害。实验结果表明:在施用不同浓度的乙草胺土壤中,玉米植株的各项生长指标均低于空白对照值。

The herbicide antidote N-dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was tested on protecting maize residual damage from chlorimuron by 6 agriculture maize as indicator plant in water with chlorimuron.

以垦玉6号玉米为指示材料,采用水培法研究了除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷减轻除草剂氯嘧磺隆对玉米产生的残留药害。

The inhibition effect of 2,2,6,6-tetramethyl-4-hydroxylpiperidine-oxyl and some phenols and quinones on the AIBN initiated radical polymerization of styrene was studied by using dilatomitry method.

用膨胀计法,研究了2,2,6,6-四甲基-4-羟基哌啶氧自由基及一些醌、酚类化合物对偶氮二异丁腈引发的苯乙烯自由基聚合的阻聚效应。结果表明,当 St在80℃聚合时,加入TMHPO·或TMHPO·-BQ,阻聚效果较为显著。

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