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氮族

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Homogeneous or heterogeneous base material is selected; an alternately superimposed barrier layer and an alternately superimposed recessed layer are grown and formed at the extension of the base material; donor impurity and acceptor impurity are doped in the interface between the barrier layer and the recessed layer and in the interface between the recessed layer and the barrier layer, and the p type group III nitride material doped at a position selecting superlattice is obtained.

选择同质或者异质的基质材料;在基质材料上外延生长形成变换叠加的垒层和阱层,在垒层与阱层的界面和阱层与垒层的界面掺入施主杂质和受主杂质,得选择超晶格位置掺杂的p型III族氮化物材料,其中,每个生长周期的步骤为:生长带隙较宽的垒层,同时掺入受主杂质;生长施主杂质或受主杂质δ掺杂层;生长非掺的带隙较窄的阱层;生长受主杂质或施主杂质δ掺杂层;在N 2 气氛下对所得的选择超晶格位置掺杂的p型III族氮化物材料退火,即得目标产物。

The paper discloses a process for diazotization fluorination of aromatic primary amines utilizing sodium nitrite and anhydrous hydrofluoride to produce the corresponding diazonium fluoride which is decomposed, usually by heat, to make the desired fluoroaromatics .

本文通过重氮化工艺路线的改进,在液态氟化氢中进行重氮化和重氮盐的热分解,提高了芳香族氟化物的收率,并且使重氮化反应工艺能应用于工业化生产。

Diazonium salt which was formed by reaction of diazotization of eldest aromatic amine then coupling with N-(1-naphthyl)-ethylenediamine dihydrochloride,in NH_3·H_2O-NH_4Cl solution showed a sensitive polarographic wave at peak potential of 0.58vs,SCE.

本文报道了芳香族伯胺的重氮-偶氮化反应所生成的偶氮化合物在NH_3·N_2O-NH_4Cl底液中,在单扫描极谱上,峰电位-0.58V

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中,本发明是引发自由基聚合的体系,包括:a在一个部分中,一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物,其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物,例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上,和b在第二部分中,在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

Six kinds of phenyl hydrazone s were synthesized by the reaction of ice bath using aromatic dia- zonium salt and active methylene compounds.

在冰盐浴条件下,芳香族重氮盐与活泼亚甲基化合物反应,合成了六种新芳香族腙类衍生物。

According to Griess reaction, diazonium-salts formed from aromatic amines such as sulfonamides etc., react with NaNO_2 in acid medium and may be coupled with α-naphthylamine or diphenylamine to produce red colored compounds.

一按Griess反应芳香族胺类的重氮化鹽,如对氨基苯磺醯胺类药物等,在酸性溶液中皆能与α-萘胺或二苯胺分别偶合成偶氮色素而显紅色,过多之亞硝酸可与氮色素再作用使紅色消失而呈棕黄色。

A multivalent nonmetallic element of the nitrogen family that occurs commonly in inorganic phosphate rocks and as organic phosphates in all living cells; is highly reactive and occurs in several allotropic forms.

一种多价的氮族非金属元素,通常见于无机磷酸盐岩石中或作为有机磷酸盐存在于活细胞中,极其活跃,有多种同素异形体。

Biogenic amines are basic nitrogenous compounds formed mainly by decarboxylation of amino acids or by amination and transamination of aldehydes and ketones.

生物胺是一类含氮的脂肪族、芳香族或杂环类低分子化合物,主要是通过氨基酸的脱羧或醛和酮的胺化和转氨基作用形成的。

Examples of metal chelating groups include hydroxides especially aryl or heteroaryl hydroxides such as phenolic hydroxides; amines which may be aliphatic aryl or heteroaryl; mercaptans which may be aliphatic aryl or heteroaryl; carboxylic acids which may be aliphatic aryl or heteroaryl; oximes and ketoximines; acetarylamides; hydroxy silanes and silicones; N-containing heterocycles such as imidazoles benzimidazoles triazoles benzotriazoles thiazoles isothiazoles acid anhydrides and more preferably acid groups (especially carboxylic acid groups phosphoric acid groups polyphosphoric acid groups phosphonic acid groups sulphuric acid groups and sulphonic acid groups).

金属螯合组的例子包括氢氧化物,特别是芳基或如酚醛氢氧化物杂氢氧化物;胺可能是脂肪族,芳基或杂;硫醇可能是脂肪族,芳基或杂,这可能是脂肪族,芳基或羧酸杂;肟和ketoximines; acetarylamides;羟基硅烷和有机硅,含N,如咪唑,苯并咪唑类,三唑类,苯并三氮唑,噻唑类,isothiazoles,酸酐杂环,多最好酸组(特别是羧酸团体,磷酸,团体,多聚酸组,膦酸组,硫酸团体和磺酸组)。

Solid poisonous element in the nitrogen family,usually gray or yellow,brittle and crystalline.

氮族化和物中的著名毒物,通常呈灰色或黄色,易碎结晶体。

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