氮化的

A series of azobenzenes with different electron effect substituents were prepared from diazonium salts and benzoguanamine.

将含有不同取代基的芳胺在盐酸介质中进行重氮化反应，制得相应的重氮盐，再与苯代三聚氰胺发生偶合反应，最终得到一系列含有不同取代基的偶氮化合物。

Chapter two: Using 5-(4-aminophenyl)-10,15,20-triphenylporphyrin as thestarting compound, the classical diazotization of aniline and the resulting reaction ofdiazo salts were applied to porphyrin for the first time, and a series of asymmetriclysubstituted meso-tetraarylporphyrins including 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin, 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin, 5-(4-cyanophenyl)-10,15,20-triphenylporphyrin, 5-(4-bisphenyl)-10,15,20-triphenylporphyrin and 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin were synthesized.

第二章：在已合成的5-(4-氨基苯基)-10，15，20-三苯基卟啉基础上，首次将芳胺的重氮化及重氮盐反应应用于卟啉，合成了5-(4-氯苯基)-10，15，20-三苯基卟啉、5-(4-碘基苯基)-10，15，20-三苯基卟啉、5-(4-氰基苯基)-10，15，20-三苯基卟啉、5-(4-联苯基)-10，15，20-三苯基卟啉和5-(4-羟基苯基)-10，15，20-三苯基卟啉等一系列不对称取代的meso-四芳基卟啉。

After esterification, the ethyl-2-chloro-3-phenylpropionate reacts with diethyl malonate under the catalysis of sodium ethylate, and we obtain the corresponding triethyl ester. The-benzylsuccinic acid is formed by the triethyl ester reacting with concentrate hydrochloric acid and taking place hydrolyzation and decarboxylation reaction at the same time. In order to avoid the formation of cinnamic acid, the sodium ethylate and diethyl malonate must be react sufficiently. The course has simple operation, inexpensive materials and better yield.

具体制备工艺为：首先以L-苯丙氨酸为原料采用重氮化方法得到-2-氯-3-苯基丙酸，再经酯化得到-2-氯-3-苯基丙酸乙酯后在乙醇钠催化作用下和丙二酸二乙酯缩合，发生SN2反应，得到相应的三乙酯，然后经水解和脱羧，得到-苄基丁二酸；在实验中乙醇钠要和丙二酸二乙酯充分反应，避免生成肉桂酸乙酯；该过程操作简单，原料便宜，产率较高，总收率可达到26.8%。

Both forming gas and SiN capping can effectively passivate interface states, and result in threshold voltage difference.

氮氢混合气体退火和具有氮化矽覆盖层的元件都可以有效地修补界面的缺陷，但是二者具有不同的临界电压。

The results show that the new fluid nitriding process, which the key component is the fluid bed reactor, could make synthesis condition assuasive, low cost and good effect.

结果表明：以流化床反应器为核心的流化氮化新工艺合成条件温和、原料成本低、效果好。

The experimental results from cyclic voltammetry and constant-potential electrolysis show that the mechanism of the reaction was two molecules and three steps electrochemical process with eight-electrons transferred: anion radical arose in the first step; two-electrons were transferred in the second step and accompanied with coupling reaction of radicals and protonation and dehydrate, the main product was azoxybenzene; two-electrons were transferred in the third step, and azobenzene was achieved.

研究结果表明，硝基苯在铂电极上的电还原反应为双分子八电子三步骤电化学过程：第一步反应为准可逆单电子转移步骤，产生阴离子自由基；第二步为二电子转移步骤，并伴有随后的双分子不可逆自由基偶合反应和快速质子化及脱水反应，主要产物为氧化偶氮苯；第三步是二电子转移产生偶氮苯的过程。

The permanent magnets of single-phase exchange coupling Nd 〓N〓 and Nd 〓N〓 with ThMn〓 structure have been prepared by MM and MA process and the following treatments of crystallization、nitrogenation. By means of XRD、SEM、TEM、DTA/DSC and magnetic measurements, the variations of microstructure in each corresponding stage and the related magnetic properties have been studied systematically.

本文采用机械合金化和机械研磨法及随后的晶化、氮化处理分别制备了具有ThMn〓结构的Nd〓N〓单相耦合及Nd〓N〓纳米永磁材料，借助于X射线衍射、扫描电镜、电子探针、透射电镜、差热分析以及磁测量等分析技术系统地研究了上述工艺各阶段对应的组织结构的变化以及它们与磁性能的相互关系。

Therefore, it can attribute quality of passivation layer of SiN.

因此，可以全面的表征氮化硅钝化层质量。

There is an activation process for passivated alumina supported molybdenum nitride and carbides catalysts at the initial stage of hydrazine decomposition.

在肼分解反应初期，钝化态的氮化钼和碳化钼催化剂有一个活化的过程，随着启动次数的增加，催化剂的初活性逐渐提高，最后达到稳定。

In the thesis, we report the GaN vertical light emitting diodes with micro lens array and surface roughening.

在本篇论文中，主要是探讨垂直式氮化镓发光二极体在表面制作微米透镜阵列与表面粗化的制成技术与特性量测。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。