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At present, traditional means namely neutralization is usually used to treat these acids in order to meet production requirements, which means great waste of acid and alkali, As to high concentration of ammoniacal nitrogen, since there is no economic and feasible means yet, it is usually discharged directly without any treatment, which has great effects on the surrounding environment.

目前,对这部分酸传统的处理方法是通过加碱中和以达到工艺要求,酸碱浪费极大,而对于生产过程所排的高浓度氨氮,由于尚未有经济可行的处理方法,一般是未加任何处理就直接排放,对稀土冶炼厂周边环境的影响不容忽视。

ABSTRACT In the process of rare earth production, large amount of sulfuric acid, hydrochloric acid and ammonia are consumed, However, there are large amount of sulfuric acid, hydrochloric acid or ammoniacal nitrogen in solutions or discharged waste water which need to be treated.

稀土冶炼过程中,一方面大量使用硫酸、盐酸及氨等化工原料,另一方面,在生产过程的某些中间环节或排放的废水当中,又含有大量的硫酸、盐酸或氨氮化合物需要处理。

Results: The changes following hydrocortisone intervention of rats could be identified by PCA, and the kidney deficiency syndrome rats entered a state of "hyperfunction", involving a series of changes in metabolic pathway and metabolic network. The response integral area of lactic acid (δ 1.37) increased, indicating the accumulation of metabolites of lactic acid. The amount of dimethylamine (δ 2.72) also increased, indicating that the disorder of kidney function was related to kidney-deficiency syndrome. The response of creatinine (δ 3.87), asparaginic acid (δ 2.83), taurine (δ 3.44, 3.28), and hippurate (δ 7.84, 7.56, 7.64, 3.97) all decreased significantly, indicating that the hydrocortisone might cause adrenal cortex excretion injury. The response integral area of succinate (δ 2.41) and citric acid (δ 2.53, 2.68) decreased, which was usually caused by disorder of the mitochondrial function.

结果:PCA方法处理肾虚证和空白对照大鼠尿液数据显示,两组大鼠的数据可以在得分图实现分类,与对照组比较肾虚组大鼠由于氢化可的松诱导,大鼠机体进入一个过消耗后衰弱的状态,相关代谢发生显著变化,乳酸(δ 1.37)代谢发生堆积;二甲胺(δ 2.72)的含量增加,提示肾虚与肾功能异常是密切相关的;天冬氨酸(δ 2.83),牛磺酸(δ 3.44, 3.25),马尿酸(δ 7.84, 7.56, 7.64, 3.97),肌氨酸(δ 3.87)等的相对积分面积明显下降,这预示糖皮质激素可能引起了肾上腺皮质分泌功能的损害;琥珀酸(δ 2.41)和柠檬酸(δ 2.53, 2.68)是三羧酸循环能量代谢及糖酵解的中间产物,其含量的降低,通常是由于线粒体功能紊乱所引起。

Compared with the temperature of 25℃, the difference of the enzyme activity of SOD and POD, contents of PRO and REL of Festuca Lolium perenne L. and Cynodon dactylon at the temperature of 5℃ had been studied. The results showed that the 4 indexes above had less difference at the temperature of 25℃; after 20h treatment at the temperature of 5℃, the activities of SOD of Lolium perenne L.

用5℃低温处理黑麦草和狗牙根,并以25℃为对照,比较低温胁迫下,黑麦草和狗牙根超氧化物歧化酶、过氧化物酶、脯氨酸和电导率的差异,结果表明,25℃时上述5个指标差别不大,5℃处理20h时,黑麦草和狗牙根的SOD活性均达到峰值,分别为处理4h时的2.88倍和2.87倍,但24h后狗牙根的SOD活性减少速率明显大于黑麦草。

The results showed that all contents were lower in male sterilie anthers than in fertilisable ones.With anther developing,the contents of soluble starch,protein and free proline increased obviously in male fertilizable anthers,but not in sterile ones.

结果表明:太空诱变处理玉米核不育材料的可育株花药中的可溶性糖、淀粉、蛋白质以及游离脯氨酸含量均高于不育株花药的,且可育株花药中的可溶性淀粉、蛋白质和脯氨酸含量都随着花药的发育逐渐累积,在不育株花药中这些指标的变化不明显。

The study was conducted to investigate the effects of heat treatment on flesh leatheriness of cold-stored loquat fruits and the possible mechanisms. Freshly harvested loquat fruits were pre-treated with hot air at 38℃ for five hours and then stored at (1±1)℃ for 35 days. Fruits firmness, extractable juice rate, the activities of phenylalanine ammonium-lyase, peroxidase, polyphenol oxidase and polygalacturonase that were related to flesh leatheriness, and contents of lignin and pectin were analyzed at seven-day intervals during storage.

为阐明热处理对冷藏枇杷果实木质化败坏的影响及其机理,该研究先将枇杷果实用38℃热空气处理5 h,然后在(1±1)℃下贮藏35 d,并每隔7 d测定果实硬度、出汁率、苯丙氨酸解氨酶、过氧化物酶、多酚氧化酶和多聚半乳糖醛酸酶等木质化相关酶活性及果胶和木质素含量的变化。

As a kind of low-priced nonmetallic mineral, zeolite has good selective adsorption ability for NH4+-N. Modifying can even increase this capacity. Clinoptilolite and mordenite have much applying prospect in this aspect. The research on NH4+-N removal with natural zeolite is sufficient in many countries.

沸石是一种廉价的非金属矿物,对氨氮具有较高的选择吸附性,通过改性处理能大大提高其对氨氮的去除能力,特别是斜发沸石和丝光沸石在这方面有很好的应用前景。

Long running performance showed that due to the membrane interception,the nitrobacter is enriched in reactor in the interest of improving the nitrification rate;the maximum ammonia nitrogen loading can be 0.19 kg/(m3·d) with effluent ammonia nitrogen<1 mg/L (removal rate 99%).

采用浸没式膜生物反应器处理焦化废水的试验结果表明:膜的截留作用可使硝化菌在反应器内富集而有利于提高系统的硝化能力,其去除氨氮的最高负荷为0.19kg/(m3·d),出水氨氮<1mg/L(去除率为99%);泥龄长可能使微生物的代谢产物或其他大分子物质积累,从而

Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.

第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂,着重考察了CTSB—G—Hy的制备条件,并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件,结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4~6.5之间,吸附剂用量为5g/L,吸附时间为1h时pb~(2+)去除率高于94%,CTS—PA_4可在酸性条件下使用,在碱性条件下依然有效但处理效果较差;CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L,吸附时间为1h时处理效果极佳,pb~(2+)去除率高于96%;CTSB—G—Hy对pb~(2+)具有一定的吸附能力,吸附剂用量为3g/L,吸附时间为1.5h时处理效果最佳,Pb~(2+)去除率高于93%,而且CTSB—G—Hy的机械强度高,耐酸碱性强,可在较宽的pH范围内使用。

Changes of leaf pigment content,soluble sugar content,enzyme activity and photosynthesis characters in leaf of Photinia×frasery"Red Robin"were searched of five different shading treatments(100%,80%,50%,25%,10%transmission rate).The seasonal variation of leaf color and stability of anthocyanin were studied in this paper.Purpose of the research is to master the Physiological characters during leaf color transformation of Photinia×frasery"Red Robin",and provide evidences to promote introduction cultivation and the application under different garden environment of them.

本文以2年生红叶石楠(Photinia×frasery'RedRobin)扦插苗为试材,探讨了不同遮光处理透光率分别为100%(全光照、80%、50%、25%、10%条件下叶片色素含量、可溶性糖含量、苯丙氨酸解氨酶活性、抗氧化酶活性变化及光合作用日变化,同时对其叶色的季节变化及花色素苷的稳定性进行了初步探讨,以掌握红叶石楠叶色变化的生理特征,为红叶石楠的广泛引种栽培及在不同园林环境中的应用提供科学依据。

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