氨基联苯

Synthesis and Property Study of 4, 4'-Bis(4-aminophenoxy)-3, 3', 5, 5'-tetramethyl Biphenyl and Polyimide Therefrom

篇名 4， 4'-双（4-氨基苯氧基）－3， 3'， 5， 5'-四甲基联苯及其聚酰亚胺的合成与性能研究

Aminobenzoic acid was used to synthesize 4'-methyl-2-cyanobiphenyl, which was one of medicine intermediates, by diazotization, acylation, substitution, and dehydration.

以邻氨基苯甲酸为起始原料，经重氮化、芳基化、取代和脱水等步骤合成药物中间体4'-甲基－2-腈基联苯。

An aminobenzene sulfonate-formaldehyde based polymer dispersant with good grinding efficiency was synthesized under alkaline condition using aminobenzene sulfonate, phenol and formaldehyde as main raw materials.

以对氨基苯磺酸、苯酚、甲醛为主要原料，采用碱性合成线路制备了具有助磨效果的氨基磺酸系高效减水剂，系统地研究了单体比例、单体浓度、交联剂用量、反应体系初始pH值、反应时间和反应温度等因素对助剂助磨效果的影响。

Ternary copolymer ammoniacal latex was obtained using the reaction of nitration and reduction reaction.

通过硝化反应与还原反应在苯乙烯的苯环上接上氨基，利用重氮化反应将登革热抗体与之相交联制成登革病毒胶乳凝集免疫诊断试剂。

In order to synthesize the functional polyquinolines (such as proton conducting polyquinolines and optically active polyquinolines) and investigate structure-property relationships, polyquinolines and polyanthrazolines containing isomeric pyrrole units or 1, 1'-binaphthyl in main chain were synthesized and their properties were studied.

建立了二乙酰吡咯的合成方法；合成并表征了四种二苯酰基-二氨基单体和五种新型的含吡咯基或联萘基的二乙酰基单体；并对部分合成方法进行了改进，简化了实验步骤，提高了产率。

Up to 95.01% yield of 2-amino-2'-hydroxy-1,1'-binaphthyl was obtained in chlorobenzene using the oxidant with 10% FeCl3 loading on the support containing 5% TiO2 at 60 ℃. The activity of the used oxidant was improved by treatment with H2O2, which provided an effective method to regenerate the solid-oxidant.

结果表明：在60 ℃，氯苯作溶剂的情况下，含TiO25%的载体，负载10% FeCl3时2-氨基-2'-羟基-1，1'-联萘的收率最高达到了95.01%；用过的固体氧化剂经H2O2氧化处理后活性明显恢复，证明此法是一条循环再生的有效途径。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法，其反应混合物包括：一种含至少85重量％的4，4′－二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分，一种多元醇组合物，其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量％之间的聚氧亚烷基多元醇，水，一种平均羟基当量为15至250之增链剂，以及视需要使用的交联剂，该硬性嵌段－含量（hardblock-content）大于45重量％。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶体结构研究表明配体H4L为顺式桥联分子，晶体中存在两种氢键，一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2)，∠O-H…O=151.8°]；另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2)，∠N-H…O=158.7°]，通过上述两种氢键将化合物H4LB连接成二维网络结构。

It is shown that the optimal conditions for the reaction of CADB with SESA are pH 12.0 and m:m=6:1.The product p-aminobenzart sulfanily ethyl CADBwas diazotized and linked with lipase.The optimal pH for lipase linked to diao-compound is 7.5.The link time is at last 12h.

试验结果表明：CADB与SESA反应的最适条件是pH＝12.0，SESA与CADB质量比为6：1，反应生成的对氨基苯磺酰乙基交联烯丙基葡聚糖凝胶经重氮化后与脂肪酶偶联的最适条件是pH7.5，偶联时间≥12h。

Three phosphorus-containing polybibenzimidazoles, namely, poly [2,2'-di-p-phenylene methyl phosphine oxide-5,5'-bibenzimidazole], have been prepared by condensing 3,3'-diaminobenzidine with di-(p-carboxy phenyl) methyl phosphine oxide.

用双烷基氧膦与3，3'-二氨基联苯胺缩聚，合成了三个在主链上带有联苯并咪唑和氧化三烃基膦结构的高分子化合物。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。