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A novel fluorescent acrylamide monomer, N-(4-Benzooxazol-2-yl-phenyl)- acrylamide, was prepared from o-aminophenol, p-aminobenzoic acid and acryloyl chloride, with polyphosphoric acid as dehydrating agent and triethylamine as deacidification agent.

以邻氨基苯酚、对氨基苯甲酸和丙烯酰氯为原料,以多聚磷酸为脱水剂、三乙胺为脱酸剂,研制了一种新的荧光丙烯酰胺单体N-[4-(苯并噁唑-2-)苯基]丙烯酰胺。

Two novel pyrazolone derivatives 2-ethylamino-6H-5-(1-phenyl-3-methyl/phenyl-5-pyrazolone-4-ylene)-1,3,4-thiadiazine (PMCP-ETSC/DPCP-ETSC) containing NNS six-membered heterocycles were synthesized by the condensation reaction of 1-phenyl-3-methyl/phenyl-4-chloroacetyl-pyrazolone-5 with 4-ethyithiosemicarbazide. The title compounds were characterized by elemental analysis, IR, 1H NMR, 13C NMR and single-crystal X-ray diffraction.

利用1-苯基-3-甲基/苯基-4-氯乙酰基-吡唑啉酮-5与4-乙基氨基硫脲发生缩合反应,生成了2个新的双杂环化合物2-乙氨基-6H-5-(1-苯基-3-甲基/苯基-5-吡唑啉酮-4-基)-1,3,4-噻二嗪(PMCP-ETSC/DPCP-ETSC),并对其进行元素分析、红外光谱、核磁共振表征和晶体结构分析。

The present invention concerns the compounds having the formula N-oxides, salts, stereoisomeric forms, racemic mixtures, prodrugs, esters and metabolites thereof, wherein R1 and R8 each are H, optionally substituted C1-6alkyl, C2-6alkenyl, C3-7cycloalkyl, aryl, Het1, Het2; R1 may also be a radical of formula (R11aR11b)NC(R10aR10b)CR9-; t is 0, 1 or 2; R2 is H or C1-6alkyl; L is -C-,-O-C-,-NR8-C-,-O-C1-6alkanediyl-C-,-NR8-C1-6alkanediyl-C-,-S2-,-O-S2-,-NR8-S2 ; R3 is C1-6alkyl, aryl, C3-7cycloalkyl, C3-7cycloalkylC1-4alkyl, or arylC1-4alkyl; R4 is H, C1-4alkylOC, carboxyl, aminoC, mono- or di(C1-4alkyl)aminoC, C3-7cycloalkyl, C2-6alkenyl, C2-6alkynyl or optionally substituted C1-6alkyl; R5 and R6 are H or C1-6alkyl.

本发明涉及右式化合物其N-氧化物、盐、立体异构形式、外消旋混合物、前药、酯及代谢物,其中R 1 及R 8 各是氢、C 1-6 烷基、C 2-6 烯基、C 3-7 环烷基、芳基、Het 1 、Het 2 ;R 1 也可以是式(R 11a R 11b )NC(R 10A R 10b )CR 9 -之基;t是0、1或2;R 2 是氢或C 1-6 烷基;L是-C-、-O-C-、-NR 8 -C-、-O-C 1-6 烷二基-C-、-NR 8 -C 1-6 烷二基-C-、-S 2 -,-O-S 2 -、-NR 8 -S 2 -;R 3 是C 1-6 烷基、芳基、C 3-7 环烷基、C 3-7 环烷基C 1-4 烷基或芳基C 1-4 烷基;R 4 是氢、C 1-4 烷基OC、羧基、氨基C、一-或二(C 1-4 烷基)氨基C、C 3-7 环烷基、C 2-6 烯基、C 2-6 炔基或任选被取代的C 1-6 烷基;R 5 及R 6 是氢或C 1-6 烷基。

The Company has been established for 20 years, and is continuously specialized in precise galvanization, coupling and lead frame galvanization, printed wiring board galvanization, hardware galvanization, nickel cobalt alloy electrolytic casting, profession products, and aluminum material surface treatment etc. Products include thionamic nickel sulfamate, cobalt sulfamate, nickel carbonate basic, cobalt carbonate basic, nickel acetate, and cobalt acetate etc.

公司成立20年来,一直为精密电镀、连接器与引线框架电镀、印刷电路板电镀、五金电镀、镍钴合金电铸、铝材表面处理等行业产品提供高品质的氨基磺酸镍、氨基磺酸钴、碱式碳酸镍、碱式碳酸钴、醋酸镍、醋酸钴等产品。

The character amino group vibration absorption bands were displayed in FTIR/ATR spectrum at 3352 and 1613 cm^(-1), respectively.

傅里叶变换红外光谱图谱在3352和1613 cm^(-1)处出现了新的氨基吸收峰,证实了表面接枝了氨基。

Diamino-dipenylamine-2-sulfonicacid was used as an alternative of benzidine,and reacted withl-hy droxy-8-aminonaphthalene-3,6-dusuifonicacid,m-benzioc-diamine and aniline to synthesize eco-friendly black direct dye s.

报道了以4,4'-酸(4,4'-二氨基-二苯胺-2-磺酸)代替联苯胺,与H酸(1-羟基-8-氨基-3,6-二萘磺酸)、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

The environmental black direct dye stuff without carcinogensis was prepared by 4,4'-diamino-dibenzidine-2-sulfonicacid,1-hydroxy-7-aminonaphthalene-3,6-dusuifonicacid,m-benzoic-diamine and aniline.

以4,4'-二氨基-二苯胺-2-磺酸代替苯胺,与1-羟基-7-氨基-3,6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

The environmental black direct dyestuff without carcinogensis was prepared by 4,4'- diamino - dibenzidine - 2 - sulfonicacid, 1 - hydroxy - 7 - aminonaphthalene - 3,6 - dusuifonicacid, m - benzoic - diamine and aniline.

以4,4'-二氨基-二苯胺-2-磺酸代替苯胺,与1-羟基-7-氨基-3,6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

A method was developed for the determination of Carbaryl in water by direct injection and HPLC with coupled ultraviolet and fluorescence detectors.

1引言甲蔡威,又称西维因,学名1一蔡基一N一甲基氨基甲酸醋,是氨基甲酸醋类农药的一种,在我国被广泛用作杀虫剂和除草剂。

The reaction mechanism of tetrakis hydroxymethyl phosphonium chloride and raw collagen were researched by the simulated materials of collagen including glycin,ethylenediamine and hide powder.

通过研究四羟甲基氯化鏻与皮胶原模拟物反应,间接证明THPC主要与胶原蛋白的氨基结合,可与氨基以n∶n=1∶2.2形成交联,THPC与羟基和酰胺基均有少量结合,并在pH=8.0时结合量最高。

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