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氨基甲酸酯

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A method for separation and determination of amino acids using pre column derivatization with 6 aminoquinoline N hydroxysuccinimido carbamate AccQ.

对Waters公司采用 6 氨基喹啉 N 羟基琥珀酰亚胺基氨基甲酸酯柱前衍生化测定氨基酸的方法进行了改进。

Similarly, 5TPS-AVB〓 or 5-TPS-IVB〓 reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce six new 4"-carbamates or 4"-phosphorylates in good yields.

LA-47与氨基甲酰氯和磷酰氯反应,得到3个对应的5-4-TPS-AVB〓氨基甲酸酯或膦酸酯衍生物,产率良好。

Similarly, IVB〓 reacted with carboxylic acids in DCC/DMAP/DCM system to produce ten new 5-IVB〓 esters in 66-82% yield. AVB〓 or IVB〓 also reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce eight corresponding carbamates or phosphorylates in good yields.

阿维菌素B〓与氨基甲酰氯反应,合成了2个5-AVB〓氨基甲酸酯衍生物:阿维菌素B〓与膦酰氯反应,合成2个5-AVB〓膦酸酯衍生物;并改进了阿维菌素与酰氯的反应条件,缩短了反应时间,提高了产率和反应的选择性。

The target compound was synthesized from clarithromycin via hydrolyzation,acetylation,cyclic carbonatation,oxidation,decarbonatation,acylation,cyclic carbamatation and cyclization.

方法以克拉霉素为起始原料,经水解、乙酰化、环碳酸酯化、氧化、脱碳酸酯化、酰化、环氨基甲酸酯化和环合等反应合成目标化合物。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法,其反应混合物包括:一种含至少85重量%的4,4′-二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分,一种多元醇组合物,其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量%之间的聚氧亚烷基多元醇,水,一种平均羟基当量为15至250之增链剂,以及视需要使用的交联剂,该硬性嵌段-含量(hardblock-content)大于45重量%。

The study evaluated the influence of the two different polyol's raw material origins and the different dispersing additives in the polyurethane coatings formulations on the weathering resistance by glossmetry, spectrocolorimetry, chalking test, infrared spectroscopy etc. The influence of light stabilizer and dispersant on the degradation characteristerics of polyurethane coating has also been evaluated. Ultraviolet radiation from sunlight causes the chalking of resin and the fading of pigment by breaking down the chemical bonds in coatings.

本实验将配制成不同灰色聚氨基甲酸酯涂料配方,加入硬化剂后涂装在试片上,待自然风乾后,制成不同配方涂膜试片,进行加速风化耐候利睑、光泽度、分光色差、粉化、红外线光谱仪等测试,探讨不同的聚醇树脂原料来源,与不同的润湿分散添加剂种类,对於聚氨基甲酸酯涂料耐候性质的影响。

A four-ball tester was used to evaluate the load carrying and antiwear properties of bismuth dibutyldithiocarbamate,bis-dibutyldithiocarbamates(V7723),sulfurized isobutylene,molybdenum ester non sulfur and phosphorus in a mineral oil respectively and their synergistic effects.

利用四球试验机评价了二丁基二硫代氨基甲酸铋与二丁基二硫代氨基甲酸酯(V7723)、硫化异丁烯和非硫磷钼酸酯添加剂的极压和抗磨性能,以及它们之间的极压和抗磨协同作用。

Herein, the research ideas of the present work, i.e., the clean syntheses of N-substituted carbamates from amines and alkyl carbamates are derived. Different catalytic systems are introduced, and their activities are also investigated at the same time.

由此确定了以小分子氨基甲酸烷基酯取代光气与有机胺合成N-取代氨基甲酸酯的研究方向,引入并考察了不同催化体系的催化活性。

The invention relates to a surface chemistry modified latex which can be obtained by carrying out radical polymerization in emulsion in the presence of at least one ethylenically unsaturated monomer or at least one polymer having ethylinically unsaturated residual bonds, at least one radical polymerization, at least one single, double or triple block polymer which is soluble or dispersible in water, comprising an active group at the end thereof, capable of forming a radical, and chosen from dithioesters, xanthates, thioether-thiones and dithiocarbamates.

本发明涉及具有改良表面化学性质的胶乳,它可以通过在以下物质的存在下进行自由基乳液聚合来获得:至少一种烯属不饱和单体或至少一种含残留烯属不饱和键的聚合物,至少一种自由基聚合引发剂,至少一种水溶性和/或水可分散的单嵌段、二嵌段或三嵌段聚合物,在其端部包括选自二硫酯,硫醚-硫酮,二硫代氨基甲酸酯和黄原酸酯中的能够形成自由基的活性基团。

Using a long-term reared housefly population which is very susceptible to pyrethroid insecticides as the susceptible strain, a population collected in 1993 in Shanghai and has been treaded by cyhalothrin as the resistant strain, we bioassayed their susceptibility to organophosphorus, carbamate, pyrethroid and organehloride insecticides. We also investigated the role of metabolic enzymes, i. e. esterase, GST, MFO and of target enzymes, i. e. AChE and 〓-ATPase in resistance to insecticides. Cyhalothrin resistance inheritance, the co-toxicity coefficient of cyhalothrin and methylene dithiocyanate was also studied. The insecticides resistance in adults and larvae of houseflies was compared and the mechanism of resistance differences between adults and larvae was discussed.

本文以采自野外并经过室内多代筛选的三氟氯氰菊酯抗性家蝇品系和室内多年饲养的敏感家蝇品系为试虫,测定了抗性家蝇品系和敏感家蝇品系对拟除虫菊酯杀虫剂三氟氯氰菊酯、氯菊酯、有机磷杀虫剂DDVP、氨基甲酸酯杀虫剂残杀威、有机氧杀虫剂DDT的抗性水平,并通过活体增效剂实验和离体生化实验研究了抗性品系的解毒酶和靶标酶的变化,本文还研究了三氟氯氰菊酯和增效剂I对抗性家蝇的增效作用及增效机理、家蝇幼虫和成虫对杀虫剂的抗性差异及其抗性差异的机理。

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