氨基甲酸酯

With the occurrence of H2/Pd-C and ethyl formic ester,the reduction of the nitro group and the formylation of the amino group could be finished in one step.

但是在甲酸乙酯存在下，用H2/Pd-C对Ⅶ的硝基进行还原，得到的Ⅷ中的氨基可当即被甲酰化，使由Ⅶ到Ⅳ的两步反应一步完成。

During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时，先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外，又研究了影响该反应的几个重要因素：亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4：1；稳定剂2-甲基-2-丁烯的用量至少大于2：1，通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出，获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

The charomatographic conditions of separation and direct dermination of benzophenone-4(MS40), salizyle acid sodium, salol, benzophenone-3(M40), octyl dimethyl PABA(6007), butyl methoxy dibenzoyl methane(1789), octyl methoxyl cinnamate and octyl salicylate(587) from u-Bondapak C18 Column were studied with methanol-water-THF as elution. A HPLC method for these compounds was founded.

研究了用甲醇-四氢呋喃-水作为流动相，从C18柱上分离和测定羟苯甲酮-5-磺酸(MS40)、水杨酸钠、水杨酸苯酯、羟苯甲酮(M40)、对-二甲酸氨基苯甲酸-2-乙基己酯(6007)、4-叔丁基-4-甲氧基二苯甲酸甲烷(1789)、对-甲氧基肉桂酸-2-乙基己酯、水氧酸-2-乙基己酯(587)等8种紫外线吸收剂的色谱条件，建立了用HPLC测定上述物质的方法。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物，通过2-氨基-5-(3-吡啶基)-1，3，4-噻二唑与酰基叠氮化物反应，设计合成了7个新的N-[5-(3-吡啶基)-1，3，4-噻二唑-2-基]-N'-取代苯基脲，其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

N-Carbobenzoxy-L-homoserinelactone was prepared via N-alkylation reaction of L-methionine and iodoacetamide with benzyl chloroformate as amino protecting agent.

以L-蛋氨酸为原料，氯甲酸苄酯为氨基保护试剂，与碘乙酰胺(I2微量)内酯化反应，合成N-苄氧羰基-L-高丝氨酸内酯。

The key intermediate 3-methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods,formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction,and then hydr...

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

The key intermediate 3- methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods, formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction, and then hydrolysis.

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

In this paper,pyromellitic dianhydride,1,2,3,4-cyclobutanetetracarboxylic dianhydride,4[(4-aminophenyl)-bis(4-methoxyphenyl)methyl]benzeneamine,4-hexyloxy-biphenyl-3′,5′-diaminobenzoate,and additive ADD-34 were used to synthesize four PIs.

文章用均苯四甲酸二酐，4[(4-氨基苯基)-二(4-甲氧基苯基)甲基]苯胺，1，2，3，4-环丁烷四羧酸二酐，4-己烷氧基联苯酚-3′，5′-二胺基苯甲酸酯和不同含量的添加剂制备了聚酰亚胺液晶取向剂。

Polyimide/silica (PI/SiO2) nano-hybrid films of different solid content were prepared based on pyromellitic dianhydride and 4, 4'-oxydianiline using tetraethoxysilane as the inorganic precursors.

以均苯四甲酸二酐和4，4'-二氨基二苯醚为有机单体，正硅酸乙酯为无机前驱体，制备了SiO2含量一定，PAA杂化胶液固体含量不同的PI/SiO2纳米杂化薄膜。

Relative retentions of 12 S-compounds on 4 different liquid phases were given.

给出了十二种硫化物在沙鱼烷、苯二甲酸二壬酯、磷酸三甲苯酯及亚氨基二丙腈四种柱子上的相对保留值。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。