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The jeopardy,mechanism,analysis method and elimination method of ethyl carbamate was summarized to enhance the social recognition of it as a carcinogen.

对氨基甲酸乙酯的危害、形成机制、分析和消除方法进行了综述,应加强对氨基甲酸乙酯这种致癌物质的认识,引起社会的关注。

In the seventh chapter, the reaction of sodium hydrogen selenide with thiocarbamates and dithiocarbamates in ethanol as a selenium-containing reagent with good nucleophilic and reductive property were studied.

第七章进行了硒试剂NaHSe与硫代氨基甲酸酯和二硫代氨基甲酸酯的反应研究,并提出了反应的可能机理。

The photoproducts of CCU in organic solvents have also been identified with HPLC- and GC-MS. The photoproducts identified in methanol are isocyanato bezene, 4-chlorophenyl isocyanate, 2-chloro benzamide, chlorobenzene, 4-chlorophenyl urea, N-phenyl methylcarbamate, N-(4chlorophenyl) methylcarbamate, and 2-chloro-N-(4-chlorophenyl) benzamide.

对灭幼脲在各种有机溶剂中的光解产物作HPLC/UV和GC-MS鉴定,发现其在甲醇中的光解产物含有:异氰酸苯酯、对氯苯基异氰酸酯、邻氯苯甲酰胺、氯苯、对氯苯基脲、N-苯基氨基甲酸甲酯、N-氨基甲酸甲酯、以及N-邻氯苯甲酰胺等。

The structure of IC with wood and its constitutes was also studied by Fourier Transform Infrared Spectroscopy. It shows that the reaction of IC with lignin mainly produces carbamate, when lignin contains some water, produces weak carbamide; but the reaction of IC with wood powder produces weak carbamite, and with the wood powder containing water mainly produces carbimide.

对于异氰酸酯与木材及其组分反应产物的结构,论文采用傅利叶红外谱图进行了分析,结果表明,木素与异氰酸酯反应主要生成氨基甲酸酯,含水率较低时有少量取代脲产生;木粉与异氰酸酯反应生成的氨基甲酸酯较少,含水木粉与异氰酸酯主要生成取代脲。

It is shown by Infrared spectra that relative concentration of amino formic acid ester has prominent relationship with compressive stress at 10% strain in the process of accelerated hygrothermal tests, which means that hydrolysis of amino formic acid ester is main factor resulting in decrease of compressive properties.

经红外光谱测定,在人工加速湿热老化试验过程中,材料的活性基团氨基甲酸酯的相对浓度与10%定应变压缩应力的相关性显著,氨基甲酸酯水解是材料室内贮存过程中力学性能下降的主要原因。

A method combining HPLC, a post-column derivation device and a fluorescent detector was used to determine residues of ten carbamate pesticides (aldicarb sulfoxide, aldicarb sulfone, oxamyl, methomyl, 3-hydroxy carbofuran, aldicarb, propaxur, carbofuran, carbaryl and methiocarb) in 68 vegetable and 32 soil samples under four different cultivation systems (traditional kailyard, open field vegetable base, green house and paddy) were collected from a certain city in South Jiangsu.

本研究采用高效液相色谱-柱后衍生-荧光检测法分析了苏南某市4种不同种植方式下(传统菜地、露天蔬菜基地、大棚蔬菜基地和水稻田)68个蔬菜样品和32个土壤样品中10种N-甲基氨基甲酸酯类农药(涕灭威、涕灭威砜、涕灭威亚砜、杀线威、灭多威、残杀威、克百威、3-羟基克百威、甲萘威和灭虫威)的残留量,结果表明在蔬菜中检出的氨基甲酸酯农药残留水平多处于0.2~23μgkg^-1,土壤中为0.1~10μgkg^-1;土壤中3-羟基克百威和灭虫威全部检出,其最高检测浓度分别为10μgkg^-1和1.64μgkg^-1,其他农药仅有少数检出。

The study evaluated the influence of the two different polyol's raw material origins and the different dispersing additives in the polyurethane coatings formulations on the weathering resistance by glossmetry, spectrocolorimetry, chalking test, infrared spectroscopy etc. The influence of light stabilizer and dispersant on the degradation characteristerics of polyurethane coating has also been evaluated. Ultraviolet radiation from sunlight causes the chalking of resin and the fading of pigment by breaking down the chemical bonds in coatings.

本实验将配制成不同灰色聚氨基甲酸酯涂料配方,加入硬化剂后涂装在试片上,待自然风乾后,制成不同配方涂膜试片,进行加速风化耐候利睑、光泽度、分光色差、粉化、红外线光谱仪等测试,探讨不同的聚醇树脂原料来源,与不同的润湿分散添加剂种类,对於聚氨基甲酸酯涂料耐候性质的影响。

A four-ball tester was used to evaluate the load carrying and antiwear properties of bismuth dibutyldithiocarbamate,bis-dibutyldithiocarbamates(V7723),sulfurized isobutylene,molybdenum ester non sulfur and phosphorus in a mineral oil respectively and their synergistic effects.

利用四球试验机评价了二丁基二硫代氨基甲酸铋与二丁基二硫代氨基甲酸酯(V7723)、硫化异丁烯和非硫磷钼酸酯添加剂的极压和抗磨性能,以及它们之间的极压和抗磨协同作用。

Herein, the research ideas of the present work, i.e., the clean syntheses of N-substituted carbamates from amines and alkyl carbamates are derived. Different catalytic systems are introduced, and their activities are also investigated at the same time.

由此确定了以小分子氨基甲酸烷基酯取代光气与有机胺合成N-取代氨基甲酸酯的研究方向,引入并考察了不同催化体系的催化活性。

Synthesis of methylene-4,4'-di catalyzed by zinc oxide Various metal oxide were investigated in the synthesis of methylene-4,4'-di from ethyl carbamate, and a serious of ZnO/SiO2 catalysts were prepared by deposition-precipitation method.

氧化锌为催化剂合成4,4'-二环己基甲烷二氨基甲酸乙酯以氨基甲酸乙酯和4,4'-二环己基甲烷二胺的反应体系为研究对象,在考察多种金属氧化物活性的基础上,使用沉积沉淀法制备了一系列硅胶负载氧化锌催化剂,并对其催化性能进行了研究。

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