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Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明,出现在A组分中的2275~2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390~3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求,即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中;凝胶渗透色谱结果表明,成膜物质的A、B组分均为低分子量,符合预聚物的要求;涂膜表面能的测算结果表明,涂膜的表面能在33.6~47.17mN/m之间;加入碱式防污剂后涂膜的表面能略有升高;碱式防污剂的释放平稳,随着涂膜在海水中浸泡时间的增长,pH值有增加的趋势;用溶解度参数原则来评价涂料与网绳的涂装,结果表明,本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

Carbon disulfide, dialkylamine, antimony trioxide have been used to synthesize the other organic antimony compounds-dialkyldithiocarbamate. The optimal technological conditions and purificating method have been studied in detail.

以二硫化碳、二元仲胺、三氧化二锑为原料合成了结构为Sb-〓的另一类含Sb-S键的有机锑化合物,通过大量的实验探索,详细研究了各种二烷基二硫代氨基甲酸锑的最佳合成工艺条件及产品的提纯方法,为该类化合物的制备提供了一种工艺简便,收率较高的合成工艺途径。

The extremities were titanic, and there was no response to touch stimulations.Our results suggested that Pentobarbital sodium inhibited neuronal firing through GABA_A receptors, therefore the local field potentials and neural firing rates were inhibited; Urethane acted on many kinds of receptors including inhibitory and excitory ones, so the local field potentials did not change significantly; however, because of the multiform receptors on the neurons, the changing of firing rates to different neurons were not the same; Ketamine mainly acted on the NMDA receptors, therefore the local field potentials and neural firing rates were enhanced, and most neural firing rates would be increased.

从这三种麻醉剂的底层作用机制来看,戊巴比妥钠通过作用于GABAA受体对神经细胞发挥抑制性作用,因此表现为场电位和神经元放电的降低;氨基甲酸乙酯同时作用于多种受体通道,既有兴奋性受体,也有抑制性受体,因此,对场电位的影响不大,但对单个神经元来说,每个神经细胞上的受体通道分布差异较大,因此,单个神经元的放电频率变化会有所不同;盐酸氯胺酮主要作用于兴奋性的NMDA受体,故整体场电位活性增加,多数神经元的放电频率也会有所升高。

This paper reviews the kinetic mechanism of acetylcholinesterase, illustrates the principle and application of the kinetic parameters such as Michealis-Menten affinity constant Km, maximum reaction velocity Vmax, turnover number Kcat, bimolecular rate constant Ki, affinity constant of the inhibitor for the a ctive site Ka, phosphorylation or carbamylation rate constant K2, and discusses the potential practical application benefiting from the study of the kinetic analysis.

综合评述了AChE的动力学机制的发展状况,着重介绍了米氏常数Km、最大反应速率Vmax、转换率Kcat、双分子速率常数Ki、抑制剂化合物对AChE活性部位的亲和力常数Ka、磷酸化或氨基甲酸化速率常数K2,这些动力学参数的原理及其应用状况,探寻了动力学机制将带来的实际应用。

In this test, metabolites and enzyme activities involved in energy metabolism in Cysticercus cellulosae were determined systematicly in vivo and in vitro and under action of drugs.The principles of variation of energy metabolism in Cysticercus cellulosae and mechanism of action of the benzimidazol carbamate drugs were illustrated so as to select an effective drug against immature and mature cysticerci and to provide a theoretical and experimental chemotherapy.

本研究首次系统地测定了体内发育过程中、体外培养条件下及抗囊药物作用下猪囊尾蚴能量代谢的有关物质含量和酶活性的变化,阐明了猪囊尾蚴的能量代谢变化规律和苯并咪唑氨基甲酸酯类药物作用机理,为筛选有效的抗囊药物以及为药物治疗提供了重要的实验和理论依据。

To investigate the relationship between the tolerance to dehydration and superoxide dismutases in Pachira macrocarpa, fresh mature seeds were pretreated with a 12 h DDTC and subjected to 3~20 h desiccation silica gel at 25℃. The results showed that 20 mmolL^(-1) diethyldithiocarbamate treatment inhibited efficiently SOD and SOD activity in seeds and reduced tolerance of seeds to water deficit, which was evidenced with increases in electrical conductivities and malondialchehy of the seeds, and a rapid decrease of the seed vigor during desiccation.

以探讨马拉巴栗种子脱水耐性与其超氧化物歧化酶之间的关联为目的,选用新鲜的成熟马拉巴栗种子,用二乙基二硫代氨基甲酸钠(DDTC, SOD抑制剂)进行12h预处理后,在25℃下进行3~20h的硅胶快速脱水处理,观察种子的萌发率和生理指标的变化。

The invention relates to a surface chemistry modified latex which can be obtained by carrying out radical polymerization in emulsion in the presence of at least one ethylenically unsaturated monomer or at least one polymer having ethylinically unsaturated residual bonds, at least one radical polymerization, at least one single, double or triple block polymer which is soluble or dispersible in water, comprising an active group at the end thereof, capable of forming a radical, and chosen from dithioesters, xanthates, thioether-thiones and dithiocarbamates.

本发明涉及具有改良表面化学性质的胶乳,它可以通过在以下物质的存在下进行自由基乳液聚合来获得:至少一种烯属不饱和单体或至少一种含残留烯属不饱和键的聚合物,至少一种自由基聚合引发剂,至少一种水溶性和/或水可分散的单嵌段、二嵌段或三嵌段聚合物,在其端部包括选自二硫酯,硫醚-硫酮,二硫代氨基甲酸酯和黄原酸酯中的能够形成自由基的活性基团。

The studies on metabolic enzymes、synergists and neurobioassays suggest that the monooxygenases、esterase and decreased nerve sensitity are involved in resistance to pyrethroids in the resistant HJ-R strain . The resistance to both organophosphorus and carbamate insecticides is mainly caused by metabolic mechanisms. The significantly synergistic effects of Pbo infer that the resistance to carbamata may be principally attributable to monooxygenases detoxification.

代谢酶系、增效作用以及神经电生理研究表明,HJ-R种群对拟除虫菊酯类杀虫剂的抗性是由多功能氧化酶及酯酶代谢增强、神经敏感性降低几个因子综合作用的结果;对有机磷、氨基甲酸酯类杀虫剂的抗性主要是由代谢机制引起,与靶标部位敏感性降低机制抗性无关,Pbo对HJ-R种群突出的增效作用,表明多功能氧化酶代谢在对灭多威的抗性中可能起主导作用。

Using a long-term reared housefly population which is very susceptible to pyrethroid insecticides as the susceptible strain, a population collected in 1993 in Shanghai and has been treaded by cyhalothrin as the resistant strain, we bioassayed their susceptibility to organophosphorus, carbamate, pyrethroid and organehloride insecticides. We also investigated the role of metabolic enzymes, i. e. esterase, GST, MFO and of target enzymes, i. e. AChE and 〓-ATPase in resistance to insecticides. Cyhalothrin resistance inheritance, the co-toxicity coefficient of cyhalothrin and methylene dithiocyanate was also studied. The insecticides resistance in adults and larvae of houseflies was compared and the mechanism of resistance differences between adults and larvae was discussed.

本文以采自野外并经过室内多代筛选的三氟氯氰菊酯抗性家蝇品系和室内多年饲养的敏感家蝇品系为试虫,测定了抗性家蝇品系和敏感家蝇品系对拟除虫菊酯杀虫剂三氟氯氰菊酯、氯菊酯、有机磷杀虫剂DDVP、氨基甲酸酯杀虫剂残杀威、有机氧杀虫剂DDT的抗性水平,并通过活体增效剂实验和离体生化实验研究了抗性品系的解毒酶和靶标酶的变化,本文还研究了三氟氯氰菊酯和增效剂I对抗性家蝇的增效作用及增效机理、家蝇幼虫和成虫对杀虫剂的抗性差异及其抗性差异的机理。

The cellulose pulp with α-cellulose higher than 90% and polymerisation degree of range of 450~625 was treated with 14%~16% sodium hydroxide solution for 30~40 min under temperature of 40~50°C, and blended with urea in the ratio of 1:2~3. The product was reacted in xylene as solvent at 137°C for 2~3 h.

指出:选用聚合度为450~625、α-纤维素含量大于90%的纤维素桨粕,用14%~16%的氢氧化钠溶液,于40~50℃条件下活化处理30~40min后,与尿素以1:2~3的比例混合,在137℃的二甲苯体系中反应2~3h,便可得到含氮量为2.4%~3.5%的纤维素氨基甲酸酯产物。

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