氨基甲酸甲酯

Dimethylhexane-1,6-dimethyleurethane is the key material for preparation of 1,6-hexamethylene diisocyanate by non-phosgene route. Our work mainly focuses on the study of the catalytic performances of metal oxysalts and metal oxides for the ammonolysis of DMC to HDU-M. Experiment effect showed the ammonolysis was omposed by two steps, in which the first step was easier to occur than the second.

中文摘要六亚甲基-1，6-二氨基甲酸甲酯是非光气合成六亚甲基二异氰酸酯的关键原料，本文主要对金属含氧酸盐和金属氧化物这两类用于碳酸二甲酯胺解合成HDU-M 的催化剂进行了初步研究并优化了工艺条件。

This method is sensitive, fast and accurate and it could satisfy high sensitive analysis of methyl carbamate residues in liquor.

该方法的灵敏度高、操作简便、快速，满足白酒中痕量氨基甲酸甲酯农残的高灵敏分析。

At the same time coupling reaction combined with urea and methanol is used in the synthesis of methyl carbamate.

重点研究了氨基甲酸甲酯的合成路线，本文将耦合反应应用于氨基甲酸甲酯的合成反应中，结合尿素醇解法制备氨基甲酸甲酯。

The clean synthesis of 1,6-dicarbamate hexane from dimethyl carbonate and 1,6-diamine hexane is studied.

对由1，6-己二胺和碳酸二甲酸合成1，6-六亚甲基二氨基甲酸甲酯的洁净化工艺过程进行了初步研究。

The photoproducts of CCU in organic solvents have also been identified with HPLC- and GC-MS. The photoproducts identified in methanol are isocyanato bezene, 4-chlorophenyl isocyanate, 2-chloro benzamide, chlorobenzene, 4-chlorophenyl urea, N-phenyl methylcarbamate, N-(4chlorophenyl) methylcarbamate, and 2-chloro-N-(4-chlorophenyl) benzamide.

对灭幼脲在各种有机溶剂中的光解产物作HPLC/UV和GC-MS鉴定，发现其在甲醇中的光解产物含有：异氰酸苯酯、对氯苯基异氰酸酯、邻氯苯甲酰胺、氯苯、对氯苯基脲、N-苯基氨基甲酸甲酯、N-氨基甲酸甲酯、以及N-邻氯苯甲酰胺等。

Keywords: methyl carbamate, isocyanic acid ester, polyurethane, green chemical technology, dimethyl carbonate

中文关键词：氨基甲酸甲酯；异氰酸酯；聚氨酯；绿色化工；碳酸二甲酯

This project mainly exploratorily studied that polyurethane was produced via condensation reaction between polyhydroxylated compounds and methyl carbamate, which was firstly synthesized by dimethyl carbonate and amines. The process is a green route because it turns away the synthesis and the utilization of toxical isocyanic acid ester.

本项目主要探索性地研究了碳酸二甲酯和胺类化合物反应生成氨基甲酸甲酯，然后氨基甲酸甲酯再和多羟基化合物直接反应得到聚氨酯材料，从而避免了异氰酸酯的合成和使用。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e，7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e，进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

The source and formation mechanism of methyl carbamate in liquor covered the followings:①methyl carbamate formed by spontaneous chemical reaction of carbamide and methanol in fermented and undistilled alcoholic beverage;②in alcohol produced by grains as raw materials, cyanide precursor of grains formed into cyanate during fermentation and distillation, which further developed into methyl carbamate in alcohol.

白酒中氨基甲酸甲酯的来源和形成机理主要有：①在已发酵的和未蒸馏的酒精饮料中尿素和甲醇自发的化学反应生成氨基甲酸甲酯；②以谷物为原料生产的酒精中，氨基甲酸甲酯形成的途径来源于谷物的氰化物前体在发酵和蒸馏时反应形成的氰酸盐，氰酸盐在酒精中转化为氨基甲酸甲酯。

Latest researches in the catalysts for synthesis of carbamate by ammonolysis of dimethyl carbonate;2. Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate;3.4,4′-Methylene diphenyl carbamatewas synthesized by ammonolysis of dimethyl carbonate, a substitute of phosgene, and 4,4′-diaminodiphenyl methane with anhydrous zinc acetate as catalyst.

用碳酸二甲酯代替光气，以4，4′-二氨基二苯基甲烷为原料，在无水醋酸锌催化剂的作用下，经胺解反应合成了4，4′-二苯甲烷二氨基甲酸甲酯；测定了MDC的熔点；采用傅里叶变换红外光谱和氢核磁共振对产品结构进行了表征；考察了反应温度、DMC用量、反应压力、反应时间、催化剂用量对MDC收率的影响。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。