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氨基甲酸乙酯

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Two new kind of energy transfer donor-acceptor dyads consisting of α-naphthoic acid moiety and 9-aminoacridine units linked by tetraethylene glycol or triethylene glycol flexible chain have been synthesized.

本工作分别用聚三乙二醇及聚四乙二醇柔性链将α-萘甲酸酯与9-氨基吖啶连接起来,合成了两种新型二元发色团分子体系,在两个体系中,选择激发α-萘甲酸酯,都可以发生从α-萘甲酸酯到9-氨基吖啶的高效率的单重态-单重态能量传递。

For the determination of five carbamate pesticide residues by high performance liquid chromatography with gel permeation chromatography purification, sample was extracted with acetonitrile and purified with gel permeation chromatography. Methanol-water was used as the mobile phase by gradient elution, flow rate of 1.0mL/min, using a fluorescence detector and quantitating with external standard method.

凝胶渗透色谱-液相色谱法测定5种氨基甲酸酯类农药残留中,实验采用乙腈提取,凝胶渗透色谱柱对样品进行净化,以甲醇-水为流动相,进行梯度洗脱,流速1.0mL/min,荧光检测器检测,外标定量测定。

Methods The amino acids in the injections were pretreated with 6-aminoquinolyl-N-hydroxysuccinimdyl separately and their derivatives were analyzed on Waters 2695 HPLC using AccQ-Tag column. Gradient eluents consisted of sodium acetate solution (pH 4.95), acetonitrile and water. The Detection wavelength was 248 nm and column temperature 37℃.

采用AccQ-Tag法,以6-氨基喹啉-N-羟基琥珀酰亚胺基甲酸酯为衍生试剂,与复方氨基酸注射液(18AA-V)中17种氨基酸柱前衍生,用Waters 2695 HPLC仪器,AccQ-Tag柱,以醋酸钠(pH 4.95)缓冲液为流动相A,乙腈为流动相B,水为流动相C进行梯度洗脱,检测波长为248 nm,柱温为37℃,进样量为5μL。

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