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氨基甲酸

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In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上,采用化学氧化法将它们与苯胺进行共聚,制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

Urethan resin for better stability, but business card printing and membership card making suitable to their needs and less soluble Li anzhai and other styryl modified monomaleate resin, water-based Amino resins, and polyvingl acid and carboxymethly celluiose, and so on, these polymer resin generally with the-COOH,-OH,-NH

氨基甲酸乙酯树脂的稳定性较好,但制卡和会员卡制作适性和可溶性要略差一些,其它还有用苯乙烯改性马来酸树脂、水性氨基树脂以及聚乙烯酸和羧甲基纤维素等,这些高分子树脂一般均含有-COOH、-OH、-NH

A method for separation and determination of amino acids using pre column derivatization with 6 aminoquinoline N hydroxysuccinimido carbamate AccQ.

对Waters公司采用 6 氨基喹啉 N 羟基琥珀酰亚胺基氨基甲酸酯柱前衍生化测定氨基酸的方法进行了改进。

Similarly, 5TPS-AVB〓 or 5-TPS-IVB〓 reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce six new 4"-carbamates or 4"-phosphorylates in good yields.

LA-47与氨基甲酰氯和磷酰氯反应,得到3个对应的5-4-TPS-AVB〓氨基甲酸酯或膦酸酯衍生物,产率良好。

Similarly, IVB〓 reacted with carboxylic acids in DCC/DMAP/DCM system to produce ten new 5-IVB〓 esters in 66-82% yield. AVB〓 or IVB〓 also reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce eight corresponding carbamates or phosphorylates in good yields.

阿维菌素B〓与氨基甲酰氯反应,合成了2个5-AVB〓氨基甲酸酯衍生物:阿维菌素B〓与膦酰氯反应,合成2个5-AVB〓膦酸酯衍生物;并改进了阿维菌素与酰氯的反应条件,缩短了反应时间,提高了产率和反应的选择性。

Bezaldehyde was used as protective agent in first method.S-Epichloeohydrin was aminated and acidulated to give(2S)-1-Amino-3-chloro-propanol Salts.The acetylation of (2S)-1-Amino-3-chloro-propanol by acetic anhydride produced the intermediate-N-[2--3-chloropropyl]acetamide.And then at 20℃,in the presence of lithium tert-butoxide,benzyl 3-fluoro-4-morpholinophenyl carbamate react with-N-[2--3-chloropropyl]acetamide to give linezolid in total yield of 43.6%.

路线一采用苯甲醛作保护剂,使S-环氧氯丙烷氨解、酸化生成S-1-氨基-3-氯-2-丙醇盐酸盐,然后经乙酰化反应后,生成中间体-N-[2-乙酰氧基-3-氯丙基]乙酰胺,再用N-(3-氟-4-吗啉苯基)氨基甲酸苄酯和中间体在催化剂叔丁醇锂存在下25℃反应生成利奈唑酮,总产率达到43.6%。

The determination of amino acids in blood clam antianaemia oral liquid using HPLC-AccQ-Tag method is reported. The oral liquid reacted with 6-aminoquinolyl-N-hydroxysuccini-mdyl carbamate. Then, the corresponding derivatives were analyzed with an HPLC. The chromatographic conditions were AccQ-TagTM C18 column for amino acids analysis (3.9mm×15cm); mobile phase of program elution sodium acetate solution(pH5.02), acetonitrile, Milli-Q water. The amino acids'AQC deriatives were detected at 248nm with a UV-detector. Eighteen kinds of amino acids were completely determined in 35 minutes.

以6-氨基喹啉-N-羟基琥珀酰亚胺基氨基甲酸酯为衍生剂,与毛蚶抗贫血口服液中的氨基酸柱前定量衍生,用WatersHPLC仪,AccQ-TagTM专用C18柱(3.9mm×15cm),以140mmol·L-1的醋酸钠溶液(pH5.02)为溶剂A,乙腈为溶剂B,超纯水为溶剂C,进行梯度洗脱,检测波长为248nm,35min测试完毕。

Latest researches in the catalysts for synthesis of carbamate by ammonolysis of dimethyl carbonate;2. Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate;3.4,4′-Methylene diphenyl carbamatewas synthesized by ammonolysis of dimethyl carbonate, a substitute of phosgene, and 4,4′-diaminodiphenyl methane with anhydrous zinc acetate as catalyst.

用碳酸二甲酯代替光气,以4,4′-二氨基二苯基甲烷为原料,在无水醋酸锌催化剂的作用下,经胺解反应合成了4,4′-二苯甲烷二氨基甲酸甲酯;测定了MDC的熔点;采用傅里叶变换红外光谱和氢核磁共振对产品结构进行了表征;考察了反应温度、DMC用量、反应压力、反应时间、催化剂用量对MDC收率的影响。

Some organic insecticides are natural, such as rotenone, pyrethrins, and nicotine. Others are synthetic, such as chlorinated hydrocarbons (e.g., DDT, dieldrin, lindane); carbamates, related to urea (e.g., carbaryl, carbofuran); and parathions, organic phosphorus ester s.

有机的杀虫剂可能是天然的,如鱼藤酮、除虫菊和尼古丁;或是合成的,如氯代烃类(例如,滴滴涕、狄氏剂、林丹)、氨基甲酸酯,与尿素有关(如氨基甲醯、灭多虫和卡甲喃)、巴拉松、有机磷酸盐。

Some organic insecticides are natural, such as rotenone, pyrethrins, and nicotine. Others are synthetic, such as chlorinated hydrocarbon s (e.g., DDT, dieldrin, lindane); carbamates, related to urea (e.g., carbaryl, carbofuran); and parathions, organic phosphorus esters.

有机的杀虫剂可能是天然的,如鱼藤酮、除虫菊和尼古丁;或是合成的,如氯代烃类(例如,滴滴涕、狄氏剂、林丹)、氨基甲酸酯,与尿素有关(如氨基甲醯、灭多虫和卡甲喃)、巴拉松、有机磷酸盐。

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