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Urethane adduct was synthesized from decarboxylated cashew nut shell liquid,hexamethylenediisocynate and polyethylglycol,which was then reacted with melamineformaldehyde resin to form aqueous coating material.

采用天然植物油、己二异氰酸酯和聚乙二醇在较温和的条件下反应,制得了水溶性的氨基甲酸酯加成物,以此和低醚化度甲醚化三聚氰氨甲醚甲醛树脂制备了水性涂料。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料,经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯,然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺,再用对甲苯磺酰氯将羟基活化,最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1~L4。

Methods Activate GAMP with cyanogens bromide and prepare GAMP-protein conjugates using ADH as a linker and EDAC as a coupling agent.

方法采用溴化氰活化多糖,以无水己二酸二肼为连接剂,1-乙基-1-3-(3-二甲基氨基-丙基)-碳化二亚胺为偶联剂,制备结合物并免疫小鼠,检测小鼠血清中抗GAMP与抗载体蛋白抗体及抗GAMP抗体的杀菌活性。

Methods Activate GAMP with cyanogens bromide and prepare GAMP-protein conjugates using ADH as a linker and EDAC as a coupling agent. Immunize mice with the conjugates and determine the antibodies against GAMP and carrier proteins in their sera as well as the bactericidal activity of antibody against GAMP.

采用溴化氰活化多糖,以无水己二酸二肼为连接剂,1-乙基-1-3-(3-二甲基氨基-丙基)-碳化二亚胺为偶联剂,制备结合物并免疫小鼠,检测小鼠血清中抗GAMP与抗载体蛋白抗体及抗GAMP抗体的杀菌活性。

Objective To investigate the photodynamic therapy of human erythroleukemia cell line K562 and drug-resistance cell line K562/ADM using hexyl 5-aminolevulinate is vitro.

目的 探讨5-氨基乙酰丙酸己酯-光动力疗法对人红白血病细胞株K562及其耐阿霉素细胞株K562/ADM的杀伤效应。

The molecular compositions of PCE-CGH and PCE-CGL were investigated by chromatography and chemical analysis. Rhamnose, arabinose, glucose and galactose were proved to be the main strctural unit of PCE-CGH, and trifle glucoronic acid was identified in the molecule. The compositions of PCE-CGL were relatively complicated. Inositol and amino sugars besides for glucose and galactose were also identified in its molecule.

其中,PCE-CGH主要是以鼠李糖、阿拉伯糖、葡萄糖和半乳糖为结构单元的大分子多糖类物质,并含有少量的己糖醛酸;PCE-CGL的分子组成相对复杂,除含有葡萄糖和半乳糖外,还含有一定量的肌醇和氨基糖。

Two compounds were synthesized with two methods. The two compounds can be synthesized by two steps with triethylamine as catalyst.

分别用氢氧化钠、三乙胺为缚酸剂,3-氨基-2-丁醇、2-氨基-3-戊醇、环己酮和二氯乙酰氯为原料,采用一步法和分步法合成了两种潜在除草剂安全剂。

N-substituted pyrroles are synthesized by reacting acetonylacetone with carbamic ester , catalysted by p-toluenyl sulfonic acid, heated at reflux temperature for 6h, collecting evolved water, giving to 75% yields, which is 26% more than the literature value.

以对甲苯磺酸为催化剂,用甲苯作溶剂,使2,5-己二酮与氨基甲酸酯在110℃反应6h,合成了5种氮取代吡咯衍生物,其中两种未见文献报道,反应产率均达到75%以上,比文献值高出了26%。

In this article, we have been investigated that synthesizing and properties of shape memory polyurethane. The shape memory polyurethane was synthesized from PCL diol, MDI(4, 4'-diphenylmethane diisocyanate) and BDO (1,4-butanediol) in this experiment. We analyzed that the effect of differential mole ratio of monomers to synthesized SMPU. Besides, the various concentrations of Nano-silver were mixed with SMPU. Mechanical properties and shape memory behavior of SMPU nanocomposite films were investigated.

本研究目的为藉由改变4,4'-二苯甲基二异氰酸盐(4,4'-diphenylmethane diisocyanate, MDI)/聚己内酯二元醇(polycaprolactone diol, PCL diol)/1,4-丁二醇(1,4-butanediol, BDO)等不同莫耳比制备形状记忆型聚氨基甲酸酯(Shape Memory Polyurethane, SMPU);并探讨改变不同单体莫耳比及添加不同浓度奈米银溶液对其物性及形状记忆性的影响。

A new type of polyaspartic esters secondary amine called PAE-b was prepared from prime amine 4,4'-methylenebis and dialkyl maleates via a Michael Addition Reaction.

通过伯胺4,4'-二氨基环己基甲烷与马来酸二乙酯的Michael加成反应,合成1种新型聚天门冬氨酸酯仲胺。

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