氨基化合物

Eight porphyrin compounds, meso-5, 10, 15, 20-Tetra [4-aminophenyl] porphine (TAPPH〓, 1), meso-5, 10, 15, 20-Tetra [4-(N-pyrrolidinyl) phenyl] porphine (TBPPH〓, 2), meso-5, 10, 15, 20-Tetra [4-(4'-ethylpiperazinyl) phenyl] porphine (TEPPH〓, 3), meso-5, 10, 15, 20-Tetra [4-(4'-butylpiperazinyl) phenyl] porphine (TUPPH〓, 4), meso-5, 10, 15, 20-Tetra [4-(4'-heptylpiperazinyl) phenyl] porphine (TEPPH〓, 5), 5- [4-(4'-ethylpiperazinyl) phenyl] -10, 15, 20-triphenylporphine (MEPPH〓, 6), 5- [4-(4'-buthylpiperazinyl) phenyl] -10, 15, 20-triphenylporphine (MUPPH〓, 7) and N, N'-di (meso-5, 10, 15, 20-tetraphenylporphinato) piperazine (DiPPH〓, 8) have been designed and synthesized. These porphyrins are never reported except TAPPH〓.

设计并合成了8种卟啉化合物，分别为meso-5，10，15，20-四（4-氨基苯基）卟啉（TAPPH〓，1），meso-5，10，15，20-四卟啉（TBPPH〓，2），meso-5，10，15，20-四[4-（4'-乙基哌嗪基）苯基]卟啉（TEPPH〓，3），meso-5，10，15，20-四[4-（4'-丁基哌嗪基）苯基]卟啉（TUPPH〓，4），meso-5，10，15，20-四[4-（4'-庚基哌嗪基）苯基]卟啉（THPPH〓，5），5，10，15-三苯基-20-[4-（4'-乙基哌嗪基）苯基]卟啉（MEPPH〓，6），5，10，15-三苯基-20-[4-（4'-丁基哌嗪基）苯基]卟啉（MUPPH〓，7）和N，N'-二（meso-5，10，15，20-四苯基卟啉基）哌嗪（DiPPH〓，8）。

Chapter III We try to synthesizing pyrazole by hydrazine and thiourea in alkaline conditions, we found we can not get the acyl pyrazole in the conditions of synthesizing succinylthydrazine and ferrocenyl chalcone, pyrazole was got instead.

第三章我们尝试以酰肼及氨基硫脲作为氮源在碱性条件下来合成吡唑类化合物，并取得了理想的结果。

Studies on the Synthesis, Crystal Structures and Photochemical Photochemical Properties of Pyrazolone Thiosemicarbazones

论文标题：吡唑啉酮缩氨基硫脲类化合物的合成，晶体结构及光化学性质研究

The charges on the substituents affected OWF〓 greatly for some azobenzene derivatives, pyridone derivatives, nitrodiphenylamine derivatives, some reactive dyes and 1, 4-diamino anthraquinone derivatives, in this instance, OWF〓 changed linearly with the change of the charges.

2给电子取代基或吸电子取代基的电荷对OWF〓有较大的影响，OWF〓随电荷的变化而线性变化，如某些偶氮苯衍生物、吡啶酮类染料母体、硝基二苯胺类化合物、偶合组分和重氮组分之间夹角α变化不大的活性染料、1，4—二氨基蒽醌衍生物等。

Synthesis and characterization of two Schiff bases based on salicylaldehyde and aminebenoic were described. The structures of new compounds were characterized by JR, 1HNMR and elementary analysis.

制备了水杨醛缩邻氨基苯甲酸Schiff碱，利用红外、核磁(1H NMR)光谱和元素分析仪对化合物结构进行了表征。

Reduction of N-substituted-4-nitrophthalimides(1)to the corresponding amines(2)was performed in hydrochloric acid at 40 ℃ using stannous chloride as reduction agent, yielding produc...

氮气保护条件下，2与乙醇在固体光气作用下生成(2 取代 1，3 二酮 2，3 二氢 1H 异吲哚 5 )氨基甲酸乙酯(3)，3的产率为67%～92%。各化合物的结构均经1H NMR、IR、元素分析和FAB MS证实。

The dependence of the radiolabeling yield of ~99mTcO-NIET and 99mTcN-NIET on pH, temperature, ligand concentration, the amount of added stannous chloride, and so on was screened by the normal procedure.

合成了一种新的氨荒酸类化合物，2-（4-硝基咪唑）-乙基二硫代氨基甲酸钾，研究了影响99mTcO-NIET以及99mTcN-NIET标记率的相关因素。

Structural analysis reveals that the assemblies of these complexes are mainly directed by counter anions, followed with the change of anions from simple inorganic species (SCN~-/dca/Cl~-) to organic ones (ip/nip/tp/chdc), diversiform structures are formed varying from mononuclear, tetranuclear molecules to infinite 1-D and 2-D frameworks.

第三章利用4-bpt的同分异构体4-氨基-3，5-双(2-吡啶基)-1，2，4-三唑(2-bpt)作为螯合试剂，与多种无机/有机阴离子以及金属Cd~盐反应，得到了一系列Cd~配位化合物(7-15)。

Twenty-eight new organophosphorus compounds were prepared by reaction of sodium thio- or dithiophosphates with α-chloroacylamides.

通过硫代磷酸酯钠盐同2-α-氯代乙酰氨基噻唑或其衍生物的缩合，合成了通式为Y(R=Me、Et、i-Pr；X=O、S；Y=H、NO_2、SCN、Cl、SEt)的新有机磷化合物28个。

Biogenic amines are basic nitrogenous compounds formed mainly by decarboxylation of amino acids or by amination and transamination of aldehydes and ketones.

生物胺是一类含氮的脂肪族、芳香族或杂环类低分子化合物，主要是通过氨基酸的脱羧或醛和酮的胺化和转氨基作用形成的。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。