氨基化

The 1,5-Bis(4-aminophenylazo) anthraquinone, 1,5-bis(4-hydroxyphenyl azo) anthraquinone and 1,5-bis(3-methyl-4-hydroxyphe nylazo) anthraquinone were synthesized by diazotizing 1,5-biaminoanthraquinone with nitrosyl sulfuric acid and coupling with aniline, phenol and o-cresol.

合成以1，5-二氨基蒽醌为原料，经亚硝酰硫酸重氮化，分别和苯胺、苯酚及邻甲酚偶合，得到双（4-氨基苯）－1，5-二偶氮蒽醌，双（4-羟基苯）－1，5-二偶氮蒽醌和双（3-甲基－4-羟基苯）－1，5-二偶氮蒽醌，反应产率达47%~62%。

During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时，先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外，又研究了影响该反应的几个重要因素：亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4：1；稳定剂2-甲基-2-丁烯的用量至少大于2：1，通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出，获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

The first step of the plant pterin branch is catalyzed by GTP cyclohydrolase Ⅰ and the first step in the conversion of chorismate to pABA is mediated in plants by aminodeoxychorismate synthase.

叶酸分子是由喋呤和对氨基苯甲酸从头合成的，二者合成的关键酶腺苷三磷酸环化水解酶和氨基脱氧分支酸合成酶已得到克隆鉴定。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨："平等互利，信誉至上，团结合作，友谊长久"乙二胺；二乙胺；三乙胺；二乙烯三胺；三乙烯二胺；三乙烯四胺；四乙烯五胺；五乙烯六胺；己内酰胺；二甲基甲酰胺；烯丙基胺；N，N二甲基苯胺；正丙胺；正丁胺；正辛胺；三聚氰胺；1，2丙二胺；一乙醇胺；二乙醇胺；三乙醇胺；碘化钾；氢氧化钾；高锰酸钾；甲苯；二甲苯；对氯甲苯；丙酮；丁酮；乙酰丙酮；醋酸乙酯；醋酸丁酯；Y-丁内酯；碳酸二甲酯；乙酰乙酸甲酯；三伏乙酰乙酸；三伏乙酰乙酸乙酯；甲醇；无水乙醇；异丙醇；丙二醇；丙三醇；丙炔醇；1.3丙二醇；木糖醇；冰醋酸；己醛酸；巯基乙酸；异辛酸；己二酸；三氟乙酸；乙二酸；对氨基苯乙酸；邻氯苦杏仁酸；DL-扁桃酸；无水哌嗪；六无哌嗪；糠醛；蓖麻油；乙二醛；戊二醛；多聚甲醛；异丙醚；苯甲醚；四氢吡咯；纯吡啶；1.2二氯乙烷；二氯甲烷；三氯甲烷；四氯化碳；水合肼；壬基酚；纯间甲酚；硒酚；苯酚；对叔丁基苯酚；钛白粉；铁粉；全糖粉；双酚A；偶氮二异丁腈；叠氮化钠；碳酸钠；氯化钠；三氧化二铁；氯化亚铜；氯化亚砜；D4；碳酸氢钠；氨水；氯化钾；无水亚硫酸钠；过硫酸铵；乙二醇丁醚；乙二醇乙醚；氯化钙；环己酮；环己烷；甲基叔丁基醚；碳酸钾；三氯化铁；硝酸钾；磷酸三钠；氧化锌；亚硝酸钠；氧化锑；酒石酸；OP-10；TX-10；粒碱；AES；苯甲酸钠；柠檬酸钠；偏硅酸钠；过硼酸钠；过碳酸钠；苯磺酸钠；亚氯酸钠；乌洛托品；尿素；盐酸；硫酸；乳酸；氨基磺酸；双氧水；碳酸氢铵

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

The analysis of 1H NMR showed that the succinyl group was successfully conjugated to the amino group of chitosan molecule, and the degree of substitution of Suc-Chi values increased with increasing succinic anhydride/amino mole ratio or reducing the molecular weight of chitosan.

利用壳聚糖和琥珀酰酐反应合成了N-琥珀酰壳聚糖，1H NMR分析表明通过反应可在壳聚糖的侧氨基引入亲水性的羧基，增加琥珀酰酐／氨基的摩尔投料比或者选择分子质量较小的壳聚糖，有利于提高N-琥珀酰壳聚糖的琥珀酰化度。

The protonation constants of formylformic acid thiosemicarbazone (A, H2FFTSC) and glycylglycine and stability constants of binary complexes formed they with Mn, Co, Ni, Cu and Zn and trinary complexes of M-FFTSC-GG at 25±0.1℃ and in the presence of 0.1 mol.L-1 KNO3 were determined. The relation between the stability of binary complexes of M-FFTSC and their disinfectivity and disinfection mechanism were discussed.

在25±0.1℃，I=0.1 mol.L-1 KNO3条件下，应用pH法测定了甲酰基甲酸缩氨基硫脲(A配体，缩写H2FFTSC)，甘氨酰甘氨酸的质子化常数，它们与锰、钴、镍、铜和锌的二元配合物以及过渡金属-甲酰基甲酸缩氨基硫脲-甘氨酰甘氨酸三元配合物稳定常数，讨论了过渡金属席夫碱配合物的杀菌活性与其稳定性之间的关系，对杀菌机理提出了一些看法。

After the diazotization ,2-aminophenol-4-(2-'carboxy)sulfanil phenylamine was coupled with acetoacetanilide,2-naphthol,1-phenyl-3-methyl-5-pyrazolone,1-naphthol-4-sulfonic acid,separately to get the different diazotized compounds,then complexed with potassium chromium sulfate or cobaltous chloride to obtain the yellow,orange,red,purple,blue and other colour dyestuffs.

2-氨基苯酚-4-(2'-羧基)磺酰苯胺重氮化，分别与乙酰乙酰苯胺、2—萘酚、1-苯基-3-甲基-5-吡唑啉酮、尼文酸、1-乙酰氨基-7-萘酚等偶合，得到不同的偶氮化合物，然后分别与硫酸铬或氯化钴进行络合反应，得到黄、橙、红、紫、蓝多种颜色染料，并进行了毛织品的染色实验。

The results showed MMT/amino-resin prepolymer can be obtained by the synthesis of MMT, amido materials and formaldehyde after sodium bisulfite process.

试验结果表明，用MMT、氨基物与甲醛进行合成，亚硫酸氢钠磺化得到MMT-氨基树脂预聚体，然后加入改性后的水玻璃得到最终产品。

A method for separation and determination of amino acids using pre column derivatization with 6 aminoquinoline N hydroxysuccinimido carbamate AccQ.

对Waters公司采用 6 氨基喹啉 N 羟基琥珀酰亚胺基氨基甲酸酯柱前衍生化测定氨基酸的方法进行了改进。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。