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氨基化

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The hydrophobic core serves as a reservoir for water-insoluble drugs.Hence,these nanoparticles can be used as carriers for hydrophobic drugs.For the synthesis of cholesterol-modified glycol chitosan conjugates,a carboxyl group was initially introduced to cholesterol molecule using succinic anhydride,and then covalently coupled with the primary amino group of glycol chitosan in the presence of 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride and N-hydroxyl succinimide.

本文采用二步反应将胆固醇接枝到乙二醇壳聚糖,首先将胆固醇进行羧基化,将胆固醇与琥珀酸酐反应生成胆固醇半琥珀酸酯,然后用1-乙基-3-(3-二甲基氨丙基)碳二亚胺盐酸盐与N-羟基琥珀酰亚胺作为偶联剂,将胆固醇半琥珀酸酯的羧基与乙二醇壳聚糖主链的氨基进行反应,得到胆固醇疏水改性乙二醇壳聚糖共聚物。

The function of shelter ing nitrite from sulfamic acid is compared with that from sodium azidum.

结果表明:海洋监测规范中COD的测定方法不适合于NO-2较高的污染海水,比较了氨基磺酸与叠氮化钠对NO-2的掩蔽效果及测定方法。

It is reviewed that sulfamic acid can be utilized as a green catalyst in many important organic reactions such as esterification and transesterification,group protection,imino-Diels-Alder,rearrangement,substitution and condensation.

综述了近年来氨基磺酸作为一种绿色催化剂在有机合成中的应用,主要包括酯化与酯交换、基团保护、氮杂Diels-Alder、重排、取代及缩合等反应。

The negatively charged sulfonic acid groups was readily introduced through the reaction of the terminal anhydride groups of the anhydride-terminated hyperbranched poly precursor with the amino groups of sulfanilic acid before chemical imidization.

研究表明,在聚合过程的聚酰胺酸阶段,采用过量的邻苯二甲酸酐或苯胺对超支化聚酰亚胺的端氨基或端酸酐基团进行的封端改性切实可行,改性反应可进行地相当彻底。

With water-alcohol as solvent, 1-amino-2-naphthol-4-sulfonic acid was prepared from β-naphthol by nitrosotion, addition, and sulphonation.

摘 要:以β萘酚为原料,在水醇混合溶剂存在下,经亚硝化、加成、磺化制得 1 氨基 2 萘酚 4 磺酸,考察了原料配比、混合溶剂配比、反应时间、反应温度及过滤等因素对反应的影响,确定了优惠工艺条件。

These results, combined with the additional findings in decerebraterats, suggest that supraspinal effects (perhaps on -aminobutyricacid type A receptors) may have a supraspinal facilitatory effecton nociception for HFB.

上述结果结合在去大脑大鼠中的发现提示 HFB 的脊髓上效应(可能作用於γ-氨基丁酸 A 型受体)可能对伤害性感受有易化作用。

The mechanism of clonidine conformational isomerization and tautomeric reaction has been studied and the geometric parameters of transition states have been located by B3LYP/6-31G**.

为了考察氯苯的共轭效应对可乐定互变异构体稳定性的影响,在B3LYP/6-31G**水平上,研究了2-氨基-2-咪唑啉的互变异构化反应机理。

At the same time, the intensity ratio of the ICT fluorescence to the LE fluorescence, I〓/I〓, shows a "bell"-shaped variation with increasing CTAB concentration The intensity ratio was found to level off after the CMC of CTAB Together with the data from UV-Vis absorption spectroscopy, electric conductance measurements and the control experiments with tetramethylammonium bromide, it was concluded that the"bell"-shaped variation in the intensity ratio before CMC is due to the formation of premicelle aggregates consisting of ICT fluorophore and CTAB.

此时,ICT荧光强度与LE荧光强度之比,I〓/I〓随CTAB浓度增大而呈&钟形&变化。当CTAB浓度高于CMC时,I〓/I〓为一常数。根据紫外-可见吸收光谱,电导以及四甲基溴化铵对照实验的结果可知,当CTAB浓度低于其CMC时,I〓/I〓的&钟形&变化是由于长链对二烷基氨基苯甲酸与CTAB组成的胶束前簇集体形成所致。

Biogenic amines are basic nitrogenous compounds formed mainly by decarboxylation of amino acids or by amination and transamination of aldehydes and ketones.

生物胺是一类含氮的脂肪族、芳香族或杂环类低分子化合物,主要是通过氨基酸的脱羧或醛和酮的胺化和转氨基作用形成的。

Based on literature procedures, a dithiol tridentate ligand containing amino groupand its iron carbonyl complex (4) are synthesised and characterised. An attempt isalso made to protonate this complex.

在文献方法的基础上也合成了含有氨基的二硫醇三齿配体及其铁羰基化合物[Fe_2(SCH_2)_2C(CH_2NH_2)_5](4)的合成与表征,尝试了合成该化合物的质子化产物。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力